Journal article Open Access

Convenient access to the anhydrous thorium tetrachloride complexes ThCl4(DME)2, ThCl4(1,4-dioxane)2 and ThCl4(THF)3.5 using commercially available and inexpensive starting materials

Cantat, Thibault; Scott, Brian L.; Kiplinger, Jaqueline L.

Anhydrous thorium tetrachloride complexes ThCl4(DME)2, ThCl4(1,4-dioxane)2, and ThCl4(THF)3.5 have been easily accessed from inexpensive, commercially available reagents under mild conditions and serve as excellent precursors to a variety of thorium(IV) halide, alkoxide, amide and organometallic compounds.

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