Published April 30, 2025 | Version CC-BY-NC-ND 4.0
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A Techno-Economic Feasibility Study: Carboxymethyl Cellulose Production from Date Palm Biomass for Industrial Applications

  • 1. Department of Downstream General Directorate, Refining and Petrochemical, Ministry of Energy and Petroleum, Khartoum, Sudan.
  • 1. Department of Downstream General Directorate, Refining and Petrochemical, Ministry of Energy and Petroleum, Khartoum, Sudan.
  • 2. Department of Petroleum Engineering, Sudan University of Science and Technology, Khartoum, Sudan.
  • 3. Associate Professor, Department of Chemical Engineering, Karry University, Khartoum, Sudan.
  • 4. Department of Refining and transportation, Sudan University of Science and Technology, Khartoum, Sudan.

Description

Abstract: This research focuses on a techno-economic process of building and designing equipment for isolating polymers from local resources for industrial purposes; the objective was to increase national revenues from the utilization of native resources and a reduction in the cost and foreign dependence on imported polymers. The study had an aim of synthesizing and characterizing CMC from leaves of Phoenix dactylifera L. (date palm) through the process of etherification using sodium monochloroacetic acid and sodium hydroxide. The optimization of parameters included a temperature of 55°C, and a total reaction time of 4 hrs., providing the highest degree of substitution (DS) at 0.77. Models of a material balance and heat generation were derived from the reactor's operational performance and were developed to determine the mechanical design of the reactor, the reactor volume calculated out to be 2435.26 dcm³, reactor capital cost, and the economic viability of the plant. Taking all equations into account, with equipment costs amounting to $103,823.5 and total capital investment of $233,311.24. The study analyzed five different priceevaluation-and-feasibility scenarios until it arrived at the conclusion that it had become economically feasible to produce approximately 3000 tons/year of sodium carboxymethyl cellulose with 4 batches per day/three-hundred-day operation year (plus 60 maintenance days) each. The given cost-and-profit analysis considered critical criteria such as raw-material cost, labor cost, selling price for the product, and process optimization. This highlighted the very encouraging financial effects the production of CMC propelled forward to an overall worth. Lastly, the review also dealt with issues of environmental compliance, regarding the manufacture of sodium carboxymethyl cellulose (CMC).

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Additional details

Identifiers

DOI
10.54105/ijac.A2029.05010425
EISSN
2582-8975

Dates

Accepted
2025-04-15
Manuscript received on 23 March 2025 | First Revised Manuscript received on 06 April 2025 | Second Revised Manuscript received on 09 April 2025 | Manuscript Accepted on 15 April 2025 | Manuscript published on 30 April 2025.

References

  • Food and Agriculture Organization of the United Nations -FAO. (2008) Database agricultural – Production – Crops primary – Coconut, July 20. Available from: http://faostat.fao.org.
  • Granström, M., (2009). Cellulose derivatives: synthesis, properties and applications, PhD thesis, University of Helsinki, Finland. ISBN 978- 952-10-5485-3 (PDF). https://core.ac.uk/download/pdf/14916693.pdf
  • Bono, A., P. H. Ying, F. Y. Yan, C. L. Muei, R. Sarbatly, and D. Krishnaiah. "Synthesis and characterization of carboxymethyl cellulose from palm kernel cake" . Advances in Natural and Applied Sciences. Vol. No. 3(1)(2009) PP:5-12, DOI: https://doi.org .10.1201/9780203508206.
  • Joshi, G., Naithani, S., Varshney, V.K., Bisht, S.S., Rana, V. and Gupta, P.K. "Synthesis and characterization of carboxymethyl cellulose from office waste paper" A greener approach towards waste management. Waste Management. Vol 38 (2015) PP:33-40. DOI: https://doi.org:10.1016/j.wasman.2014.11.015
  • Adinugraha, M. P. and Marseno, D. W. "Synthesis and characterization of sodium carboxymethylcellulose from Cavendish banana pseudo stem (Musa cavendishi LAMBERT)" Carbohydrate Polymers Journal. Vol. 62. (2005) PP:164-169. DOI: https://doi.org/10.1016/j.carbpol.2005.07.019
  • Toğrul, H. and Nurhan Arslan. "Production of carboxymethyl cellulose from sugar beet pulp cellulose and rheological behavior of carboxymethyl cellulose. Carbohydrate Polymers", Vol. 54(1)(2003) PP:73-82. DOI: https://doi.org/10.1016/S0144-8617(03)00147-4
  • ELrayah. A. I. Ahmed, M. Amani A, M. I. IBRAHIM and K. H. AHMED. (26-28 August 2020). Drilling Fluids Additive Sodium Carboxylmethyl Cellulose (CMC) Produced from Palm Frond. IPPTC Organization Committee, International Petroleum and Petrochemical Technology Conference, Shanghai China. https://www.researchgate.net/publication/350995499
  • Hattori, K., E. Abe, T. Yoshida and J. Cuculo.New 'solvents for Cellulose II ethylenediamine/thiocyanate salt system. Polymer" Vol. 36(2). (2004). PP:123-130. DOI: https://doi.org/10.1295/polymj.36.123
  • Eggeman, T. and R. T. Elander. "Process and economic analysis of pretreatment technologies. Bioresource Technology" Vol.96(2005.). PP:2019-2025. DOI: https://doi.org/10.1016/j.biortech.2005.01.017
  • Wafaa, M. Osman, Ahmed, A. Ibrahim, Abdullah, B. Karma, Amel, A.A. Nimir, "Design Process of CSTR for Production Carboxyl Methyl Cellulose" Published in International Research Journal of Innovations in Engineering and Technology - IRJIET, Volume 7, Issue 2, February 2023 pp 27-35, DOI: https://doi.org/10.47001/IRJIET/2023.702004
  • Mondal, M. I. H, Yeasmin, M. S. and Rahman, M. S., "Preparation of food grade carboxymethyl cellulose from corn husk agrowaste," International journal of biological macromolecules, (2015) pp.79, 144- 150: DOI: http://doi.org/10.1016/j.ijbiomac.2015.04.061.
  • G. P. Towler and R. K. Sinnott, 'Chemical Engineering Design: Principles, Practice, and Economics of Plant and Process Design' (2nd ed.) Waltham, MA; Oxford; Butterworth-Heinemann, 2013; Accessible from UBC library at https://core.ac.uk/download/pdf/143491361.pdf
  • Chan S Park. (2021). Fundamentals of Engineering Economics. fourth Edition, Published by Pearson NY, USA. Pearson NY, USA. https://mrce.in/ebooks/Engineering%20Economics%20Fundamentals% 204th%20Ed.pdf
  • Arora, J., Ramawat, K. G., & Mérillon, J. M. "Disposal of agricultural waste and its effects on the environment, production of useful metabolites and energy: Potential and challenges" In K. G. Ramawat, J. M. Mérillon, & J. Arora (Eds.), Agricultural waste: Environmental impact, useful metabolites and energy production (2023) pp. 3–20 Springer Nature Singapore. DOI: https://doi.org/10.1007/978-981-19- 8774-8
  • Joseph A. Shaeiwitz; Debangsu Bhattacharyya; Wallace B. Whiting; Richard C. Bailie; Richard Turton." Analysis, Synthesis and Design of Chemical Processes" fifth edition. [online][Accessed 11 June, 2020]. Prentice Hall.. Pearson Education, Inc., USA. https://ptgmedia.pearsoncmg.com/images/9780132618120/samplepage s/0132618125.pdf
  • Peter M. S, Timmermans D. K, West E. R."Plant Design and economic for chemical engineers" 5th Edition. McGraw-Hill, New York, NY, USA, (2003) PP:245-205, 536, 539 and 597. https://davuniversity.org/images/files/studymaterial/PLANT%20DESIGN%20AND%20ECONOMICS%20FOR% 20CHEMICAL%20ENGINEERS.pdf
  • Perry, Robert H., and Chilton, Cecil H. (1999) Chemical Engineers' Handbook. Fifth Edition. PP:55 -390. McGraw-Hill, New York, USA. https://students.aiu.edu/submissions/profiles/resources/onlineBo ok/z5y2E6_Perry-s_Chemical_Engineers-_Handbook.pdf
  • Palani, S., Jambulingam, R., Mohanam, A., & Srinivasan, G. R. (2020). Synthesis and Characterisation of Carboxymethyl Cellulose Based Bentonite Polymer Blend. In International Journal of Recent Technology and Engineering (IJRTE) (Vol. 8, Issue 5, pp. 5661–5664). DOI: https://doi.org/10.35940/ijrte.e6772.018520
  • E.P, G., A.P, G., E.V., R., N.S, A., Z.V., S., & I.E., M. (2019). Development Practice of Production Systems — Systems of Product Creation in Domestic Production (On the Example of Reference Areas). In International Journal of Innovative Technology and Exploring Engineering (Vol. 9, Issue 1, pp. 3398–3401). DOI: https://doi.org/10.35940/ijitee.a4354.119119
  • Naik, O., Jaiswal, S., Bhuyar, Dr. K., & Kodape, Dr. S. (2023). Green Hydrogen Production as a Sustainable Initiative for Alternative Energy Source: A Review. In International Journal of Basic Sciences and Applied Computing (Vol. 9, Issue 10, pp. 1–5). DOI: https://doi.org/10.35940/ijbsac.i0503.0691023
  • Reddy, P., Reddy, K., Durisety, H., & Pydimalla, Dr. M. (2020). Optimization of Base Catalysts for Biodiesel Production from Jatropha curcas oil. In International Journal of Innovative Science and Modern Engineering (Vol. 6, Issue 7, pp. 8–14). DOI: https://doi.org/10.35940/ijisme.g1237.056720