Active Robots Ltd) a small PV panel, nominal 6V/200mW, Voc~8V, 37mmx66mm polycrystalline (part SCC3766-MSE). I shall connect it to the batteries via a diode and a 470Ω resistor (to limit maximum charge current in bright sunlight to about 6mA or a 0.0033C trickle charge limit as suggested on Wikipedia). Inside, even mid-day, I cannot expect energy capture above ~1% of nominal, so in particular I'll use a low-leakage diode to minimise drain from the battery back to the panel. Given a lamp draw ~1mW and the PV output possibly similar for maybe 8h/day each, with the PV output improved if we can pop the box on a window-ledge when the light gets too dim at night, this might just work, else I can upgrade to the relatively-huge 1W PV!
Update 2011-09-25: as a further cheat/enhancement I'm swapping the ordinary NiHM cells for 'hybrid' versions of similar capacity that should have lower leakage, ie self-discharge, and thus eke out some extra life in winter. The new cells are 2100mAh nominal compared to the 2500mAh of the previous ones.
Update 2011-10-17: Voc of the solar cell/PV in the sort of lighting I'm anticipating is ~2.5V compared to the battery still over 5V, so to get any useful charging I suspect that I'll have to buy a second panel and put it in series.
Update 2012-02-10: Battery still reading 5.00V!
Update 2012-06-12: when I notice direct sunshine falling on come convenient surface, eg in one of the bedrooms, I put the nightlight there to help it charge. Still no manual charge has been required since December (ie 6 months so far).
Update 2012-09-25: battery voltage down to ~4.2V in spite of occasionally being put in full sun (inside, eg on a window-ledge) to charge a little, tested because the light seemed a little on the dim side last night, so batteries being given a manual (fast) charge from off-grid solar PV. ~2h recharging every 9 months is not too bad, but I may used a bigger internal solar panel to make the nightlight nearer self-sufficient.
Update 2013-06-24: battery reading 2.84V (!) though still glimmering faintly at night; getting recharged from off-grid solar system today.
Update 2013-11-19: snuck in battery recharge from off-grid solar system today, as was sunny.
Update 2014-08-29: battery reading 3.48V, so recharging from off-grid system while light outside! My fast charger seems a little fierce and the battery is reading over 9V after.
Update 2015-07-21: fast (<1h I think) charge from off-grid supply as light very dim. One cell finished charging well before the others, so may be failing.
Update 2016-09-14: (battery voltage 3.22V) fast (<1h I think) charge from off-grid supply as light very dim. Charger initially drawing ~16W for the 4xAA NiMH hybrids. One cell finished charging well before the others, so has been swapped out for another cell of exactly the same type (ie Maplin NiMH hybrid 2100mAh). Hot out of the fast charger at 5.56V, balanced 2.78V between each pair.
Update 2017-05-20: (battery voltage 3.45V) fast charge from off-grid supply as light very dim. Charger initially drawing ~18W for the 4xAA NiMH hybrids. 5.6V after charge.
Update 2018-02-28: fast charge from off-grid supply as light very dim.
Update 2019-01-22: fast charge from off-grid supply as light very dim.
Update 2020-05-15: fast charge from off-grid supply because I can, and as a maintenance charge. Two cells showing as 'bad' in the fast charger; some jiggery was needed to get past this, but cells likely well out of balance.
Update 2021-03-20: fast charge from off-grid supply, on a roll from having recharged bucket full of other AAs yesterday!
Update 2022-01-17: light very dim, on a nice sunny day, but an attempted fast charge from the off-grid supply had the fast charger rejecting 3 of the 4 cells as bad! So I started the 'bad' ones on a slow charge to see if that recovered them to where the fast charger would be happy to do its thing... The cells have done ~10 years so if I have to replace them then not too bad.
After some TLC all the cells are now apparently fully charged (though I suspect that some are fairly weak), and the night light is back in place and bright again.
Update 2023-10-28: The 'hybrid' NiMH AA cells are probably getting weak, given age and misuse! While swapping them for others I broke one connection to the PV panel, so will need to careful re-solder.
I have recharged all four of the AAs, with a short slow 'non-smart' charge, then in the fast charger. The fast charger initially marked them as 'bad'.
(Given that this is the last winter our daughter may be home, since university beckons next year, this device probably can be said to have surpassed its original goal!)
Update 2024-10-22: the 'hybrid' Maplin NiMH cells that I was using seem to have gone 'bad', which seems acceptable after well over a decade. They are being recycled!