----------------------------------------------------------------------------------------------------
S E R I E S D A T A R E C O R D
----------------------------------------------------------------------------------------------------
System Type IGA Systems
System Owner EPFL
System Reference G200773
System Serial Number HALIGA241
Sample Number 0329
Experiment Type Sequence
Experiment No 001
Title UiO-66-NH2 Prisma
Comment
Source
Batch
ID
Experiment Title Isotherm_20deg
S A M P L E S E T U P
Sample Wet Weight 6.0206 mg
Sample Dry Weight 5.6319 mg
Sample Dry Mass 5.6319 mg
Sample Weight Loss 6.9 %d.b.
Balance Trim (V) 0.0024 cc
Balance Trim (T) Cabinet
Counterweight (M) 0.3062 g
Counterweight (ρ) 7.886 g/cc
Counterweight (T) Air
Sample Container (M) 0.0895 g
Sample Container (ρ) 7.886 g/cc
Sample Container (T) Sample
Tungsten (M) 0.0568 g
Tungsten (ρ) 19.03976 g/cc
Tungsten (T) Sample
Chain Excess (M) 0.0719 g
Chain Excess (ρ) 11.09856 g/cc
Chain Excess (T) Air
Interaction Type Adsorption
Classification Not Specified
Sample Geometry Not Specified
Sample Dimension Not Specified
Presorbed Not Specified
Sample Molar Mass Not Specified
Sample Skeletal Density Not Specified
Absolute Adsorption Basis None
Adsorbate Density Not Specified
Micropore Volume Not Specified
Dilation Not Specified
A P P L I C A T I O N S E T U P
Application Code 201510
Mode Vacuum
Source Gas Cylinder
Gas Source NITROGEN at supply pressure 10 barg
Vessel CF-SW High Pressure
Reactor Conflat SS316L
Pressure Sensor(s) 20 bar
Thermostat Water Bath
NITROGEN EOS calculation NIST REFPROP v9.1
NITROGEN SVP calculation NIST REFPROP v9.1
Source Data C:\HIsorp\G200773\Sample_0329\Sequence\Sequence001\Data.txt
Operations Log C:\HIsorp\G200773\Sample_0329\Sequence\Sequence001\Operations Log.txt
Method Log C:\HIsorp\G200773\Sample_0329\Sequence\Sequence001\Method Log.txt
File created 14:49:54 on 02 March 2020 by WR200774
Issue Level Recalculation Not Issued
Series Type Isothermal Series
Data Delimiter Space
Scan 1
Course Sorption
Reference State Device Sample
Scan Title
Scan Commenced 09:51:29 on 12 February 2020 by WR200774
Pressure Gas p/p0 Total Excess Excess BET Sample %Wt
Density Weight Adsorption Adsorption
(mbar) (g/cc) (mg) (%) (mmol/g) (g/ml(stp)) (°C) (% d.b.)
-----------------------------------------------------------------------------------------------------
-.7 0.000000 0.00 5.6319 -.0003 -.0001 0.0000 24.33 0.000
19.9 0.000023 0.00 5.6443 0.2121 0.0757 0.0000 20.00 0.220
40.0 0.000046 0.00 5.6458 0.2306 0.0823 0.0000 20.00 0.247
59.9 0.000069 0.00 5.6470 0.2447 0.0874 0.0000 20.00 0.269
79.7 0.000092 0.00 5.6486 0.2645 0.0944 0.0000 20.00 0.297
99.5 0.000114 0.00 5.6504 0.2888 0.1031 0.0000 20.00 0.329
149.1 0.000171 0.00 5.6549 0.3475 0.1241 0.0000 20.00 0.408
198.8 0.000228 0.00 5.6583 0.3888 0.1388 0.0000 19.99 0.469
248.2 0.000285 0.00 5.6615 0.4255 0.1519 0.0000 19.99 0.526
297.9 0.000342 0.00 5.6652 0.4699 0.1677 0.0000 19.99 0.591
346.9 0.000399 0.00 5.6681 0.5030 0.1796 0.0000 19.99 0.644
395.8 0.000455 0.00 5.6710 0.5346 0.1908 0.0000 20.00 0.695
449.9 0.000517 0.00 5.6748 0.5798 0.2070 0.0000 20.00 0.762
499.9 0.000575 0.00 5.6778 0.6130 0.2188 0.0000 20.00 0.815
599.9 0.000689 0.00 5.6835 0.6739 0.2406 0.0000 19.99 0.916
699.8 0.000804 0.00 5.6892 0.7346 0.2622 0.0000 19.99 1.018
749.8 0.000862 0.00 5.6922 0.7670 0.2738 0.0000 19.99 1.071
799.8 0.000919 0.00 5.6949 0.7942 0.2835 0.0000 19.99 1.118
899.8 0.001034 0.00 5.7006 0.8563 0.3057 0.0000 19.99 1.221
999.7 0.001149 0.00 5.7064 0.9189 0.3280 0.0000 20.00 1.323
1199.8 0.001379 0.00 5.7171 1.0280 0.3670 0.0000 19.99 1.513
1399.8 0.001609 0.00 5.7273 1.1293 0.4031 0.0001 19.98 1.695
1599.8 0.001839 0.00 5.7377 1.2310 0.4394 0.0001 19.97 1.878
1799.8 0.002069 0.00 5.7474 1.3225 0.4721 0.0001 19.97 2.051
1899.7 0.002184 0.00 5.7526 1.3724 0.4899 0.0001 19.97 2.143
1999.7 0.002298 0.00 5.7576 1.4216 0.5075 0.0001 19.99 2.231
2199.6 0.002528 0.00 5.7669 1.5084 0.5385 0.0001 19.99 2.397
2399.6 0.002758 0.00 5.7763 1.5939 0.5690 0.0001 19.99 2.563
2599.5 0.002988 0.00 5.7849 1.6668 0.5950 0.0001 19.98 2.717
2799.4 0.003218 0.01 5.7939 1.7435 0.6224 0.0001 19.98 2.876
-----------------------------------------------------------------------------------------------------
Scan Ends 19:30:20 on 12 February 2020 by WR200774
Reference State 19.99°C
----------------------------------------------------------------------------------------------------
S E R I E S D A T A R E C O R D
----------------------------------------------------------------------------------------------------
System Type IGA Systems
System Owner EPFL
System Reference G200773
System Serial Number HALIGA241
Sample Number 0329
Experiment Type Sequence
Experiment No 002
Title UiO-66-NH2 Prisma
Comment
Source
Batch
ID
Experiment Title Isotherm_N2_40
S A M P L E S E T U P
Sample Wet Weight 6.0206 mg
Sample Dry Weight 5.6619 mg
Sample Dry Mass 5.6619 mg
Sample Weight Loss 6.34 %d.b.
Balance Trim (V) 0.0024 cc
Balance Trim (T) Cabinet
Counterweight (M) 0.3062 g
Counterweight (ρ) 7.886 g/cc
Counterweight (T) Air
Sample Container (M) 0.0895 g
Sample Container (ρ) 7.886 g/cc
Sample Container (T) Sample
Tungsten (M) 0.0568 g
Tungsten (ρ) 19.03976 g/cc
Tungsten (T) Sample
Chain Excess (M) 0.0719 g
Chain Excess (ρ) 11.09856 g/cc
Chain Excess (T) Air
Interaction Type Adsorption
Classification Not Specified
Sample Geometry Not Specified
Sample Dimension Not Specified
Presorbed Not Specified
Sample Molar Mass Not Specified
Sample Skeletal Density Not Specified
Absolute Adsorption Basis None
Adsorbate Density Not Specified
Micropore Volume Not Specified
Dilation Not Specified
A P P L I C A T I O N S E T U P
Application Code 201510
Mode Vacuum
Source Gas Cylinder
Gas Source NITROGEN at supply pressure 10 barg
Vessel CF-SW High Pressure
Reactor Conflat SS316L
Pressure Sensor(s) 20 bar
Thermostat Water Bath
NITROGEN EOS calculation NIST REFPROP v9.1
NITROGEN SVP calculation NIST REFPROP v9.1
Source Data C:\HIsorp\G200773\Sample_0329\Sequence\Sequence002\Data.txt
Operations Log C:\HIsorp\G200773\Sample_0329\Sequence\Sequence002\Operations Log.txt
Method Log C:\HIsorp\G200773\Sample_0329\Sequence\Sequence002\Method Log.txt
File created 14:49:57 on 02 March 2020 by WR200774
Issue Level Recalculation Not Issued
Series Type Isothermal Series
Data Delimiter Space
Scan 1
Course Sorption
Reference State Device Sample
Scan Title
Scan Commenced 11:49:08 on 13 February 2020 by WR200774
Pressure Gas p/p0 Total Excess Excess BET Sample %Wt
Density Weight Adsorption Adsorption
(mbar) (g/cc) (mg) (%) (mmol/g) (g/ml(stp)) (°C) (% d.b.)
-----------------------------------------------------------------------------------------------------
-.8 0.000000 0.00 5.6619 -.0001 0.0000 0.0000 20.12 0.000
19.7 0.000021 0.00 5.6693 0.1218 0.0435 0.0000 40.02 0.130
39.8 0.000043 0.00 5.6702 0.1291 0.0461 0.0000 40.00 0.146
59.7 0.000064 0.00 5.6715 0.1453 0.0519 0.0000 40.00 0.170
79.6 0.000086 0.00 5.6728 0.1595 0.0569 0.0000 40.00 0.193
99.4 0.000107 0.00 5.6742 0.1763 0.0629 0.0000 40.00 0.218
149.1 0.000160 0.00 5.6772 0.2083 0.0744 0.0000 40.00 0.271
198.6 0.000214 0.00 5.6797 0.2309 0.0824 0.0000 39.99 0.314
250.0 0.000269 0.00 5.6824 0.2564 0.0915 0.0000 40.00 0.361
299.9 0.000323 0.00 5.6851 0.2837 0.1013 0.0000 40.00 0.409
349.9 0.000376 0.00 5.6875 0.3060 0.1092 0.0000 39.99 0.452
399.8 0.000430 0.00 5.6897 0.3238 0.1156 0.0000 39.99 0.491
449.8 0.000484 0.00 5.6922 0.3459 0.1235 0.0000 39.99 0.535
499.8 0.000538 0.00 5.6944 0.3646 0.1301 0.0000 39.99 0.574
599.8 0.000645 0.00 5.6995 0.4129 0.1474 0.0001 40.01 0.664
699.8 0.000753 0.00 5.7042 0.4535 0.1619 0.0001 40.00 0.746
749.8 0.000807 0.00 5.7061 0.4669 0.1667 0.0001 39.98 0.781
799.7 0.000860 0.00 5.7079 0.4767 0.1702 0.0001 39.99 0.812
899.9 0.000968 0.00 5.7120 0.5075 0.1812 0.0001 39.99 0.885
999.7 0.001076 0.00 5.7165 0.5462 0.1950 0.0001 40.00 0.965
1199.5 0.001291 0.00 5.7245 0.6039 0.2156 0.0001 39.99 1.106
1399.3 0.001506 0.00 5.7312 0.6376 0.2276 0.0001 39.97 1.223
1599.0 0.001721 0.00 5.7382 0.6769 0.2416 0.0001 39.97 1.347
1799.4 0.001936 0.00 5.7469 0.7460 0.2663 0.0001 39.97 1.501
1898.9 0.002043 0.00 5.7528 0.8097 0.2890 0.0001 39.98 1.605
1998.8 0.002151 0.00 5.7586 0.8726 0.3115 0.0001 39.99 1.709
2198.3 0.002365 0.00 5.7711 1.0083 0.3599 0.0001 39.98 1.928
2397.7 0.002580 0.00 5.7824 1.1226 0.4007 0.0001 39.96 2.127
2598.4 0.002796 0.00 5.7921 1.2090 0.4316 0.0001 39.95 2.300
2797.5 0.003010 0.00 5.8018 1.2980 0.4633 0.0001 39.95 2.471
-----------------------------------------------------------------------------------------------------
Scan Ends 21:31:52 on 13 February 2020 by WR200774
Reference State 39.99°C
----------------------------------------------------------------------------------------------------
S E R I E S D A T A R E C O R D
----------------------------------------------------------------------------------------------------
System Type IGA Systems
System Owner EPFL
System Reference G200773
System Serial Number HALIGA241
Sample Number 0329
Experiment Type Sequence
Experiment No 003
Title UiO-66-NH2 Prisma
Comment
Source
Batch
ID
Experiment Title Isotherm_N2_60
S A M P L E S E T U P
Sample Wet Weight 6.0206 mg
Sample Dry Weight 5.6674 mg
Sample Dry Mass 5.6674 mg
Sample Weight Loss 6.23 %d.b.
Balance Trim (V) 0.0024 cc
Balance Trim (T) Cabinet
Counterweight (M) 0.3062 g
Counterweight (ρ) 7.886 g/cc
Counterweight (T) Air
Sample Container (M) 0.0895 g
Sample Container (ρ) 7.886 g/cc
Sample Container (T) Sample
Tungsten (M) 0.0568 g
Tungsten (ρ) 19.03976 g/cc
Tungsten (T) Sample
Chain Excess (M) 0.0719 g
Chain Excess (ρ) 11.09856 g/cc
Chain Excess (T) Air
Interaction Type Adsorption
Classification Not Specified
Sample Geometry Not Specified
Sample Dimension Not Specified
Presorbed Not Specified
Sample Molar Mass Not Specified
Sample Skeletal Density Not Specified
Absolute Adsorption Basis None
Adsorbate Density Not Specified
Micropore Volume Not Specified
Dilation Not Specified
A P P L I C A T I O N S E T U P
Application Code 201510
Mode Vacuum
Source Gas Cylinder
Gas Source NITROGEN at supply pressure 10 barg
Vessel CF-SW High Pressure
Reactor Conflat SS316L
Pressure Sensor(s) 20 bar
Thermostat Water Bath
NITROGEN EOS calculation NIST REFPROP v9.1
NITROGEN SVP calculation NIST REFPROP v9.1
Source Data C:\HIsorp\G200773\Sample_0329\Sequence\Sequence003\Data.txt
Operations Log C:\HIsorp\G200773\Sample_0329\Sequence\Sequence003\Operations Log.txt
Method Log C:\HIsorp\G200773\Sample_0329\Sequence\Sequence003\Method Log.txt
File created 14:50:01 on 02 March 2020 by WR200774
Issue Level Recalculation Not Issued
Series Type Isothermal Series
Data Delimiter Space
Scan 1
Course Sorption
Reference State Device Sample
Scan Title
Scan Commenced 17:50:15 on 14 February 2020 by WR200774
Pressure Gas p/p0 Total Excess Excess BET Sample %Wt
Density Weight Adsorption Adsorption
(mbar) (g/cc) (mg) (%) (mmol/g) (g/ml(stp)) (°C) (% d.b.)
-----------------------------------------------------------------------------------------------------
-1.0 0.000000 0.00 5.6674 0.0004 0.0002 0.0000 40.13 0.000
19.9 0.000020 0.00 5.6779 0.1767 0.0631 0.0000 60.00 0.185
39.9 0.000040 0.00 5.6788 0.1847 0.0659 0.0000 60.02 0.202
59.8 0.000060 0.00 5.6799 0.1941 0.0693 0.0000 60.00 0.220
79.6 0.000080 0.00 5.6812 0.2100 0.0750 0.0000 60.01 0.244
99.5 0.000101 0.00 5.6820 0.2142 0.0765 0.0000 59.99 0.257
149.8 0.000151 0.00 5.6847 0.2405 0.0859 0.0000 60.00 0.305
199.8 0.000202 0.00 5.6868 0.2554 0.0912 0.0000 60.01 0.342
249.9 0.000253 0.00 5.6890 0.2726 0.0973 0.0000 60.00 0.380
299.9 0.000303 0.00 5.6906 0.2798 0.0999 0.0000 59.98 0.409
349.9 0.000354 0.00 5.6924 0.2908 0.1038 0.0000 59.98 0.442
399.7 0.000404 0.00 5.6942 0.3003 0.1072 0.0000 59.98 0.473
449.8 0.000455 0.00 5.6970 0.3272 0.1168 0.0000 59.99 0.521
499.8 0.000505 0.00 5.6988 0.3391 0.1210 0.0000 59.99 0.555
599.8 0.000607 0.00 5.7018 0.3483 0.1243 0.0001 60.00 0.607
699.8 0.000708 0.00 5.7042 0.3469 0.1238 0.0001 59.99 0.649
749.8 0.000758 0.00 5.7045 0.3308 0.1181 0.0001 59.97 0.655
799.8 0.000809 0.00 5.7048 0.3147 0.1123 0.0001 59.97 0.660
899.7 0.000910 0.00 5.7071 0.3116 0.1112 0.0001 59.98 0.701
999.8 0.001011 0.00 5.7099 0.3184 0.1137 0.0001 59.99 0.750
1199.9 0.001214 0.00 5.7182 0.3789 0.1353 0.0001 59.98 0.896
1399.7 0.001416 0.00 5.7293 0.4882 0.1743 0.0001 59.98 1.092
1599.5 0.001618 0.00 5.7408 0.6042 0.2157 0.0001 59.96 1.295
1799.1 0.001820 0.00 5.7532 0.7371 0.2631 0.0001 59.95 1.514
1898.9 0.001921 0.00 5.7584 0.7852 0.2803 0.0001 59.95 1.606
1998.9 0.002022 0.00 5.7630 0.8231 0.2938 0.0001 59.95 1.686
2198.8 0.002224 0.00 5.7763 0.9743 0.3478 0.0001 59.94 1.922
2398.4 0.002426 0.00 5.7839 1.0216 0.3647 0.0001 59.95 2.056
2598.2 0.002628 0.00 5.7977 1.1770 0.4202 0.0001 59.94 2.298
2798.0 0.002830 0.00 5.8146 1.3894 0.4960 0.0001 59.95 2.598
-----------------------------------------------------------------------------------------------------
Scan Ends 03:34:02 on 15 February 2020 by WR200774
Reference State 59.98°C
----------------------------------------------------------------------------------------------------
S E R I E S D A T A R E C O R D
----------------------------------------------------------------------------------------------------
System Type IGA Systems
System Owner EPFL
System Reference G200773
System Serial Number HALIGA241
Sample Number 0329
Experiment Type Sequence
Experiment No 004
Title UiO-66-NH2 Prisma
Comment
Source
Batch
ID
Experiment Title Isotherm
S A M P L E S E T U P
Sample Wet Weight 6.0206 mg
Sample Dry Weight 5.6737 mg
Sample Dry Mass 5.6737 mg
Sample Weight Loss 6.11 %d.b.
Balance Trim (V) 0.0024 cc
Balance Trim (T) Cabinet
Counterweight (M) 0.3062 g
Counterweight (ρ) 7.886 g/cc
Counterweight (T) Air
Sample Container (M) 0.0895 g
Sample Container (ρ) 7.886 g/cc
Sample Container (T) Sample
Tungsten (M) 0.0568 g
Tungsten (ρ) 19.03976 g/cc
Tungsten (T) Sample
Chain Excess (M) 0.0719 g
Chain Excess (ρ) 11.09856 g/cc
Chain Excess (T) Air
Interaction Type Adsorption
Classification Not Specified
Sample Geometry Not Specified
Sample Dimension Not Specified
Presorbed Not Specified
Sample Molar Mass Not Specified
Sample Skeletal Density Not Specified
Absolute Adsorption Basis None
Adsorbate Density Not Specified
Micropore Volume Not Specified
Dilation Not Specified
A P P L I C A T I O N S E T U P
Application Code 201510
Mode Vacuum
Source Gas Cylinder
Gas Source NITROGEN at supply pressure 10 barg
Vessel CF-SW High Pressure
Reactor Conflat SS316L
Pressure Sensor(s) 20 bar
Thermostat Water Bath
NITROGEN EOS calculation NIST REFPROP v9.1
NITROGEN SVP calculation NIST REFPROP v9.1
Source Data C:\HIsorp\G200773\Sample_0329\Sequence\Sequence004\Data.txt
Operations Log C:\HIsorp\G200773\Sample_0329\Sequence\Sequence004\Operations Log.txt
Method Log C:\HIsorp\G200773\Sample_0329\Sequence\Sequence004\Method Log.txt
File created 14:50:04 on 02 March 2020 by WR200774
Issue Level Recalculation Not Issued
Series Type Isothermal Series
Data Delimiter Space
Scan 1
Course Sorption
Reference State Device Sample
Scan Title
Scan Commenced 13:03:38 on 16 February 2020 by WR200774
Pressure Gas p/p0 Total Excess Excess BET Sample %Wt
Density Weight Adsorption Adsorption
(mbar) (g/cc) (mg) (%) (mmol/g) (g/ml(stp)) (°C) (% d.b.)
-----------------------------------------------------------------------------------------------------
-.8 0.000000 0.00 5.6737 0.0003 0.0001 0.0000 57.63 0.000
19.9 0.000020 0.00 5.6865 0.2169 0.0774 0.0000 70.01 0.226
39.9 0.000039 0.00 5.6874 0.2240 0.0800 0.0000 70.01 0.241
59.9 0.000059 0.00 5.6885 0.2347 0.0838 0.0000 70.01 0.261
79.8 0.000078 0.00 5.6890 0.2345 0.0837 0.0000 70.00 0.269
99.8 0.000098 0.00 5.6901 0.2458 0.0878 0.0000 70.00 0.289
149.9 0.000147 0.00 5.6919 0.2554 0.0912 0.0000 69.99 0.321
199.9 0.000196 0.00 5.6935 0.2625 0.0937 0.0000 69.99 0.350
249.8 0.000245 0.00 5.6951 0.2675 0.0955 0.0000 69.98 0.377
299.8 0.000294 0.00 5.6974 0.2861 0.1021 0.0000 69.99 0.417
349.9 0.000344 0.00 5.6994 0.3000 0.1071 0.0000 69.99 0.453
400.0 0.000393 0.00 5.7011 0.3094 0.1104 0.0000 70.00 0.484
449.8 0.000442 0.00 5.7027 0.3143 0.1122 0.0000 69.99 0.511
499.9 0.000491 0.00 5.7035 0.3069 0.1095 0.0000 69.98 0.525
599.8 0.000589 0.00 5.7047 0.2848 0.1017 0.0001 69.98 0.547
699.8 0.000687 0.00 5.7055 0.2540 0.0907 0.0001 69.98 0.560
749.8 0.000736 0.00 5.7074 0.2660 0.0949 0.0001 69.99 0.594
799.7 0.000785 0.00 5.7083 0.2604 0.0930 0.0001 70.00 0.609
899.8 0.000883 0.00 5.7090 0.2303 0.0822 0.0001 70.00 0.623
999.7 0.000982 0.00 5.7115 0.2307 0.0824 0.0001 69.99 0.667
1199.5 0.001178 0.00 5.7221 0.3294 0.1176 0.0001 69.97 0.853
1399.5 0.001374 0.00 5.7297 0.3760 0.1342 0.0001 69.97 0.987
1599.1 0.001570 0.00 5.7474 0.6006 0.2144 0.0001 69.95 1.299
1799.0 0.001767 0.00 5.7579 0.6987 0.2494 0.0001 69.95 1.485
1899.0 0.001865 0.00 5.7604 0.7003 0.2500 0.0001 69.94 1.529
1999.0 0.001963 0.00 5.7641 0.7213 0.2575 0.0001 69.95 1.593
2198.7 0.002159 0.00 5.7802 0.9172 0.3274 0.0001 69.95 1.877
2398.9 0.002356 0.00 5.7899 1.0008 0.3573 0.0001 69.90 2.047
2598.3 0.002552 0.00 5.8044 1.1697 0.4176 0.0001 69.92 2.304
2797.7 0.002748 0.00 5.8102 1.1830 0.4223 0.0001 69.92 2.405
-----------------------------------------------------------------------------------------------------
Scan Ends 22:47:37 on 16 February 2020 by WR200774
Reference State 69.97°C