Published October 12, 2024 | Version v2

Data for "A combined experimental and computational exploration of heteroleptic cis-Pd2L2L'2 nanocages through geometric complementarity"

Description

In the following subdirectories are the input and output of GFN2-xTB and DFT calculations for this publication:
 
 
 
Zenodo code DOI: 10.5281/zenodo.13649229
 
data directory:
  • a spreadsheet with all final energy values and exchange energy calculations
  • CSD Survey data, NPd_survey_data_261119.csv, for Pd centres
Naming convention for file conversions:
  • l1: 1DBF
  • l2: 1Ph
  • l3: 1Th
  • la: 2DBF
  • lb: 2Py
  • lc: 2Ph
  • ld: 2Th
Structure naming convention: 
  •  mX indicates a homoleptic cage with X Pd atoms, cis/trans are the cis/trans heteroleptic cages, respectively

 

structures/xtb directory:

  • contains the structures from GFN2-xTB/ALPB(DMSO) optimisations of stk-generated structures   
 
structures/opt_*METHOD*_SP_*METHOD*_06-02-2024 directories:
  • All DFT was run by Victor Posligua
  • contains the input files (.com), output files (.log) and structure files (.xyz/.mol) of DFT optimisations and single point energy calculations with each method
  • When the opt method and SP method are the same, the final structure is included in .mol and .xyz formats
  • However, if opt method is different from the SP method, the final structure is not included because only a single-point energy calculation was run. 
  • For example, there are no .mol or .xyz files for 'opt_PBE0_SP_B3LYP_06-02-2024’ since the structure is already in 'opt_PBE0_SP_PBE0_06-02-2024’.
  • you’ll find 8 different folders:
    • opt_PBE0_SP_PBE0_06-02-2024
    • opt_PBE0_SP_B3LYP_06-02-2024
    • opt_PBE0_SP_B97D3_06-02-2024
    • opt_PBE0_SP_HSE_06-02-2024
    • opt_B3LYP_SP_B3LYP_06-02-2024
    • opt_B97D3_SP_B97D3_06-02-2024
    • opt_HSE_SP_HSE_06-02-2024
    • opt_GFN2-xTB_SP_PBE0_06-02-2024

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tarzia_lewis_2024_revised.zip

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tarzia_lewis_2024

Funding

European Commission
CoMMaD - Computational Molecular Materials Discovery 758370
European Commission
NextGenerationEU program: CAGEX SOE_0000033