Table 4. Identified secondary metabolites in dual culture (barley-malt medium with Hymenoscyphus fraxineus) of the surveyed strains listed in Table 3. Identified compounds: 5: phomopsidin; 6: 10-hydroxyphomopsidin; 8: rickiol A; 9: orthosporin; 10: daldinone B; 11: 1,8-dimethoxynaphtahlene; 13: 5-methyl-mellein. Identified stromal azaphilone groups detected in culture: MI = Mitorubrin type; NA = Naphthalene type; DA = Daldinin type. For chemical structures, see Fig. 8.
Organism Strain Culture metabolites Stromal metabolites
5 6 Others MI NA
Hypoxylon cercidicola MUCL 54180 + - 13 - -
Hypoxylon fuscum STMA 13090 - - 11, 13 - +
Hypoxylon texense DSM 107933 - - - + -
Hypoxylon crocopeplum CBS 119004 - - - + -
Hypoxylon perforatum MUCL 47187 + - - + -
Hypoxylon petriniae MUCL 53756 + - - - -
Hypoxylon aff. rubiginosum MUCL 57724 + + - + -
Hypoxylon rubiginosum MUCL 47152 + - 9, 10 - +
Hypoxylon rubiginosum MUCL 47970 + - 9, 10 - +
Hypoxylon guilanense MUCL 57726 - - - - -
Hypoxylon carneum MUCL 54177 - - 10 - -