Bulk magnetic properties arise from micron-sized supraparticle interactions and can be modified on the nanoscale

This data publication is based on the metadata and datasets underlying the manuscript: Bulk magnetic properties arise from micron-sized supraparticle interactions and can be modified on the nanoscale

Magnetic supraparticles (SPs) can be employed as micron-sized particulate additives in arbitrary objects to serve as ID-tag or recorder of environmental triggers. Combined with magnetic particle spectroscopy (MPS), that enables read-out of the magnetic information in ambient conditions within seconds, magnetic SPs represent a powerful approach to equip materials with information. The encoded information relies on magnetic interactions within the SPs (intra-SP interactions) of chosen NPs. However, possible magnetic interactions between SPs (inter-SP interactions), that might alter the MPS signal as well, have been neglected so far. Herein, it is elucidated that significant inter-SP interactions exist and that they can be tailored via adjustments in the SP structure, i.e. by defined adjustments of their intra-interaction as revealed by 3D-MuMax simulations and experiments in viscous fluids. Superparamagnetic iron oxide nanoparticle-based SP powders with strong inter-SP interactions exhibit significantly different MPS signals compared to their state after being incorporated into a matrix. Powders with weak inter-SP interactions (achieved by integration of non-magnetic SiO₂ nanoparticles) show almost no signal change before and after incorporation. Both extremes of inter-SP interactions can be beneficial for various application scenarios and can be tailored on the nano-scale due to the interdependency of intra- and inter-SP interactions.