Published January 1, 2009
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Low-energy photoelectron imaging spectroscopy of nitromethane anions: Electron affinity, vibrational features, anisotropies, and the dipole-bound state
Description
We present low-energy velocity map photoelectron imaging results for nitromethane anions. The photoelectron spectrum is interpreted with the aid of ab initio theory and Franck–Condon factor calculations. We obtain a new value for the adiabatic electron affinity of nitromethane of (172±6) meV and observe the dipole-bound state of nitromethane. The photoelectron angular distributions of the observed features are discussed in the context of threshold laws for photodetachment.
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