Published November 15, 2023 | Version v1

Detection of Submicron- and Nanoplastics Spiked in Environmental Fresh- and Saltwater with Raman Spectroscopy

Description

ABSTRACT

Detection of small plastic particles in environmental water samples has been a topic of increasing interest in recent years. A multitude of techniques, such as variants of Raman spectroscopy, have been employed to facilitate their analysis in such complex sample matrices. However, these studies are often conducted for a limited number of plastic types in matrices with relatively little additional materials. Thus, much remains unknown about what parameters influence the detection limits of Raman spectroscopy for more environmentally relevant samples.  To address this, this study utilizes Raman spectroscopy to detect six plastic particle types; 161 and 33 nm polystyrene, < 450 nm and 36 nm poly(ethylene terephthalate), 121 nm polypropylene, and 126 nm polyethylene; spiked into artificial saltwater, artificial freshwater, North Sea, Thames River, and Elbe River water. Overall, factors such as plastic particle properties, water matrix composition, and experimental setup were shown to influence the final limits of detection.

Technical info

This dataset is to accompany the open access manuscript of the same title published at Marine Pollution Bulletin under the DOI:     
https://doi.org/10.1016/j.marpolbul.2024.116468

The main findings of this study are outlined in that manuscript. This data is presented as a complimentary proof. Using this data for further work is possible with appropriate attribution (citation of the data repository and manuscript). It is recommended to download and look through the "Read Me" file associated with this dataset for additional details about the generation, organization, and interpretation of the data presented.

Files

Figure1_NorthSeaRamanAllPlastics.zip

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Additional details

Related works

Is supplement to
10.1016/j.marpolbul.2024.116468 (DOI)

Funding

Swiss National Science Foundation
Nanoparticle Characterization 200020_184635
European Union
Land-Based Solutions for Plastics in the Sea (LABPLAS), Horizon 2020 101003954
Fundação para a Ciência e Tecnologia
Scientific Employment Stimulus Program 2020.04021.CEECIND