----------------------------------------------------------------------------------------------------
S E R I E S D A T A R E C O R D
----------------------------------------------------------------------------------------------------
System Type IGA Systems
System Owner EPFL
System Reference G200773
System Serial Number HALIGA241
Sample Number 0329
Experiment Type Sequence
Experiment No 005
Title UiO-66-NH2 Prisma
Comment
Source
Batch
ID
Experiment Title Isotherm_CO2_20
S A M P L E S E T U P
Sample Wet Weight 6.0206 mg
Sample Dry Weight 5.6973 mg
Sample Dry Mass 5.6973 mg
Sample Weight Loss 5.67 %d.b.
Balance Trim (V) 0.0024 cc
Balance Trim (T) Cabinet
Counterweight (M) 0.3062 g
Counterweight (ρ) 7.886 g/cc
Counterweight (T) Air
Sample Container (M) 0.0895 g
Sample Container (ρ) 7.886 g/cc
Sample Container (T) Sample
Tungsten (M) 0.0568 g
Tungsten (ρ) 19.03976 g/cc
Tungsten (T) Sample
Chain Excess (M) 0.0719 g
Chain Excess (ρ) 11.09856 g/cc
Chain Excess (T) Air
Interaction Type Adsorption
Classification Not Specified
Sample Geometry Not Specified
Sample Dimension Not Specified
Presorbed Not Specified
Sample Molar Mass Not Specified
Sample Skeletal Density Not Specified
Absolute Adsorption Basis None
Adsorbate Density Not Specified
Micropore Volume Not Specified
Dilation Not Specified
A P P L I C A T I O N S E T U P
Application Code 201510
Mode Vacuum
Source Gas Cylinder
Gas Source CO2 at supply pressure 3 barg
Vessel CF-SW High Pressure
Reactor Conflat SS316L
Pressure Sensor(s) 20 bar
Thermostat Water Bath
CO2 EOS calculation Lookup Table
CO2 SVP calculation NIST REFPROP v9.1
Source Data C:\HIsorp\G200773\Sample_0329\Sequence\Sequence005\Data.txt
Operations Log C:\HIsorp\G200773\Sample_0329\Sequence\Sequence005\Operations Log.txt
Method Log C:\HIsorp\G200773\Sample_0329\Sequence\Sequence005\Method Log.txt
File created 14:43:20 on 02 March 2020 by WR200774
Issue Level Recalculation Not Issued
Series Type Isothermal Series
Data Delimiter Space
Scan 1
Course Sorption
Reference State Device Sample
Scan Title
Scan Commenced 16:37:18 on 17 February 2020 by WR200774
Pressure Gas p/p0 Total Excess Excess BET Sample %Wt
Density Weight Adsorption Adsorption
(mbar) (g/cc) (mg) (%) (mmol/g) (g/ml(stp)) (°C) (% d.b.)
-----------------------------------------------------------------------------------------------------
-.9 0.000000 0.00 5.6973 -.0006 -.0001 0.0000 20.49 0.00
19.8 0.000036 0.00 5.7448 0.8216 0.1867 0.0000 20.01 0.83
40.0 0.000072 0.00 5.7771 1.3753 0.3125 0.0000 20.00 1.40
59.9 0.000108 0.00 5.8055 1.8609 0.4228 0.0000 20.00 1.90
79.9 0.000145 0.00 5.8322 2.3168 0.5264 0.0000 20.00 2.37
99.9 0.000181 0.00 5.8578 2.7535 0.6256 0.0000 20.00 2.82
149.8 0.000271 0.00 5.9146 3.7195 0.8451 0.0000 19.99 3.81
199.9 0.000362 0.00 5.9628 4.5342 1.0303 0.0000 20.00 4.66
249.8 0.000452 0.00 6.0065 5.2705 1.1976 0.0000 20.01 5.43
299.9 0.000543 0.01 6.0466 5.9422 1.3502 0.0000 20.00 6.13
349.8 0.000633 0.01 6.0832 6.5534 1.4891 0.0000 19.99 6.77
399.8 0.000724 0.01 6.1171 7.1164 1.6170 0.0000 19.98 7.37
449.8 0.000814 0.01 6.1485 7.6361 1.7351 0.0000 19.98 7.92
499.8 0.000905 0.01 6.1785 8.1303 1.8474 0.0000 19.99 8.45
599.6 0.001086 0.01 6.2307 8.9852 2.0416 0.0000 20.00 9.36
699.4 0.001267 0.01 6.2780 9.7531 2.2161 0.0000 20.00 10.19
749.5 0.001359 0.01 6.3011 10.1267 2.3010 0.0000 19.98 10.60
799.5 0.001450 0.01 6.3223 10.4655 2.3780 0.0000 19.99 10.97
899.0 0.001631 0.02 6.3614 11.0876 2.5193 0.0000 19.99 11.66
998.9 0.001813 0.02 6.3970 11.6487 2.6468 0.0001 19.98 12.28
1198.2 0.002177 0.02 6.4600 12.6297 2.8697 0.0001 19.98 13.39
1397.8 0.002543 0.02 6.5168 13.5011 3.0678 0.0001 19.98 14.38
1597.4 0.002909 0.03 6.5678 14.2699 3.2424 0.0001 19.97 15.28
1800.0 0.003281 0.03 6.6144 14.9581 3.3988 0.0001 19.97 16.10
1900.0 0.003466 0.03 6.6373 15.2937 3.4751 0.0001 19.97 16.50
2000.0 0.003650 0.03 6.6588 15.6061 3.5461 0.0001 19.97 16.88
2200.0 0.004019 0.04 6.6986 16.1735 3.6750 0.0001 19.98 17.57
2400.1 0.004389 0.04 6.7365 16.7148 3.7980 0.0001 19.99 18.24
2599.9 0.004760 0.05 6.7712 17.1968 3.9075 0.0001 19.99 18.85
2800.0 0.005132 0.05 6.8045 17.6533 4.0112 0.0001 19.99 19.43
-----------------------------------------------------------------------------------------------------
Scan Ends 02:21:28 on 18 February 2020 by WR200774
Reference State 19.99°C
----------------------------------------------------------------------------------------------------
S E R I E S D A T A R E C O R D
----------------------------------------------------------------------------------------------------
System Type IGA Systems
System Owner EPFL
System Reference G200773
System Serial Number HALIGA241
Sample Number 0329
Experiment Type Sequence
Experiment No 006
Title UiO-66-NH2 Prisma
Comment
Source
Batch
ID
Experiment Title Isotherm_CO2_40
S A M P L E S E T U P
Sample Wet Weight 6.0206 mg
Sample Dry Weight 5.7183 mg
Sample Dry Mass 5.7183 mg
Sample Weight Loss 5.29 %d.b.
Balance Trim (V) 0.0024 cc
Balance Trim (T) Cabinet
Counterweight (M) 0.3062 g
Counterweight (ρ) 7.886 g/cc
Counterweight (T) Air
Sample Container (M) 0.0895 g
Sample Container (ρ) 7.886 g/cc
Sample Container (T) Sample
Tungsten (M) 0.0568 g
Tungsten (ρ) 19.03976 g/cc
Tungsten (T) Sample
Chain Excess (M) 0.0719 g
Chain Excess (ρ) 11.09856 g/cc
Chain Excess (T) Air
Interaction Type Adsorption
Classification Not Specified
Sample Geometry Not Specified
Sample Dimension Not Specified
Presorbed Not Specified
Sample Molar Mass Not Specified
Sample Skeletal Density Not Specified
Absolute Adsorption Basis None
Adsorbate Density Not Specified
Micropore Volume Not Specified
Dilation Not Specified
A P P L I C A T I O N S E T U P
Application Code 201510
Mode Vacuum
Source Gas Cylinder
Gas Source CO2 at supply pressure 3 barg
Vessel CF-SW High Pressure
Reactor Conflat SS316L
Pressure Sensor(s) 20 bar
Thermostat Water Bath
CO2 EOS calculation Lookup Table
CO2 SVP calculation NIST REFPROP v9.1
Source Data C:\HIsorp\G200773\Sample_0329\Sequence\Sequence006\Data.txt
Operations Log C:\HIsorp\G200773\Sample_0329\Sequence\Sequence006\Operations Log.txt
Method Log C:\HIsorp\G200773\Sample_0329\Sequence\Sequence006\Method Log.txt
File created 14:43:23 on 02 March 2020 by WR200774
Issue Level Recalculation Not Issued
Series Type Isothermal Series
Data Delimiter Space
Scan 1
Course Sorption
Reference State Device Sample
Scan Title
Scan Commenced 19:27:52 on 18 February 2020 by WR200774
Pressure Gas p/p0 Total Excess Excess BET Sample %Wt
Density Weight Adsorption Adsorption
(mbar) (g/cc) (mg) (%) (mmol/g) (g/ml(stp)) (°C) (% d.b.)
-----------------------------------------------------------------------------------------------------
-.7 0.000000 0.00 5.7183 0.0002 0.0000 0.0000 20.11 0.00
20.0 0.000034 0.00 5.7469 0.4871 0.1107 0.0000 40.00 0.50
39.9 0.000068 0.00 5.7657 0.8020 0.1822 0.0000 39.99 0.83
60.0 0.000102 0.00 5.7831 1.0944 0.2487 0.0000 40.00 1.13
79.9 0.000135 0.00 5.7999 1.3750 0.3124 0.0000 40.01 1.43
99.9 0.000169 0.00 5.8155 1.6347 0.3714 0.0000 39.98 1.70
149.7 0.000254 0.00 5.8519 2.2390 0.5088 0.0000 40.00 2.34
199.8 0.000338 0.00 5.8846 2.7784 0.6313 0.0000 40.01 2.91
249.9 0.000423 0.00 5.9149 3.2759 0.7444 0.0000 40.00 3.44
299.8 0.000508 0.00 5.9428 3.7294 0.8474 0.0000 39.99 3.93
349.8 0.000593 0.00 5.9687 4.1501 0.9430 0.0000 39.98 4.38
399.7 0.000677 0.00 5.9931 4.5435 1.0324 0.0000 39.98 4.81
449.6 0.000762 0.01 6.0165 4.9201 1.1180 0.0000 39.99 5.21
499.7 0.000846 0.01 6.0391 5.2843 1.2007 0.0000 40.00 5.61
599.4 0.001016 0.01 6.0790 5.9159 1.3442 0.0000 39.99 6.31
699.6 0.001186 0.01 6.1154 6.4877 1.4741 0.0000 39.98 6.94
749.3 0.001271 0.01 6.1325 6.7535 1.5345 0.0000 39.98 7.24
799.3 0.001356 0.01 6.1491 7.0104 1.5929 0.0000 39.97 7.53
899.0 0.001526 0.01 6.1814 7.5084 1.7061 0.0000 39.97 8.10
998.8 0.001695 0.01 6.2124 7.9862 1.8146 0.0000 39.99 8.64
1198.3 0.002036 0.01 6.2729 8.9147 2.0256 0.0001 39.98 9.70
1400.0 0.002381 0.02 6.3252 9.6964 2.2032 0.0001 39.95 10.61
1600.0 0.002723 0.02 6.3719 10.3795 2.3585 0.0001 39.96 11.43
1800.0 0.003067 0.02 6.4139 10.9783 2.4945 0.0001 39.94 12.16
1899.9 0.003238 0.02 6.4382 11.3360 2.5758 0.0001 39.93 12.59
2000.0 0.003410 0.02 6.4629 11.7026 2.6591 0.0001 39.94 13.02
2200.0 0.003754 0.02 6.5018 12.2523 2.7840 0.0001 39.95 13.70
2400.0 0.004099 0.03 6.5401 12.7907 2.9063 0.0001 39.98 14.37
2600.0 0.004445 0.03 6.5736 13.2402 3.0085 0.0001 39.96 14.96
2799.9 0.004790 0.03 6.6028 13.6136 3.0933 0.0001 39.97 15.47
-----------------------------------------------------------------------------------------------------
Scan Ends 05:26:18 on 19 February 2020 by WR200774
Reference State 39.98°C
----------------------------------------------------------------------------------------------------
S E R I E S D A T A R E C O R D
----------------------------------------------------------------------------------------------------
System Type IGA Systems
System Owner EPFL
System Reference G200773
System Serial Number HALIGA241
Sample Number 0329
Experiment Type Sequence
Experiment No 007
Title UiO-66-NH2 Prisma
Comment
Source
Batch
ID
Experiment Title Isotherm_CO2_60deg
S A M P L E S E T U P
Sample Wet Weight 6.0206 mg
Sample Dry Weight 5.7215 mg
Sample Dry Mass 5.7215 mg
Sample Weight Loss 5.23 %d.b.
Balance Trim (V) 0.0024 cc
Balance Trim (T) Cabinet
Counterweight (M) 0.3062 g
Counterweight (ρ) 7.886 g/cc
Counterweight (T) Air
Sample Container (M) 0.0895 g
Sample Container (ρ) 7.886 g/cc
Sample Container (T) Sample
Tungsten (M) 0.0568 g
Tungsten (ρ) 19.03976 g/cc
Tungsten (T) Sample
Chain Excess (M) 0.0719 g
Chain Excess (ρ) 11.09856 g/cc
Chain Excess (T) Air
Interaction Type Adsorption
Classification Not Specified
Sample Geometry Not Specified
Sample Dimension Not Specified
Presorbed Not Specified
Sample Molar Mass Not Specified
Sample Skeletal Density Not Specified
Absolute Adsorption Basis None
Adsorbate Density Not Specified
Micropore Volume Not Specified
Dilation Not Specified
A P P L I C A T I O N S E T U P
Application Code 201510
Mode Vacuum
Source Gas Cylinder
Gas Source CO2 at supply pressure 3 barg
Vessel CF-SW High Pressure
Reactor Conflat SS316L
Pressure Sensor(s) 20 bar
Thermostat Water Bath
CO2 EOS calculation Lookup Table
CO2 SVP calculation NIST REFPROP v9.1
Source Data C:\HIsorp\G200773\Sample_0329\Sequence\Sequence007\Data.txt
Operations Log C:\HIsorp\G200773\Sample_0329\Sequence\Sequence007\Operations Log.txt
Method Log C:\HIsorp\G200773\Sample_0329\Sequence\Sequence007\Method Log.txt
File created 14:43:27 on 02 March 2020 by WR200774
Issue Level Recalculation Not Issued
Series Type Isothermal Series
Data Delimiter Space
Scan 1
Course Sorption
Reference State Device Sample
Scan Title
Scan Commenced 11:54:07 on 19 February 2020 by WR200774
Pressure Gas p/p0 Total Excess Excess BET Sample %Wt
Density Weight Adsorption Adsorption
(mbar) (g/cc) (mg) (%) (mmol/g) (g/ml(stp)) (°C) (% d.b.)
-----------------------------------------------------------------------------------------------------
-1.0 0.000000 0.00 5.7215 0.0002 0.0000 0.0000 40.19 0.00
19.8 0.000031 0.00 5.7409 0.3263 0.0741 0.0000 60.00 0.34
39.9 0.000064 0.00 5.7519 0.5048 0.1147 0.0000 59.99 0.53
59.9 0.000095 0.00 5.7626 0.6781 0.1541 0.0000 60.00 0.72
79.9 0.000127 0.00 5.7725 0.8378 0.1904 0.0000 59.99 0.89
99.9 0.000159 0.00 5.7828 1.0036 0.2280 0.0000 60.00 1.07
149.6 0.000238 0.00 5.8057 1.3714 0.3116 0.0000 59.99 1.47
199.8 0.000318 0.00 5.8265 1.6998 0.3862 0.0000 60.00 1.83
249.8 0.000398 0.00 5.8463 2.0134 0.4575 0.0000 59.98 2.18
300.0 0.000477 0.00 5.8660 2.3242 0.5281 0.0000 59.99 2.53
349.9 0.000557 0.00 5.8841 2.6066 0.5923 0.0000 60.00 2.84
400.0 0.000637 0.00 5.9005 2.8598 0.6498 0.0000 60.00 3.13
450.1 0.000716 0.00 5.9158 3.0923 0.7026 0.0000 59.99 3.40
500.0 0.000796 0.00 5.9297 3.3016 0.7502 0.0000 59.98 3.64
600.0 0.000955 0.00 5.9584 3.7357 0.8488 0.0000 59.98 4.14
700.0 0.001115 0.01 5.9915 4.2474 0.9651 0.0000 59.98 4.72
750.0 0.001195 0.01 6.0085 4.5103 1.0249 0.0000 59.98 5.02
800.0 0.001275 0.01 6.0180 4.6443 1.0553 0.0000 59.99 5.18
900.0 0.001434 0.01 6.0518 5.1664 1.1739 0.0000 59.98 5.77
1000.0 0.001594 0.01 6.0792 5.5769 1.2672 0.0000 59.95 6.25
1199.9 0.001915 0.01 6.1233 6.2105 1.4112 0.0001 59.93 7.02
1400.0 0.002236 0.01 6.1767 7.0077 1.5923 0.0001 59.86 7.96
1600.0 0.002557 0.01 6.2225 7.6740 1.7437 0.0001 59.85 8.76
1799.9 0.002878 0.01 6.2608 8.2073 1.8649 0.0001 59.92 9.43
1900.0 0.003039 0.01 6.2785 8.4473 1.9194 0.0001 59.97 9.74
2000.0 0.003200 0.02 6.2962 8.6871 1.9739 0.0001 59.96 10.05
2200.0 0.003523 0.02 6.3239 9.0332 2.0525 0.0001 59.93 10.53
2400.0 0.003845 0.02 6.3539 9.4181 2.1400 0.0001 60.02 11.05
2600.0 0.004167 0.02 6.3819 9.7721 2.2204 0.0001 60.06 11.54
2800.0 0.004492 0.02 6.4045 10.0299 2.2790 0.0001 60.02 11.94
-----------------------------------------------------------------------------------------------------
Scan Ends 21:42:50 on 19 February 2020 by WR200774
Reference State 59.98°C
----------------------------------------------------------------------------------------------------
S E R I E S D A T A R E C O R D
----------------------------------------------------------------------------------------------------
System Type IGA Systems
System Owner EPFL
System Reference G200773
System Serial Number HALIGA241
Sample Number 0329
Experiment Type Sequence
Experiment No 013
Title UiO-66-NH2 Prisma
Comment
Source
Batch
ID
Experiment Title Isotherm_CO2_70deg
S A M P L E S E T U P
Sample Wet Weight 6.0206 mg
Sample Dry Weight 5.7353 mg
Sample Dry Mass 5.7353 mg
Sample Weight Loss 4.97 %d.b.
Balance Trim (V) 0.0024 cc
Balance Trim (T) Cabinet
Counterweight (M) 0.3062 g
Counterweight (ρ) 7.886 g/cc
Counterweight (T) Air
Sample Container (M) 0.0895 g
Sample Container (ρ) 7.886 g/cc
Sample Container (T) Sample
Tungsten (M) 0.0568 g
Tungsten (ρ) 19.03976 g/cc
Tungsten (T) Sample
Chain Excess (M) 0.0719 g
Chain Excess (ρ) 11.09856 g/cc
Chain Excess (T) Air
Interaction Type Adsorption
Classification Not Specified
Sample Geometry Not Specified
Sample Dimension Not Specified
Presorbed Not Specified
Sample Molar Mass Not Specified
Sample Skeletal Density Not Specified
Absolute Adsorption Basis None
Adsorbate Density Not Specified
Micropore Volume Not Specified
Dilation Not Specified
A P P L I C A T I O N S E T U P
Application Code 201510
Mode Vacuum
Source Gas Cylinder
Gas Source CO2 at supply pressure 5 barg
Vessel CF-SW High Pressure
Reactor Conflat SS316L
Pressure Sensor(s) 20 bar
Thermostat Water Bath
CO2 EOS calculation Lookup Table
CO2 SVP calculation NIST REFPROP v9.1
Source Data C:\HIsorp\G200773\Sample_0329\Sequence\Sequence013\Data.txt
Operations Log C:\HIsorp\G200773\Sample_0329\Sequence\Sequence013\Operations Log.txt
Method Log C:\HIsorp\G200773\Sample_0329\Sequence\Sequence013\Method Log.txt
File created 14:43:30 on 02 March 2020 by WR200774
Issue Level Recalculation Not Issued
Series Type Isothermal Series
Data Delimiter Space
Scan 1
Course Sorption
Reference State Device Sample
Scan Title
Scan Commenced 11:42:51 on 01 March 2020 by WR200774
Pressure Gas p/p0 Total Excess Excess BET Sample %Wt
Density Weight Adsorption Adsorption
(mbar) (g/cc) (mg) (%) (mmol/g) (g/ml(stp)) (°C) (% d.b.)
-----------------------------------------------------------------------------------------------------
-.4 0.000000 0.00 5.7353 -.0008 -.0002 0.0000 61.53 0.00
19.8 0.000031 0.00 5.7536 0.3056 0.0694 0.0000 70.00 0.32
39.8 0.000061 0.00 5.7628 0.4523 0.1028 0.0000 70.01 0.48
60.0 0.000093 0.00 5.7712 0.5851 0.1329 0.0000 69.99 0.63
79.7 0.000123 0.00 5.7791 0.7086 0.1610 0.0000 69.99 0.76
99.9 0.000154 0.00 5.7878 0.8471 0.1925 0.0000 70.02 0.92
149.8 0.000231 0.00 5.8070 1.1483 0.2609 0.0000 69.99 1.25
199.8 0.000309 0.00 5.8238 1.4075 0.3198 0.0000 69.99 1.54
250.3 0.000387 0.00 5.8407 1.6659 0.3785 0.0000 69.99 1.84
300.1 0.000464 0.00 5.8558 1.8953 0.4307 0.0000 69.98 2.10
349.3 0.000540 0.00 5.8708 2.1233 0.4825 0.0000 70.00 2.36
399.4 0.000617 0.00 5.8843 2.3260 0.5285 0.0000 70.00 2.60
449.9 0.000695 0.00 5.8964 2.5026 0.5686 0.0000 70.00 2.81
500.1 0.000773 0.00 5.9077 2.6644 0.6054 0.0000 69.97 3.01
600.0 0.000927 0.00 5.9350 3.0712 0.6978 0.0000 69.97 3.48
697.6 0.001078 0.00 5.9626 3.4860 0.7921 0.0000 69.96 3.96
748.0 0.001157 0.00 5.9818 3.7862 0.8603 0.0000 69.96 4.30
800.2 0.001237 0.01 5.9956 3.9912 0.9069 0.0000 69.98 4.54
900.2 0.001392 0.01 6.0220 4.3831 0.9959 0.0000 69.99 5.00
1000.1 0.001548 0.01 6.0420 4.6642 1.0598 0.0000 69.94 5.35
1198.2 0.001855 0.01 6.0861 5.2967 1.2035 0.0000 69.91 6.12
1399.1 0.002169 0.01 6.1316 5.9503 1.3520 0.0001 69.81 6.91
1596.8 0.002477 0.01 6.1796 6.6499 1.5110 0.0001 69.79 7.75
1800.3 0.002793 0.01 6.2075 6.9971 1.5899 0.0001 69.93 8.23
1895.8 0.002942 0.01 6.2318 7.3544 1.6711 0.0001 69.92 8.66
1996.5 0.003099 0.01 6.2411 7.4466 1.6920 0.0001 69.96 8.82
2196.0 0.003409 0.01 6.2584 7.6068 1.7284 0.0001 70.18 9.12
2400.0 0.003729 0.02 6.2883 7.9848 1.8143 0.0001 70.08 9.64
2600.2 0.004043 0.02 6.3158 8.3238 1.8913 0.0001 70.00 10.12
2796.3 0.004351 0.02 6.3463 8.7196 1.9813 0.0001 70.00 10.65
-----------------------------------------------------------------------------------------------------
Scan Ends 21:38:21 on 01 March 2020 by WR200774
Reference State 69.98°C