Elucidation of radical- and oxygenate-driven paths in zeolite-catalyzed conversion of methanol and methyl chloride to hydrocarbons

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Elucidation of radical- and oxygenate-driven paths in zeolite-catalyzed conversion of methanol and methyl chloride to hydrocarbons

Alessia Cesarini,^1† Sharon Mitchell,^1† Guido Zichittella,^1†* Mikhail Agrachev,² Stefan P. Schmid,² Gunnar Jeschke,² Zeyou Pan,³ Andras Bodi,³ Patrick Hemberger,³* and Javier Pérez‑Ramírez¹*

¹ Institute for Chemical and Bioengineering, Department of Chemistry and Applied Biosciences, ETH Zurich, Vladimir-Prelog-Weg 1, 8093 Zurich, Switzerland,

² Laboratory of Physical Chemistry, Department of Chemistry and Applied Biosciences, ETH Zurich, Vladimir-Prelog-Weg 2, 8093 Zurich, Switzerland,

³ Laboratory of Synchrotron Radiation and Femtochemistry, Paul Scherrer Institute, 5232 Villigen PSI, Switzerland,

^†These authors contributed equally, listed alphabetically.

*Corresponding author. E-mails: zguido@mit.edu, patrick.hemberger@psi.ch, jpr@chem.ethz.ch.