The folder contains the data for each spectrum reported in the figures of the manuscript and the Supporting Information.

Main manuscript:

The files for Figure 5 contains data of:
(1) XRD shown in iteration 1-2
(2) XRD shown in iteration 3
(3) XRD shown in iteration 4
(4) XRD shown in iteration 5
(5) XRD shown in iteration 6
(6) XRD shown in iteration 7-8
(7) XRD shown in iteration 9

The files for Figure 6 contains data of:
(1) XRD of RD Cu NCs (Figure 6e)
(2) 31P{1H} NMR of a solution containing CuI and TOP in OLAM (green in Figure 6g)
(3) 31P{1H} NMR of the TOP reference (purple in Figure 6g)


Supporting Information:

The files for Figure S2 contains data of:
(1) 31P{1H} NMR of a solution containing CuBr and TOP in OLAM (Figure S2A)
(2) For the 31P{1H} NMR of the TOP reference (Figure S2A), see the file in Figure 6g  
(3) 31P{1H} NMR of a solution containing CuBr and TMP in OLAM (Figure S2B)
(4) 31P{1H} NMR of the TMP reference (Figure S2B)

The file for Figure S5 contains data of:
(1) 31P{1H} NMR of a solution containing CuCl, CuBr, TOP and TMP in OLAM (Figure S5)
(2) For the 31P{1H} NMR of the TOP reference, see the file in Figure 6g
(3) For the 31P{1H} NMR of the TMP reference, see the file in Figure S2

The file for Figure S6 contains data of:
(1) For the XRD, see the file in Figure 5 for iteration 3

The file for Figure S7 contains data of:
(1) For the XRD, see the file in Figure 5 for iteration 6

The file for Figure S10 contains data of:
(1) The size statistics of the Cu RD NCs (Figure S10)

The files for Figure S11 contains data of:
(1) For the XRD of the Cu RDs NCs, see the file in Figure 6e
(2) XRD of Cu cubes (Figure S11B)
(3) XRD of Cu octahedra (Figure S11B)