---------------------------------------------------------------------------------------------------- S E R I E S D A T A R E C O R D ---------------------------------------------------------------------------------------------------- System Type IGA Systems System Owner EPFL System Reference G200773 System Serial Number HALIGA241 Sample Number 0329 Experiment Type Sequence Experiment No 005 Title UiO-66-NH2 Prisma Comment Source Batch ID Experiment Title Isotherm_CO2_20 S A M P L E S E T U P Sample Wet Weight 6.0206 mg Sample Dry Weight 5.6973 mg Sample Dry Mass 5.6973 mg Sample Weight Loss 5.67 %d.b. Balance Trim (V) 0.0024 cc Balance Trim (T) Cabinet Counterweight (M) 0.3062 g Counterweight (ρ) 7.886 g/cc Counterweight (T) Air Sample Container (M) 0.0895 g Sample Container (ρ) 7.886 g/cc Sample Container (T) Sample Tungsten (M) 0.0568 g Tungsten (ρ) 19.03976 g/cc Tungsten (T) Sample Chain Excess (M) 0.0719 g Chain Excess (ρ) 11.09856 g/cc Chain Excess (T) Air Interaction Type Adsorption Classification Not Specified Sample Geometry Not Specified Sample Dimension Not Specified Presorbed Not Specified Sample Molar Mass Not Specified Sample Skeletal Density Not Specified Absolute Adsorption Basis None Adsorbate Density Not Specified Micropore Volume Not Specified Dilation Not Specified A P P L I C A T I O N S E T U P Application Code 201510 Mode Vacuum Source Gas Cylinder Gas Source CO2 at supply pressure 3 barg Vessel CF-SW High Pressure Reactor Conflat SS316L Pressure Sensor(s) 20 bar Thermostat Water Bath CO2 EOS calculation Lookup Table CO2 SVP calculation NIST REFPROP v9.1 Source Data C:\HIsorp\G200773\Sample_0329\Sequence\Sequence005\Data.txt Operations Log C:\HIsorp\G200773\Sample_0329\Sequence\Sequence005\Operations Log.txt Method Log C:\HIsorp\G200773\Sample_0329\Sequence\Sequence005\Method Log.txt File created 14:43:20 on 02 March 2020 by WR200774 Issue Level Recalculation Not Issued Series Type Isothermal Series Data Delimiter Space Scan 1 Course Sorption Reference State Device Sample Scan Title Scan Commenced 16:37:18 on 17 February 2020 by WR200774 Pressure Gas p/p0 Total Excess Excess BET Sample %Wt Density Weight Adsorption Adsorption (mbar) (g/cc) (mg) (%) (mmol/g) (g/ml(stp)) (°C) (% d.b.) ----------------------------------------------------------------------------------------------------- -.9 0.000000 0.00 5.6973 -.0006 -.0001 0.0000 20.49 0.00 19.8 0.000036 0.00 5.7448 0.8216 0.1867 0.0000 20.01 0.83 40.0 0.000072 0.00 5.7771 1.3753 0.3125 0.0000 20.00 1.40 59.9 0.000108 0.00 5.8055 1.8609 0.4228 0.0000 20.00 1.90 79.9 0.000145 0.00 5.8322 2.3168 0.5264 0.0000 20.00 2.37 99.9 0.000181 0.00 5.8578 2.7535 0.6256 0.0000 20.00 2.82 149.8 0.000271 0.00 5.9146 3.7195 0.8451 0.0000 19.99 3.81 199.9 0.000362 0.00 5.9628 4.5342 1.0303 0.0000 20.00 4.66 249.8 0.000452 0.00 6.0065 5.2705 1.1976 0.0000 20.01 5.43 299.9 0.000543 0.01 6.0466 5.9422 1.3502 0.0000 20.00 6.13 349.8 0.000633 0.01 6.0832 6.5534 1.4891 0.0000 19.99 6.77 399.8 0.000724 0.01 6.1171 7.1164 1.6170 0.0000 19.98 7.37 449.8 0.000814 0.01 6.1485 7.6361 1.7351 0.0000 19.98 7.92 499.8 0.000905 0.01 6.1785 8.1303 1.8474 0.0000 19.99 8.45 599.6 0.001086 0.01 6.2307 8.9852 2.0416 0.0000 20.00 9.36 699.4 0.001267 0.01 6.2780 9.7531 2.2161 0.0000 20.00 10.19 749.5 0.001359 0.01 6.3011 10.1267 2.3010 0.0000 19.98 10.60 799.5 0.001450 0.01 6.3223 10.4655 2.3780 0.0000 19.99 10.97 899.0 0.001631 0.02 6.3614 11.0876 2.5193 0.0000 19.99 11.66 998.9 0.001813 0.02 6.3970 11.6487 2.6468 0.0001 19.98 12.28 1198.2 0.002177 0.02 6.4600 12.6297 2.8697 0.0001 19.98 13.39 1397.8 0.002543 0.02 6.5168 13.5011 3.0678 0.0001 19.98 14.38 1597.4 0.002909 0.03 6.5678 14.2699 3.2424 0.0001 19.97 15.28 1800.0 0.003281 0.03 6.6144 14.9581 3.3988 0.0001 19.97 16.10 1900.0 0.003466 0.03 6.6373 15.2937 3.4751 0.0001 19.97 16.50 2000.0 0.003650 0.03 6.6588 15.6061 3.5461 0.0001 19.97 16.88 2200.0 0.004019 0.04 6.6986 16.1735 3.6750 0.0001 19.98 17.57 2400.1 0.004389 0.04 6.7365 16.7148 3.7980 0.0001 19.99 18.24 2599.9 0.004760 0.05 6.7712 17.1968 3.9075 0.0001 19.99 18.85 2800.0 0.005132 0.05 6.8045 17.6533 4.0112 0.0001 19.99 19.43 ----------------------------------------------------------------------------------------------------- Scan Ends 02:21:28 on 18 February 2020 by WR200774 Reference State 19.99°C ---------------------------------------------------------------------------------------------------- S E R I E S D A T A R E C O R D ---------------------------------------------------------------------------------------------------- System Type IGA Systems System Owner EPFL System Reference G200773 System Serial Number HALIGA241 Sample Number 0329 Experiment Type Sequence Experiment No 006 Title UiO-66-NH2 Prisma Comment Source Batch ID Experiment Title Isotherm_CO2_40 S A M P L E S E T U P Sample Wet Weight 6.0206 mg Sample Dry Weight 5.7183 mg Sample Dry Mass 5.7183 mg Sample Weight Loss 5.29 %d.b. Balance Trim (V) 0.0024 cc Balance Trim (T) Cabinet Counterweight (M) 0.3062 g Counterweight (ρ) 7.886 g/cc Counterweight (T) Air Sample Container (M) 0.0895 g Sample Container (ρ) 7.886 g/cc Sample Container (T) Sample Tungsten (M) 0.0568 g Tungsten (ρ) 19.03976 g/cc Tungsten (T) Sample Chain Excess (M) 0.0719 g Chain Excess (ρ) 11.09856 g/cc Chain Excess (T) Air Interaction Type Adsorption Classification Not Specified Sample Geometry Not Specified Sample Dimension Not Specified Presorbed Not Specified Sample Molar Mass Not Specified Sample Skeletal Density Not Specified Absolute Adsorption Basis None Adsorbate Density Not Specified Micropore Volume Not Specified Dilation Not Specified A P P L I C A T I O N S E T U P Application Code 201510 Mode Vacuum Source Gas Cylinder Gas Source CO2 at supply pressure 3 barg Vessel CF-SW High Pressure Reactor Conflat SS316L Pressure Sensor(s) 20 bar Thermostat Water Bath CO2 EOS calculation Lookup Table CO2 SVP calculation NIST REFPROP v9.1 Source Data C:\HIsorp\G200773\Sample_0329\Sequence\Sequence006\Data.txt Operations Log C:\HIsorp\G200773\Sample_0329\Sequence\Sequence006\Operations Log.txt Method Log C:\HIsorp\G200773\Sample_0329\Sequence\Sequence006\Method Log.txt File created 14:43:23 on 02 March 2020 by WR200774 Issue Level Recalculation Not Issued Series Type Isothermal Series Data Delimiter Space Scan 1 Course Sorption Reference State Device Sample Scan Title Scan Commenced 19:27:52 on 18 February 2020 by WR200774 Pressure Gas p/p0 Total Excess Excess BET Sample %Wt Density Weight Adsorption Adsorption (mbar) (g/cc) (mg) (%) (mmol/g) (g/ml(stp)) (°C) (% d.b.) ----------------------------------------------------------------------------------------------------- -.7 0.000000 0.00 5.7183 0.0002 0.0000 0.0000 20.11 0.00 20.0 0.000034 0.00 5.7469 0.4871 0.1107 0.0000 40.00 0.50 39.9 0.000068 0.00 5.7657 0.8020 0.1822 0.0000 39.99 0.83 60.0 0.000102 0.00 5.7831 1.0944 0.2487 0.0000 40.00 1.13 79.9 0.000135 0.00 5.7999 1.3750 0.3124 0.0000 40.01 1.43 99.9 0.000169 0.00 5.8155 1.6347 0.3714 0.0000 39.98 1.70 149.7 0.000254 0.00 5.8519 2.2390 0.5088 0.0000 40.00 2.34 199.8 0.000338 0.00 5.8846 2.7784 0.6313 0.0000 40.01 2.91 249.9 0.000423 0.00 5.9149 3.2759 0.7444 0.0000 40.00 3.44 299.8 0.000508 0.00 5.9428 3.7294 0.8474 0.0000 39.99 3.93 349.8 0.000593 0.00 5.9687 4.1501 0.9430 0.0000 39.98 4.38 399.7 0.000677 0.00 5.9931 4.5435 1.0324 0.0000 39.98 4.81 449.6 0.000762 0.01 6.0165 4.9201 1.1180 0.0000 39.99 5.21 499.7 0.000846 0.01 6.0391 5.2843 1.2007 0.0000 40.00 5.61 599.4 0.001016 0.01 6.0790 5.9159 1.3442 0.0000 39.99 6.31 699.6 0.001186 0.01 6.1154 6.4877 1.4741 0.0000 39.98 6.94 749.3 0.001271 0.01 6.1325 6.7535 1.5345 0.0000 39.98 7.24 799.3 0.001356 0.01 6.1491 7.0104 1.5929 0.0000 39.97 7.53 899.0 0.001526 0.01 6.1814 7.5084 1.7061 0.0000 39.97 8.10 998.8 0.001695 0.01 6.2124 7.9862 1.8146 0.0000 39.99 8.64 1198.3 0.002036 0.01 6.2729 8.9147 2.0256 0.0001 39.98 9.70 1400.0 0.002381 0.02 6.3252 9.6964 2.2032 0.0001 39.95 10.61 1600.0 0.002723 0.02 6.3719 10.3795 2.3585 0.0001 39.96 11.43 1800.0 0.003067 0.02 6.4139 10.9783 2.4945 0.0001 39.94 12.16 1899.9 0.003238 0.02 6.4382 11.3360 2.5758 0.0001 39.93 12.59 2000.0 0.003410 0.02 6.4629 11.7026 2.6591 0.0001 39.94 13.02 2200.0 0.003754 0.02 6.5018 12.2523 2.7840 0.0001 39.95 13.70 2400.0 0.004099 0.03 6.5401 12.7907 2.9063 0.0001 39.98 14.37 2600.0 0.004445 0.03 6.5736 13.2402 3.0085 0.0001 39.96 14.96 2799.9 0.004790 0.03 6.6028 13.6136 3.0933 0.0001 39.97 15.47 ----------------------------------------------------------------------------------------------------- Scan Ends 05:26:18 on 19 February 2020 by WR200774 Reference State 39.98°C ---------------------------------------------------------------------------------------------------- S E R I E S D A T A R E C O R D ---------------------------------------------------------------------------------------------------- System Type IGA Systems System Owner EPFL System Reference G200773 System Serial Number HALIGA241 Sample Number 0329 Experiment Type Sequence Experiment No 007 Title UiO-66-NH2 Prisma Comment Source Batch ID Experiment Title Isotherm_CO2_60deg S A M P L E S E T U P Sample Wet Weight 6.0206 mg Sample Dry Weight 5.7215 mg Sample Dry Mass 5.7215 mg Sample Weight Loss 5.23 %d.b. Balance Trim (V) 0.0024 cc Balance Trim (T) Cabinet Counterweight (M) 0.3062 g Counterweight (ρ) 7.886 g/cc Counterweight (T) Air Sample Container (M) 0.0895 g Sample Container (ρ) 7.886 g/cc Sample Container (T) Sample Tungsten (M) 0.0568 g Tungsten (ρ) 19.03976 g/cc Tungsten (T) Sample Chain Excess (M) 0.0719 g Chain Excess (ρ) 11.09856 g/cc Chain Excess (T) Air Interaction Type Adsorption Classification Not Specified Sample Geometry Not Specified Sample Dimension Not Specified Presorbed Not Specified Sample Molar Mass Not Specified Sample Skeletal Density Not Specified Absolute Adsorption Basis None Adsorbate Density Not Specified Micropore Volume Not Specified Dilation Not Specified A P P L I C A T I O N S E T U P Application Code 201510 Mode Vacuum Source Gas Cylinder Gas Source CO2 at supply pressure 3 barg Vessel CF-SW High Pressure Reactor Conflat SS316L Pressure Sensor(s) 20 bar Thermostat Water Bath CO2 EOS calculation Lookup Table CO2 SVP calculation NIST REFPROP v9.1 Source Data C:\HIsorp\G200773\Sample_0329\Sequence\Sequence007\Data.txt Operations Log C:\HIsorp\G200773\Sample_0329\Sequence\Sequence007\Operations Log.txt Method Log C:\HIsorp\G200773\Sample_0329\Sequence\Sequence007\Method Log.txt File created 14:43:27 on 02 March 2020 by WR200774 Issue Level Recalculation Not Issued Series Type Isothermal Series Data Delimiter Space Scan 1 Course Sorption Reference State Device Sample Scan Title Scan Commenced 11:54:07 on 19 February 2020 by WR200774 Pressure Gas p/p0 Total Excess Excess BET Sample %Wt Density Weight Adsorption Adsorption (mbar) (g/cc) (mg) (%) (mmol/g) (g/ml(stp)) (°C) (% d.b.) ----------------------------------------------------------------------------------------------------- -1.0 0.000000 0.00 5.7215 0.0002 0.0000 0.0000 40.19 0.00 19.8 0.000031 0.00 5.7409 0.3263 0.0741 0.0000 60.00 0.34 39.9 0.000064 0.00 5.7519 0.5048 0.1147 0.0000 59.99 0.53 59.9 0.000095 0.00 5.7626 0.6781 0.1541 0.0000 60.00 0.72 79.9 0.000127 0.00 5.7725 0.8378 0.1904 0.0000 59.99 0.89 99.9 0.000159 0.00 5.7828 1.0036 0.2280 0.0000 60.00 1.07 149.6 0.000238 0.00 5.8057 1.3714 0.3116 0.0000 59.99 1.47 199.8 0.000318 0.00 5.8265 1.6998 0.3862 0.0000 60.00 1.83 249.8 0.000398 0.00 5.8463 2.0134 0.4575 0.0000 59.98 2.18 300.0 0.000477 0.00 5.8660 2.3242 0.5281 0.0000 59.99 2.53 349.9 0.000557 0.00 5.8841 2.6066 0.5923 0.0000 60.00 2.84 400.0 0.000637 0.00 5.9005 2.8598 0.6498 0.0000 60.00 3.13 450.1 0.000716 0.00 5.9158 3.0923 0.7026 0.0000 59.99 3.40 500.0 0.000796 0.00 5.9297 3.3016 0.7502 0.0000 59.98 3.64 600.0 0.000955 0.00 5.9584 3.7357 0.8488 0.0000 59.98 4.14 700.0 0.001115 0.01 5.9915 4.2474 0.9651 0.0000 59.98 4.72 750.0 0.001195 0.01 6.0085 4.5103 1.0249 0.0000 59.98 5.02 800.0 0.001275 0.01 6.0180 4.6443 1.0553 0.0000 59.99 5.18 900.0 0.001434 0.01 6.0518 5.1664 1.1739 0.0000 59.98 5.77 1000.0 0.001594 0.01 6.0792 5.5769 1.2672 0.0000 59.95 6.25 1199.9 0.001915 0.01 6.1233 6.2105 1.4112 0.0001 59.93 7.02 1400.0 0.002236 0.01 6.1767 7.0077 1.5923 0.0001 59.86 7.96 1600.0 0.002557 0.01 6.2225 7.6740 1.7437 0.0001 59.85 8.76 1799.9 0.002878 0.01 6.2608 8.2073 1.8649 0.0001 59.92 9.43 1900.0 0.003039 0.01 6.2785 8.4473 1.9194 0.0001 59.97 9.74 2000.0 0.003200 0.02 6.2962 8.6871 1.9739 0.0001 59.96 10.05 2200.0 0.003523 0.02 6.3239 9.0332 2.0525 0.0001 59.93 10.53 2400.0 0.003845 0.02 6.3539 9.4181 2.1400 0.0001 60.02 11.05 2600.0 0.004167 0.02 6.3819 9.7721 2.2204 0.0001 60.06 11.54 2800.0 0.004492 0.02 6.4045 10.0299 2.2790 0.0001 60.02 11.94 ----------------------------------------------------------------------------------------------------- Scan Ends 21:42:50 on 19 February 2020 by WR200774 Reference State 59.98°C ---------------------------------------------------------------------------------------------------- S E R I E S D A T A R E C O R D ---------------------------------------------------------------------------------------------------- System Type IGA Systems System Owner EPFL System Reference G200773 System Serial Number HALIGA241 Sample Number 0329 Experiment Type Sequence Experiment No 013 Title UiO-66-NH2 Prisma Comment Source Batch ID Experiment Title Isotherm_CO2_70deg S A M P L E S E T U P Sample Wet Weight 6.0206 mg Sample Dry Weight 5.7353 mg Sample Dry Mass 5.7353 mg Sample Weight Loss 4.97 %d.b. Balance Trim (V) 0.0024 cc Balance Trim (T) Cabinet Counterweight (M) 0.3062 g Counterweight (ρ) 7.886 g/cc Counterweight (T) Air Sample Container (M) 0.0895 g Sample Container (ρ) 7.886 g/cc Sample Container (T) Sample Tungsten (M) 0.0568 g Tungsten (ρ) 19.03976 g/cc Tungsten (T) Sample Chain Excess (M) 0.0719 g Chain Excess (ρ) 11.09856 g/cc Chain Excess (T) Air Interaction Type Adsorption Classification Not Specified Sample Geometry Not Specified Sample Dimension Not Specified Presorbed Not Specified Sample Molar Mass Not Specified Sample Skeletal Density Not Specified Absolute Adsorption Basis None Adsorbate Density Not Specified Micropore Volume Not Specified Dilation Not Specified A P P L I C A T I O N S E T U P Application Code 201510 Mode Vacuum Source Gas Cylinder Gas Source CO2 at supply pressure 5 barg Vessel CF-SW High Pressure Reactor Conflat SS316L Pressure Sensor(s) 20 bar Thermostat Water Bath CO2 EOS calculation Lookup Table CO2 SVP calculation NIST REFPROP v9.1 Source Data C:\HIsorp\G200773\Sample_0329\Sequence\Sequence013\Data.txt Operations Log C:\HIsorp\G200773\Sample_0329\Sequence\Sequence013\Operations Log.txt Method Log C:\HIsorp\G200773\Sample_0329\Sequence\Sequence013\Method Log.txt File created 14:43:30 on 02 March 2020 by WR200774 Issue Level Recalculation Not Issued Series Type Isothermal Series Data Delimiter Space Scan 1 Course Sorption Reference State Device Sample Scan Title Scan Commenced 11:42:51 on 01 March 2020 by WR200774 Pressure Gas p/p0 Total Excess Excess BET Sample %Wt Density Weight Adsorption Adsorption (mbar) (g/cc) (mg) (%) (mmol/g) (g/ml(stp)) (°C) (% d.b.) ----------------------------------------------------------------------------------------------------- -.4 0.000000 0.00 5.7353 -.0008 -.0002 0.0000 61.53 0.00 19.8 0.000031 0.00 5.7536 0.3056 0.0694 0.0000 70.00 0.32 39.8 0.000061 0.00 5.7628 0.4523 0.1028 0.0000 70.01 0.48 60.0 0.000093 0.00 5.7712 0.5851 0.1329 0.0000 69.99 0.63 79.7 0.000123 0.00 5.7791 0.7086 0.1610 0.0000 69.99 0.76 99.9 0.000154 0.00 5.7878 0.8471 0.1925 0.0000 70.02 0.92 149.8 0.000231 0.00 5.8070 1.1483 0.2609 0.0000 69.99 1.25 199.8 0.000309 0.00 5.8238 1.4075 0.3198 0.0000 69.99 1.54 250.3 0.000387 0.00 5.8407 1.6659 0.3785 0.0000 69.99 1.84 300.1 0.000464 0.00 5.8558 1.8953 0.4307 0.0000 69.98 2.10 349.3 0.000540 0.00 5.8708 2.1233 0.4825 0.0000 70.00 2.36 399.4 0.000617 0.00 5.8843 2.3260 0.5285 0.0000 70.00 2.60 449.9 0.000695 0.00 5.8964 2.5026 0.5686 0.0000 70.00 2.81 500.1 0.000773 0.00 5.9077 2.6644 0.6054 0.0000 69.97 3.01 600.0 0.000927 0.00 5.9350 3.0712 0.6978 0.0000 69.97 3.48 697.6 0.001078 0.00 5.9626 3.4860 0.7921 0.0000 69.96 3.96 748.0 0.001157 0.00 5.9818 3.7862 0.8603 0.0000 69.96 4.30 800.2 0.001237 0.01 5.9956 3.9912 0.9069 0.0000 69.98 4.54 900.2 0.001392 0.01 6.0220 4.3831 0.9959 0.0000 69.99 5.00 1000.1 0.001548 0.01 6.0420 4.6642 1.0598 0.0000 69.94 5.35 1198.2 0.001855 0.01 6.0861 5.2967 1.2035 0.0000 69.91 6.12 1399.1 0.002169 0.01 6.1316 5.9503 1.3520 0.0001 69.81 6.91 1596.8 0.002477 0.01 6.1796 6.6499 1.5110 0.0001 69.79 7.75 1800.3 0.002793 0.01 6.2075 6.9971 1.5899 0.0001 69.93 8.23 1895.8 0.002942 0.01 6.2318 7.3544 1.6711 0.0001 69.92 8.66 1996.5 0.003099 0.01 6.2411 7.4466 1.6920 0.0001 69.96 8.82 2196.0 0.003409 0.01 6.2584 7.6068 1.7284 0.0001 70.18 9.12 2400.0 0.003729 0.02 6.2883 7.9848 1.8143 0.0001 70.08 9.64 2600.2 0.004043 0.02 6.3158 8.3238 1.8913 0.0001 70.00 10.12 2796.3 0.004351 0.02 6.3463 8.7196 1.9813 0.0001 70.00 10.65 ----------------------------------------------------------------------------------------------------- Scan Ends 21:38:21 on 01 March 2020 by WR200774 Reference State 69.98°C