GRAPHERGIA Scientific Publication: X-ray photoelectron spectroscopy analysis of electrospun polyacrylonitrile fibers

The GRAPHERGIA project has released a new scientific publication, led by the coordination team at Foundation for Research and Technology Hellas (FORTH) – Institute of Chemical Engineering Sciences, a scientific journal.  This scientific article, entitled "X-ray photoelectron spectroscopy analysis of electrospun polyacrylonitrile fibres: Pre- and post-thermal stabilisation investigations”, was published in Surface Science Spectra Journal, Special Collection: Materials for Energy and the Environment (Volume 31, Issue 2 December 2024). 

GRAPHERGIA’s Scientific Paper Abstract

Polyacrylonitrile (PAN) is a hard, rigid, thermoplastic substance with various applications, including carbon fiber production for the aerospace and automotive sectors, textile manufacturing, and water and air filtration. Its usage as a synthetic resin is particularly notable in its stabilized form. Stabilization ensures thermal stability during graphitization by transforming the structure from linear to lateral, resulting in an aromatic ladder. In this study, an 8% w/w polyacrylonitrile solution in N,N-dimethylformamide is electrospun and subsequently stabilized by heating up to 280 °C. The electrospun sample (pristine material) and its stabilized form at 280°C in air were analyzed using x-ray photoelectron spectroscopy (XPS) at room temperature with a nonmonochromatic Mg Kα x-ray source.