Raw data S2p3 1T S2p1 1T S2p3 2H S2p1 2H S2p3 S-C S2p1 S-C Fitting data Binding Energy (eV) Intensity (a.u.) Intensity (a.u.) Intensity (a.u.) Intensity (a.u.) Intensity (a.u.) Intensity (a.u.) Intensity (a.u.) Intensity (a.u.) 174.78 231.2 0 0 0 0 0 0 0 174.68 -265 0 0 0 0 0 0 0 174.58 46.5 0 0 0 0 0 0 0 174.48 392.9 0 0 0 0 0 0 0 174.38 66.6 0 0 0 0 0 0 0 174.28 -216.3 0 0 0 0 0 0 0 174.18 -31.4 0 0 0 0 0 0 0 174.08 101.4 0 0 0 0 0 0 0 173.98 64.4 0 0 0 0 0 0 0 173.88 485.6 0 0 0 0 0 0 0 173.78 49.5 0 0 0 0 0 0 0 173.68 -211.5 0 0 0 0 0 0 0 173.58 -100.6 0 0 0 0 0 0 0 173.48 -43.9 0 0 0 0 0 0 0 173.38 298 0 0 0 0 0 0 0 173.28 298.1 0 0 0 0 0 0 0 173.18 158.6 0 0 0 0 0 0 0 173.08 250.6 0 0 0 0 0 0 0 172.98 -35.5 0 0 0 0 0 0 0 172.88 300.5 0 0 0 0 0 0 0 172.78 377.9 0 0 0 0 0 0 0 172.68 265.5 0 0 0 0 0 0 0 172.58 303.6 0 0 0 0 0 0 0 172.48 245.7 0 0 0 0 0 0 0 172.38 219.3 0 0 0 0 0 0 0 172.28 301.1 0 0 0 0 0 0 0 172.18 606 0 0 0 0 0 0 0 172.08 316.7 0 0 0 0 0 0 0 171.98 437.2 0 0 0 0 0 0 0 171.88 423.9 0 0 0 0 0 0 0 171.78 260.1 0 0 0 0 0 0 0 171.68 288.6 0 0 0 0 0 0 0 171.58 382.3 0 0 0 0 0 0 0 171.48 451 0 0 0 0 0 0 0 171.38 214.4 0 0 0 0 0 0 0 171.28 249.5 0 0 0 0 0 0 0 171.18 514.3 0 0 0 0 0 0 0 171.08 623.8 0 0 0 0 0 0 0 170.98 407.3 0 0 0 0 0 0 0 170.88 290.6 0 0 0 0 0 0 0 170.78 405.3 0 0 0 0 0 0 0 170.68 388.4 0 0 0 0 0 0 0 170.58 497.6 0 0 0 0 0 0 0 170.48 240.1 0 0 0 0 0 0 0 170.38 403.9 0 0 0 0 0 0 0 170.28 240.3 0 0 0 0 0 0 0 170.18 469.6 0 0 0 0 0 0 0 170.08 469.7 0 0 0 0 0 0 0 169.98 321.9 0 0 0 0 0 0 0 169.88 188.7 0 0 0 0 0 0 0 169.78 371.8 0 0 0 0 0 0 0 169.68 613 0 0 0 0 0 0 0 169.58 713.8 0 0 0 0 0 0 0 169.48 315.7 0 0 0 0 0 0 0 169.38 734.5 0 0 0 0 0 0 0 169.28 318.7 0 0 0 0 0 0 0 169.18 58 0 0 0 0 0 0 0 169.08 527 0 0 0 0 0 0 0 168.98 315.1 0 0 0 0 0 0 0 168.88 19.7 0 0 0 0 0 0 0 168.78 595.3 0 0 0 0 0 0 0 168.68 555.6 0 0 0 0 0 0 0 168.58 477.9 0 0 0 0 0 0 0 168.48 789.4 0 0 0 0 0 0 0 168.38 437.1 0 0 0 0 0 0 0 168.28 96.7 0 0 0 0 0 0 0 168.18 346.9 0 0 0 0 0 0 0 168.08 501.7 0 0 0 0 0 0 0 167.98 332 0 0 0 0 0 0 0 167.88 304.9 0 0 0 0 0 0 0 167.78 334.3 0 0 0 0 0 0 0 167.68 66.9 0 0 0 0 0 0 0 167.58 -168.1 0 0 0 0 0 0 0 167.48 95.6 0 0 0 0 0 0 0 167.38 -276.3 0 0 0 0 0 0 0 167.28 281.2 0 0 0 0 0 0 0 167.18 113.8 0 0 0 0 0 0 0 167.08 148.7 0 0 0 0 0 0 0 166.98 464.2 0 0 0 0 0 0 0 166.88 54.2 0 0 0 0 0 0 0 166.78 -156.7 0 0.1 0 0 0 0.1 0.1 166.68 358.6 0 0 0 0 0 0.1 0.1 166.58 440.5 0 0 0 0 0 0.1 0.1 166.48 321.7 0 0.1 0 0 0 0.3 0.4 166.38 333 0 0 0 0 0 0.7 0.8 166.28 336.7 0 0.2 0 0 0 1.9 2.1 166.18 402.7 0 0.4 0 0 0 4.3 4.7 166.08 665.2 0 1 0 0.1 0 9.5 10.5 165.98 903 0 2.1 0 0 0 19.9 22.1 165.88 786.9 0 4.7 0 0.1 0 40.3 45.2 165.78 1088 0 10.2 0 0.3 0 77.9 88.4 165.68 1108.4 0 21 0 0.5 0 143.9 165.4 165.58 1225.1 0 41.8 0 1 0 254 296.7 165.48 1556.1 0 80.2 0 1.9 0.1 427.5 509.5 165.38 1843 0 148.7 0 3.4 0.1 685.2 837.5 165.28 2506.5 0 266.2 0 6.3 0.4 1043.8 1316.7 165.18 3113.4 0.1 459.9 0 11.3 1.1 1505.5 1977.7 165.08 3533.6 0.1 766.2 0 19.8 2.6 2047.6 2836.4 164.98 4507.7 0.3 1230.4 0 34.3 6.2 2613.5 3884.7 164.88 5735.3 0.9 1902.2 0.1 58.1 13.9 3114 5089 164.78 6761.6 2 2826.8 0.1 96.4 29.7 3448 6402.8 164.68 8560.8 4.5 4029.5 0.1 157 61 3536.6 7788.7 164.58 10302.1 9.9 5496.1 0.3 250.7 119.8 3357.8 9234.4 164.48 11507.4 20.8 7150.1 0.5 392.4 225 2955.7 10744.6 164.38 13262.1 42.3 8841.2 1.1 602.2 404 2421.3 12312.2 164.28 14008.4 83.2 10353.3 2.2 905.8 692.2 1855 13891.7 164.18 15461.5 157.9 11444.1 4 1335.1 1130.4 1335.9 15407.6 164.08 16934.2 289.3 11912.3 7.6 1927.8 1755.9 908.6 16801.5 163.98 17942.1 511.6 11664.4 13.8 2725.7 2586.1 585.9 18087.5 163.88 19276.2 873 10750.4 24.8 3771.8 3597.7 359.3 19377 163.78 20568 1436.4 9344.4 43.5 5105 4705.5 210 20844.7 163.68 22595.6 2276.9 7683.6 74.7 6752.2 5756.5 117.1 22661.3 163.58 24341.9 3473.3 5998.3 126.1 8719.6 6554.6 62.4 24934.4 163.48 26640.6 5089.4 4461.6 208.7 10980.4 6920.3 31.8 27692.5 163.38 30454.3 7148.2 3172.4 338.6 13466.3 6763.2 15.6 30904.1 163.28 33938.9 9596.1 2162.2 538.4 16059.8 6122.6 7.3 34486.3 163.18 38206.9 12272.9 1415.7 839.4 18596.4 5149.9 3.2 38277.7 163.08 41159.2 14900.5 892 1283 20876.5 4043.4 1.4 41996.6 162.98 45358.8 17111.8 541.5 1921.8 22689.3 2978.4 0.5 45243.5 162.88 47352.5 18532.1 317 2820.9 23847.7 2068.6 0.2 47586.6 162.78 49112 18889.8 179.1 4056 24222.7 1360.4 0.1 48708 162.68 48901.6 18113 97.6 5710 23770.9 849.8 0 48541.5 162.58 47379.7 16356.2 51.4 7866.4 22544.6 505.6 0 47324.3 162.48 45587.5 13943 26.1 10598 20679.3 287 0 45533.5 162.38 43621.7 11257.5 12.8 13951 18366.3 155.6 0 43743.2 162.28 42686.6 8640.1 6.1 17925.7 15816.3 80.7 0 42468.7 162.18 41771.6 6325.6 2.8 22455 13226.5 40 0 42049.9 162.08 42632.8 4431.5 1.3 27386.1 10757.6 19 0 42595.3 161.98 44165.6 2978.4 0.6 32469.5 8522 8.6 0 43978.9 161.88 46174.4 1924.1 0.2 37366.5 6584.1 3.7 0 45878.7 161.78 49399.1 1196.9 0.1 41677.2 4967 1.6 0 47842.6 161.68 50110.2 717.5 0 44992.9 3662.1 0.6 0 49373.1 161.58 50026.2 414.8 0 46964.6 2641 0.2 0 50020.7 161.48 50382.3 231.5 0 47370.7 1864.2 0.1 0 49466.5 161.38 47317 124.7 0 46164.3 1288.6 0 0 47577.6 161.28 43044.3 64.9 0 43483.4 872.6 0 0 44420.9 161.18 38894.1 32.6 0 39621.2 579 0 0 40232.8 161.08 34729.7 15.8 0 34965.3 376.6 0 0 35357.7 160.98 29726.8 7.4 0 29928 240.1 0 0 30175.5 160.88 25626.8 3.4 0 24883.7 150.1 0 0 25037.1 160.78 21339.5 1.4 0 20128.3 92 0 0 20221.8 160.68 17493.9 0.6 0 15862.9 55.3 0 0 15918.8 160.58 13826.6 0.3 0 12195.5 32.6 0 0 12228.3 160.48 10971.2 0.1 0 9156.6 18.8 0 0 9175.5 160.38 8676.2 0.1 0 6720.5 10.7 0 0 6731.2 160.28 7038 0 0 4825.3 5.9 0 0 4831.2 160.18 5076.2 0 0 3391.4 3.2 0 0 3394.6 160.08 3967.4 0 0 2334.4 1.7 0 0 2336.1 159.98 2721.8 0 0 1574.2 0.9 0 0 1575.1 159.88 2513.3 0 0 1040.4 0.5 0 0 1040.8 159.78 1949.4 0 0 674 0.3 0 0 674.2 159.68 1748.1 0 0 428 0.1 0 0 428.1 159.58 1510 0 0 266.4 0.1 0 0 266.5 159.48 835.2 0 0 162.6 0 0 0 162.7 159.38 741.4 0 0 97.4 0 0 0 97.4 159.28 669 0 0 57.1 0 0 0 57.1 159.18 627.4 0 0 32.9 0 0 0 32.9 159.08 576.2 0 0 18.6 0.1 0 0 18.6 158.98 511.1 0 0 10.3 0 0 0 10.3 158.88 452.1 0 0 5.6 0 0 0 5.6 158.78 197.6 0 0 2.9 0 0 0 2.9 158.68 179.6 0 0 1.5 0 0 0 1.5 158.58 376.9 0 0 0.7 0 0 0 0.7 158.48 483.8 0 0 0.4 0 0 0 0.4 158.38 435.7 0 0 0.2 0 0 0 0.2 158.28 84.8 0 0 0.1 0 0 0 0.1 158.18 212.5 0 0 0 0 0 0 0 158.08 313.2 0 0 0.1 0 0 0 0.1 157.98 151.1 0 0 0 0 0 0 0 157.88 171.9 0 0 0 0 0 0 0 157.78 -205.1 0 0 0 0 0 0 0 157.68 -72.6 0 0 0 0 0 0 0 157.58 213.7 0 0 0 0 0 0 0 157.48 6.8 0 0 0 0 0 0 0 157.38 41.8 0 0 0 0 0 0 0 157.28 243.2 0 0 0 0 0 0 0 157.18 -7.4 0 0 0 0 0 0 0 157.08 -132.6 0 0 0 0 0 0 0 156.98 -7.7 0 0 0 0 0 0 0 156.88 156.9 0 0 0 0 0 0 0 156.78 -70.4 0 0 0 0 0 0 0