EPRO Position Chemical shift H Chemical shift Couplings... C-1 84.6963 H-1 5.0441 J(H-1,H-2) = 9.8834 C-2 74.8374 H-2 3.4789 J(H-2,H-1) = 9.8834 J(H-2,H-3) = 8.9436 C-3 79.8768 H-3 3.5632 J(H-3,H-2) = 8.9436 J(H-3,H-4) = 9.2048 C-4 71.9803 H-4 3.4666 J(H-4,H-3) = 9.2048 J(H-4,H-5) = 9.9691 C-5 83.0656 H-5 3.5598 J(H-5,H-4) = 9.9691 J(H-5,H-6S) = 2.2173 J(H-5,H-6R) = 6.0355 C-6 63.5311 H-6R 3.7172 J(H-6R,H-5) = 6.0355 J(H-6R,H-6S) = -12.6413 H-6S 3.914 J(H-6S,H-5) = 2.2173 J(H-6S,H-6R) = -12.6413 C-7 163.2257 C-8 42.2438 H-8R 2.9331 J(H-8R,H-8S) = -15.3738 J(H-8R,H-17) = 8.157 H-8S 2.9642 J(H-8S,H-8R) = -15.3738 J(H-8S,H-17) = 4.9943 N-10 349.308 C-17 72.6871 H-17 4.6563 J(H-17,H-8S) = 4.9943 J(H-17,H-8R) = 8.157 J(H-17,H-18) = 6.223 J(H-17,H-19Z) = -1.3472 J(H-17,H-19E) = -1.178 C-18 141.1179 H-18 5.978 J(H-18,H-17) = 6.223 J(H-18,H-19Z) = 17.2323 J(H-18,H-19E) = 10.5224 C-19 119.2433 H-19Z 5.3635 J(H-19Z,H-17) = -1.3472 J(H-19Z,H-18) = 17.2323 J(H-19Z,H-19E) = 1.2303 H-19E 5.2564 J(H-19E,H-17) = -1.178 J(H-19E,H-18) = 10.5224 J(H-19E,H-19Z) = 1.2303 DS-EPRO Position Chemical shift H Chemical shift Couplings... C-1 84.5091 H-1 5.0024 J(H-1,H-2) = 9.8496 C-2 75.1031 H-2 3.4553 J(H-2,H-1) = 9.8496 J(H-2,H-3) = 8.9452 C-3 79.9752 H-3 3.5559 J(H-3,H-2) = 8.9452 J(H-3,H-4) = 9.2143 C-4 72.0607 H-4 3.4592 J(H-4,H-3) = 9.2143 J(H-4,H-5) = 9.9255 C-5 83.01 H-5 3.5423 J(H-5,H-4) = 9.9255 J(H-5,H-6S) = 2.1868 J(H-5,H-6R) = 6.0028 C-6 63.5712 H-6R 3.7123 J(H-6R,H-5) = 6.0028 J(H-6R,H-6S) = -12.5803 H-6S 3.9048 J(H-6S,H-5) = 2.1868 J(H-6S,H-6R) = -12.5803 C-7 155.0699 C-8 41.9957 H-8R 2.8153 J(H-8R,H-8S) = -15.0406 J(H-8R,H-17) = 9.0492 H-8S 2.8203 J(H-8S,H-8R) = -15.0406 J(H-8S,H-17) = 4.2486 N-10 342.236 C-17 73.1145 H-17 4.5678 J(H-17,H-8S) = 4.2486 J(H-17,H-8R) = 9.0492 J(H-17,H-18) = 6.3578 J(H-17,H-19Z) = -1.2541 J(H-17,H-19E) = -1.1028 C-18 141.365 H-18 5.9366 J(H-18,H-17) = 6.3578 J(H-18,H-19Z) = 17.2312 J(H-18,H-19E) = 10.5284 C-19 119.1602 H-19Z 5.3278 J(H-19Z,H-17) = -1.2541 J(H-19Z,H-18) = 17.2312 J(H-19Z,H-19E) = 1.3197 H-19E 5.2332 J(H-19E,H-17) = -1.1028 J(H-19E,H-18) = 10.5284 J(H-19E,H-19Z) = 1.3197 GBB Position Chemical shift H Chemical shift Couplings... C-1 84.5599 H-1 4.8094 J(H-1,H-2) = 6.7584 C-2 74.7319 H-2 3.4396 J(H-2,H-1) = 6.7584 J(H-2,H-3) = 10.1756 C-3 79.8638 H-3 3.4752 J(H-3,H-2) = 10.1756 J(H-3,H-4) = 9.2251 C-4 71.9524 H-4 3.4396 J(H-4,H-3) = 9.2251 J(H-4,H-5) = 10.7587 C-5 83.1353 H-5 3.4402 J(H-5,H-4) = 10.7587 J(H-5,H-6S) = 2.2159 J(H-5,H-6R) = 5.6974 C-6 63.5001 H-6R 3.6894 J(H-6R,H-5) = 5.6974 J(H-6R,H-6S) = -12.6318 H-6S 3.8789 J(H-6S,H-5) = 2.2159 J(H-6S,H-6R) = -12.6318 C-7 163.0537 C-8 44.1367 H-8R 3.1119 J(H-8R,H-8S) = -15.5139 J(H-8R,H-17) = 5.2577 H-8S 3.243 J(H-8S,H-8R) = -15.5139 J(H-8S,H-17) = 8.0978 N-10 350.032 C-17 74.0036 H-17 5.2447 J(H-17,H-8S) = 8.0978 J(H-17,H-8R) = 5.2577 J(H-17,H-21) = -0.2148 C-18 145.0033 C-19 128.9806 H-19 7.4837 J(H-19,H-20) = 7.7137 J(H-19,H-21) = 1.3414 J(H-19,H-22) = 0.6111 J(H-19,H-23) = 2.0438 C-20 131.7834 H-20 7.4686 J(H-20,H-19) = 7.7137 J(H-20,H-21) = 7.3573 J(H-20,H-22) = 1.3554 J(H-20,H-23) = 0.6111 C-21 131.2991 H-21 7.4113 J(H-21,H-17) = -0.2148 J(H-21,H-19) = 1.3414 J(H-21,H-20) = 7.3573 J(H-21,H-22) = 7.3573 J(H-21,H-23) = 1.3414 C-22 131.7834 H-22 7.4686 J(H-22,H-19) = 0.6111 J(H-22,H-20) = 1.3554 J(H-22,H-21) = 7.3573 J(H-22,H-23) = 7.7137 C-23 128.9806 H-23 7.4837 J(H-23,H-19) = 2.0438 J(H-23,H-20) = 0.6111 J(H-23,H-21) = 1.3414 J(H-23,H-22) = 7.7137 DS-GBB Position Chemical shift H Chemical shift Couplings... C-1 84.4533 H-1 4.8219 J(H-1,H-2) = 9.8446 C-2 74.9887 H-2 3.4319 J(H-2,H-1) = 9.8446 J(H-2,H-3) = 8.9631 C-3 79.9522 H-3 3.4957 J(H-3,H-2) = 8.9631 J(H-3,H-4) = 9.0299 C-4 71.999 H-4 3.4482 J(H-4,H-3) = 9.0299 J(H-4,H-5) = 9.946 C-5 83.0414 H-5 3.4621 J(H-5,H-4) = 9.946 J(H-5,H-6S) = 2.0301 J(H-5,H-6R) = 5.6274 C-6 63.5081 H-6R 3.7001 J(H-6R,H-5) = 5.6274 J(H-6R,H-6S) = -12.5793 H-6S 3.8844 J(H-6S,H-5) = 2.0301 J(H-6S,H-6R) = -12.5793 C-7 154.881 C-8 43.918 H-8R 2.9677 J(H-8R,H-8S) = -15.1482 J(H-8R,H-17) = 5.9631 H-8S 3.1219 J(H-8S,H-8R) = -15.1482 J(H-8S,H-17) = 7.5691 N-10 343.2 C-17 74.4152 H-17 5.1624 J(H-17,H-8S) = 7.5691 J(H-17,H-8R) = 5.9631 C-18 145.124 C-19 128.9742 H-19 7.4464 J(H-19,H-20) = 7.7421 J(H-19,H-21) = 1.0729 J(H-19,H-22) = 0.7578 J(H-19,H-23) = 1.8663 C-20 131.6972 H-20 7.4584 J(H-20,H-19) = 7.7421 J(H-20,H-21) = 7.7035 J(H-20,H-22) = 1.2731 J(H-20,H-23) = 0.7578 C-21 131.1984 H-21 7.4032 J(H-21,H-19) = 1.0729 J(H-21,H-20) = 7.7035 J(H-21,H-22) = 7.7035 J(H-21,H-23) = 1.0729 C-22 131.6972 H-22 7.4584 J(H-22,H-19) = 0.7578 J(H-22,H-20) = 1.2731 J(H-22,H-21) = 7.7035 J(H-22,H-23) = 7.7421 C-23 128.9742 H-23 7.4464 J(H-23,H-19) = 1.8663 J(H-23,H-20) = 0.7578 J(H-23,H-21) = 1.0729 J(H-23,H-22) = 7.7421 DS-GCL Position Chemical shift H Chemical shift Couplings... C-1 84.7668 H-1 5.2612 J(H-1,H-2) = 9.912 C-2 75.1084 H-2 3.4446 J(H-2,H-1) = 9.912 J(H-2,H-3) = 8.977 C-3 79.9884 H-3 3.5548 J(H-3,H-2) = 8.977 J(H-3,H-4) = 9.1837 C-4 72.1261 H-4 3.4533 J(H-4,H-3) = 9.1837 J(H-4,H-5) = 9.9412 C-5 82.9642 H-5 3.5419 J(H-5,H-4) = 9.9412 J(H-5,H-6S) = 2.188 J(H-5,H-6R) = 6.0106 C-6 63.5225 H-6R 3.7072 J(H-6R,H-5) = 6.0106 J(H-6R,H-6S) = -12.5978 H-6S 3.9084 J(H-6S,H-5) = 2.188 J(H-6S,H-6R) = -12.5978 C-7 155.923 C-8 44.7523 H-8R 2.6655 J(H-8R,H-8S) = -15.2594 H-8S 2.83 J(H-8S,H-8R) = -15.2594 N-10 343.26 C-17 76.2157 C-18 37.3807 H-18R 1.6388 J(H-18R,H-18S) = -13.9263 J(H-18R,H-19) = 7.4289 H-18S 1.6242 J(H-18S,H-18R) = -13.9263 J(H-18S,H-19) = 7.5858 C-19 10.3585 H-19 0.9381 J(H-19,H-18S) = 7.5858 J(H-19,H-18R) = 7.4289 C-20 27.5485 H-20 1.2421 GER Position Chemical shift H Chemical shift Couplings... C-1 84.7308 H-1 5.0631 J(H-1,H-2) = 9.9024 C-2 74.886 H-2 3.4649 J(H-2,H-1) = 9.9024 J(H-2,H-3) = 8.9435 C-3 79.9919 H-3 3.5721 J(H-3,H-2) = 8.9435 J(H-3,H-4) = 9.2058 C-4 72.0727 H-4 3.4734 J(H-4,H-3) = 9.2058 J(H-4,H-5) = 9.9469 C-5 83.0913 H-5 3.5821 J(H-5,H-4) = 9.9469 J(H-5,H-6S) = 2.2386 J(H-5,H-6R) = 5.8203 C-6 63.5812 H-6R 3.721 J(H-6R,H-5) = 5.8203 J(H-6R,H-6S) = -12.6141 H-6S 3.9077 J(H-6S,H-5) = 2.2386 J(H-6S,H-6R) = -12.6141 C-7 167.3351 C-8 34.59 H-8R 2.7522 J(H-8R,H-8S) = -15.7577 J(H-8R,H-17R) = 8.9934 J(H-8R,H-17S) = 5.9266 H-8S 2.7522 J(H-8S,H-8R) = -15.7577 J(H-8S,H-17R) = 6.1395 J(H-8S,H-17S) = 9.1683 N-10 345.581 C-17 28.6469 H-17R 1.8297 J(H-17R,H-8S) = 6.1395 J(H-17R,H-8R) = 8.9934 J(H-17R,H-17S) = -12.2374 J(H-17R,H-18S) = 11.8729 J(H-17R,H-18R) = 2.7275 H-17S 1.8153 J(H-17S,H-8S) = 9.1683 J(H-17S,H-8R) = 5.9266 J(H-17S,H-17R) = -12.2374 J(H-17S,H-18S) = 7.4241 J(H-17S,H-18R) = 8.7904 C-18 30.1943 H-18R 1.725 J(H-18R,H-17R) = 2.7275 J(H-18R,H-17S) = 8.7904 J(H-18R,H-18S) = -12.4219 J(H-18R,H-19R) = 7.3033 J(H-18R,H-19S) = 6.1088 H-18S 1.725 J(H-18S,H-17R) = 11.8729 J(H-18S,H-17S) = 7.4241 J(H-18S,H-18R) = -12.4219 J(H-18S,H-19R) = 7.1637 J(H-18S,H-19S) = 8.3911 C-19 35.5165 H-19R 2.6068 J(H-19R,H-18S) = 7.1637 J(H-19R,H-18R) = 7.3033 J(H-19R,H-19S) = -21.1761 H-19S 2.6008 J(H-19S,H-18S) = 8.3911 J(H-19S,H-18R) = 6.1088 J(H-19S,H-19R) = -21.1761 C-21 16.9564 H-21 2.1119 DS-GER Position Chemical shift H Chemical shift Couplings... C-1 84.3207 H-1 5.0239 J(H-1,H-2) = 9.8866 C-2 75.0172 H-2 3.446 J(H-2,H-1) = 9.8866 J(H-2,H-3) = 8.9473 C-3 79.965 H-3 3.5669 J(H-3,H-2) = 8.9473 J(H-3,H-4) = 9.1993 C-4 72.0216 H-4 3.4689 J(H-4,H-3) = 9.1993 J(H-4,H-5) = 9.9616 C-5 82.9109 H-5 3.5658 J(H-5,H-4) = 9.9616 J(H-5,H-6S) = 2.2608 J(H-5,H-6R) = 5.7694 C-6 63.4918 H-6R 3.7182 J(H-6R,H-5) = 5.7694 J(H-6R,H-6S) = -12.5791 H-6S 3.9015 J(H-6S,H-5) = 2.2608 J(H-6S,H-6R) = -12.5791 C-7 159.256 C-8 34.1145 H-8R 2.6288 J(H-8R,H-8S) = -15.0374 J(H-8R,H-17R) = 8.0149 J(H-8R,H-17S) = 7.3892 H-8S 2.6438 J(H-8S,H-8R) = -15.0374 J(H-8S,H-17R) = 8.7658 J(H-8S,H-17S) = 6.0186 N-10 335.688 C-17 28.8313 H-17R 1.7675 J(H-17R,H-8S) = 8.7658 J(H-17R,H-8R) = 8.0149 J(H-17R,H-17S) = -13.9373 J(H-17R,H-18S) = 9.0149 J(H-17R,H-18R) = 5.0518 H-17S 1.7409 J(H-17S,H-8S) = 6.0186 J(H-17S,H-8R) = 7.3892 J(H-17S,H-17R) = -13.9373 J(H-17S,H-18S) = 5.6695 J(H-17S,H-18R) = 9.7943 C-18 30.146 H-18R 1.674 J(H-18R,H-17R) = 5.0518 J(H-18R,H-17S) = 9.7943 J(H-18R,H-18S) = -13.9036 J(H-18R,H-19R) = 7.7055 J(H-18R,H-19S) = 6.9792 H-18S 1.6902 J(H-18S,H-17R) = 9.0149 J(H-18S,H-17S) = 5.6695 J(H-18S,H-18R) = -13.9036 J(H-18S,H-19R) = 7.1378 J(H-18S,H-19S) = 6.9891 C-19 35.4822 H-19R 2.5943 J(H-19R,H-18S) = 7.1378 J(H-19R,H-18R) = 7.7055 J(H-19R,H-19S) = -20.0866 H-19S 2.5837 J(H-19S,H-18S) = 6.9891 J(H-19S,H-18R) = 6.9792 J(H-19S,H-19R) = -20.0866 C-21 16.8901 H-21 2.1063 GIB Position Chemical shift H Chemical shift Couplings... C-1 84.4997 H-1 5.071 J(H-1,H-2) = 9.8979 C-2 74.7547 H-2 3.4701 J(H-2,H-1) = 9.8979 J(H-2,H-3) = 8.9313 C-3 79.8572 H-3 3.5742 J(H-3,H-2) = 8.9313 J(H-3,H-4) = 9.2011 C-4 71.9637 H-4 3.4727 J(H-4,H-3) = 9.2011 J(H-4,H-5) = 9.9578 C-5 82.9039 H-5 3.5949 J(H-5,H-4) = 9.9578 J(H-5,H-6S) = 2.2366 J(H-5,H-6R) = 5.8611 C-6 63.4712 H-6R 3.7227 J(H-6R,H-5) = 5.8611 J(H-6R,H-6S) = -12.6312 H-6S 3.9135 J(H-6S,H-5) = 2.2366 J(H-6S,H-6R) = -12.6312 C-7 165.4109 C-8 33.6527 H-8R 2.9438 J(H-8R,H-8S) = -15.4743 J(H-8R,H-17R) = 6.8271 J(H-8R,H-17S) = 7.3319 H-8S 2.9506 J(H-8S,H-8R) = -15.4743 J(H-8S,H-17R) = 7.4377 J(H-8S,H-17S) = 6.996 N-10 347.332 C-17 22.4835 H-17R 2.2052 J(H-17R,H-8S) = 7.4377 J(H-17R,H-8R) = 6.8271 J(H-17R,H-17S) = -13.9079 J(H-17R,H-18S) = 7.2824 J(H-17R,H-18R) = 8.6591 H-17S 2.2165 J(H-17S,H-8S) = 6.996 J(H-17S,H-8R) = 7.3319 J(H-17S,H-17R) = -13.9079 J(H-17S,H-18S) = 8.7555 J(H-17S,H-18R) = 5.2372 C-18 54.2453 H-18R 2.9772 J(H-18R,H-17R) = 8.6591 J(H-18R,H-17S) = 5.2372 J(H-18R,H-18S) = -13.4762 H-18S 3.0508 J(H-18S,H-17R) = 7.2824 J(H-18S,H-17S) = 8.7555 J(H-18S,H-18R) = -13.4762 C-20 39.3818 H-20 2.7326 DS-GIB Position Chemical shift H Chemical shift Couplings... C-1 84.28 H-1 5.02 J(H-1,H-2) = 9.8678 C-2 75.0405 H-2 3.4446 J(H-2,H-1) = 9.8678 J(H-2,H-3) = 8.9165 C-3 79.9627 H-3 3.5639 J(H-3,H-2) = 8.9165 J(H-3,H-4) = 9.2622 C-4 72.0656 H-4 3.46 J(H-4,H-3) = 9.2622 J(H-4,H-5) = 10.0107 C-5 82.8848 H-5 3.5743 J(H-5,H-4) = 10.0107 J(H-5,H-6S) = 2.2136 J(H-5,H-6R) = 5.8752 C-6 63.5331 H-6R 3.7121 J(H-6R,H-5) = 5.8752 J(H-6R,H-6S) = -12.5877 H-6S 3.9013 J(H-6S,H-5) = 2.2136 J(H-6S,H-6R) = -12.5877 C-7 157.4111 C-8 33.3622 H-8R 2.809 J(H-8R,H-8S) = -14.8496 J(H-8R,H-17R) = 7.277 J(H-8R,H-17S) = 8.7549 H-8S 2.8059 J(H-8S,H-8R) = -14.8496 J(H-8S,H-17R) = 7.3549 J(H-8S,H-17S) = 5.7891 N-10 339.355 C-17 22.9875 H-17R 2.1308 J(H-17R,H-8S) = 7.3549 J(H-17R,H-8R) = 7.277 J(H-17R,H-17S) = -13.0871 J(H-17R,H-18S) = 5.7114 J(H-17R,H-18R) = 8.0556 H-17S 2.1326 J(H-17S,H-8S) = 5.7891 J(H-17S,H-8R) = 8.7549 J(H-17S,H-17R) = -13.0871 J(H-17S,H-18S) = 10.2685 J(H-17S,H-18R) = 5.9379 C-18 54.4283 H-18R 2.9339 J(H-18R,H-17R) = 8.0556 J(H-18R,H-17S) = 5.9379 J(H-18R,H-18S) = -13.4237 H-18S 2.9794 J(H-18S,H-17R) = 5.7114 J(H-18S,H-17S) = 10.2685 J(H-18S,H-18R) = -13.4237 C-20 39.4289 H-20 2.7154 GLI Position Chemical shift H Chemical shift Couplings... C-1 84.2803 H-1 4.727 J(H-1,H-2) = 9.785 C-2 74.6257 H-2 3.3377 J(H-2,H-1) = 9.785 J(H-2,H-3) = 9.0901 C-3 79.835 H-3 3.3301 J(H-3,H-2) = 9.0901 J(H-3,H-4) = 9.3169 C-4 71.586 H-4 3.4142 J(H-4,H-3) = 9.3169 J(H-4,H-5) = 9.9129 C-5 82.7239 H-5 3.2353 J(H-5,H-4) = 9.9129 J(H-5,H-6S) = 2.1577 J(H-5,H-6R) = 5.2039 C-6 63.1073 H-6R 3.6498 J(H-6R,H-5) = 5.2039 J(H-6R,H-6S) = -12.1599 H-6S 3.6499 J(H-6S,H-5) = 2.1577 J(H-6S,H-6R) = -12.1599 C-7 165.4902 C-8 41.0223 H-8R 4.1355 J(H-8R,H-8S) = -16.4142 H-8S 4.1517 J(H-8S,H-8R) = -16.4142 N-10 347.129 C-17 139.7072 C-18 123.7277 H-18 7.0403 J(H-18,H-19) = 7.5923 J(H-18,H-20) = 0.8581 J(H-18,H-22) = 1.5875 C-19 133.3042 H-19 7.3935 J(H-19,H-18) = 7.5923 J(H-19,H-20) = 8.3225 J(H-19,H-22) = 0.0073 C-20 116.1065 H-20 6.981 J(H-20,H-18) = 0.8581 J(H-20,H-19) = 8.3225 J(H-20,H-22) = 2.5776 C-21 162.2667 C-22 116.3355 H-22 7.0102 J(H-22,H-18) = 1.5875 J(H-22,H-19) = 0.0073 J(H-22,H-20) = 2.5776 C-24 58.2584 H-24 3.8504 DS-GLI Position Chemical shift H Chemical shift Couplings... C-1 83.9802 H-1 4.7212 J(H-1,H-2) = 9.7057 C-2 74.8492 H-2 3.3324 J(H-2,H-1) = 9.7057 J(H-2,H-3) = 8.7673 C-3 79.9128 H-3 3.3409 J(H-3,H-2) = 8.7673 J(H-3,H-4) = 9.2124 C-4 71.6781 H-4 3.4136 J(H-4,H-3) = 9.2124 J(H-4,H-5) = 9.9083 C-5 82.6306 H-5 3.2265 J(H-5,H-4) = 9.9083 J(H-5,H-6S) = 2.3308 J(H-5,H-6R) = 5.1402 C-6 63.1515 H-6R 3.6466 J(H-6R,H-5) = 5.1402 J(H-6R,H-6S) = -12.5819 H-6S 3.6628 J(H-6S,H-5) = 2.3308 J(H-6S,H-6R) = -12.5819 C-7 157.2566 C-8 40.7873 H-8R 4.021 J(H-8R,H-8S) = -16.627 H-8S 4.0362 J(H-8S,H-8R) = -16.627 N-10 340.041 C-17 140.6735 C-18 123.6951 H-18 6.9814 J(H-18,H-19) = 7.5897 J(H-18,H-20) = 0.7547 J(H-18,H-22) = 1.5666 C-19 133.1862 H-19 7.3732 J(H-19,H-18) = 7.5897 J(H-19,H-20) = 8.3122 J(H-19,H-22) = 0.2208 C-20 115.6538 H-20 6.9597 J(H-20,H-18) = 0.7547 J(H-20,H-19) = 8.3122 J(H-20,H-22) = 2.6034 C-21 162.16 C-22 116.4803 H-22 6.9387 J(H-22,H-18) = 1.5666 J(H-22,H-19) = 0.2208 J(H-22,H-20) = 2.6034 C-24 58.1971 H-24 3.8412 GMG Position Chemical shift H Chemical shift Couplings... C-1 84.2256 H-1 4.7204 J(H-1,H-2) = 9.7185 C-2 74.6341 H-2 3.3394 J(H-2,H-1) = 9.7185 J(H-2,H-3) = 8.9375 C-3 79.8478 H-3 3.342 J(H-3,H-2) = 8.9375 J(H-3,H-4) = 9.179 C-4 71.5814 H-4 3.4194 J(H-4,H-3) = 9.179 J(H-4,H-5) = 9.9289 C-5 82.7088 H-5 3.2429 J(H-5,H-4) = 9.9289 J(H-5,H-6S) = 3.6733 J(H-5,H-6R) = 3.6532 C-6 63.138 H-6R 3.6468 J(H-6R,H-5) = 3.6532 J(H-6R,H-6S) = -12.0277 H-6S 3.6512 J(H-6S,H-5) = 3.6733 J(H-6S,H-6R) = -12.0277 C-7 165.582 C-8 40.3724 H-8R 4.1055 J(H-8R,H-8S) = -16.2722 H-8S 4.121 J(H-8S,H-8R) = -16.2722 J(H-8S,H-18) = -0.8725 J(H-8S,H-22) = -0.8725 N-10 346.847 C-17 132.3216 C-18 132.2893 H-18 7.3771 J(H-18,H-8S) = -0.8725 J(H-18,H-19) = 8.5543 J(H-18,H-21) = 0.3012 J(H-18,H-22) = 2.7731 C-19 120.4358 H-19 7.1651 J(H-19,H-18) = 8.5543 J(H-19,H-21) = 2.406 J(H-19,H-22) = 0.3012 C-20 157.5697 C-21 120.4358 H-21 7.1651 J(H-21,H-18) = 0.3012 J(H-21,H-19) = 2.406 J(H-21,H-22) = 8.5543 C-22 132.2893 H-22 7.3771 J(H-22,H-8S) = -0.8725 J(H-22,H-18) = 2.7731 J(H-22,H-19) = 0.3012 J(H-22,H-21) = 8.5543 C-1' 101.016 H-1' 5.5668 J(H-1',H-2') = 1.8624 C-2' 72.8453 H-2' 4.1789 J(H-2',H-1') = 1.8624 J(H-2',H-3') = 3.4801 C-3' 72.9493 H-3' 4.0143 J(H-3',H-2') = 3.4801 J(H-3',H-4') = 9.7866 C-4' 74.9041 H-4' 3.5282 J(H-4',H-3') = 9.7866 J(H-4',H-5') = 9.6315 C-5' 72.2952 H-5' 3.8156 J(H-5',H-4') = 9.6315 J(H-5',H-6') = 6.2715 C-6' 19.5356 H-6' 1.2464 J(H-6',H-5') = 6.2715 DS-GMG Position Chemical shift H Chemical shift Couplings... C-1 83.9371 H-1 4.718 J(H-1,H-2) = 9.7403 C-2 74.8644 H-2 3.3343 J(H-2,H-1) = 9.7403 J(H-2,H-3) = 8.9488 C-3 79.9338 H-3 3.3515 J(H-3,H-2) = 8.9488 J(H-3,H-4) = 9.1355 C-4 71.6817 H-4 3.4188 J(H-4,H-3) = 9.1355 J(H-4,H-5) = 9.9322 C-5 82.6322 H-5 3.2352 J(H-5,H-4) = 9.9322 J(H-5,H-6S) = 2.331 J(H-5,H-6R) = 5.0997 C-6 63.1797 H-6R 3.6469 J(H-6R,H-5) = 5.0997 J(H-6R,H-6S) = -12.58 H-6S 3.6591 J(H-6S,H-5) = 2.331 J(H-6S,H-6R) = -12.58 C-7 157.5018 C-8 40.1218 H-8R 3.9944 J(H-8R,H-8S) = -16.5738 H-8S 4.0088 J(H-8S,H-8R) = -16.5738 N-10 339.604 C-17 133.297 C-18 132.2255 H-18 7.3136 J(H-18,H-19) = 8.52 J(H-18,H-21) = 0.3004 J(H-18,H-22) = 2.2854 C-19 120.3597 H-19 7.141 J(H-19,H-18) = 8.52 J(H-19,H-21) = 2.8013 J(H-19,H-22) = 0.3004 C-20 157.3745 C-21 120.3597 H-21 7.141 J(H-21,H-18) = 0.3004 J(H-21,H-19) = 2.8013 J(H-21,H-22) = 8.52 C-22 132.2255 H-22 7.3136 J(H-22,H-18) = 2.2854 J(H-22,H-19) = 0.3004 J(H-22,H-21) = 8.52 C-1' 101.0324 H-1' 5.5539 J(H-1',H-2') = 1.844 C-2' 72.8387 H-2' 4.1743 J(H-2',H-1') = 1.844 J(H-2',H-3') = 3.4782 C-3' 72.9522 H-3' 4.0089 J(H-3',H-2') = 3.4782 J(H-3',H-4') = 9.7852 C-4' 74.8822 H-4' 3.5305 J(H-4',H-3') = 9.7852 J(H-4',H-5') = 9.6219 C-5' 72.2796 H-5' 3.8123 J(H-5',H-4') = 9.6219 J(H-5',H-6') = 6.2679 C-6' 19.525 H-6' 1.2435 J(H-6',H-5') = 6.2679 GNA Position Chemical shift H Chemical shift Couplings... C-1 84.6763 H-1 5.0384 J(H-1,H-2) = 9.9053 C-2 74.8306 H-2 3.4665 J(H-2,H-1) = 9.9053 J(H-2,H-3) = 8.9268 C-3 79.9602 H-3 3.564 J(H-3,H-2) = 8.9268 J(H-3,H-4) = 9.2018 C-4 72.0214 H-4 3.4716 J(H-4,H-3) = 9.2018 J(H-4,H-5) = 9.9532 C-5 82.9895 H-5 3.5624 J(H-5,H-4) = 9.9532 J(H-5,H-6S) = 2.254 J(H-5,H-6R) = 5.7641 C-6 63.4884 H-6R 3.7144 J(H-6R,H-5) = 5.7641 J(H-6R,H-6S) = -12.6509 H-6S 3.8994 J(H-6S,H-5) = 2.254 J(H-6S,H-6R) = -12.6509 C-7 166.6922 C-8 34.3874 H-8R 2.8151 J(H-8R,H-8S) = -15.5449 J(H-8R,H-17R) = 8.7638 J(H-8R,H-17S) = 5.8622 H-8S 2.8372 J(H-8S,H-8R) = -15.5449 J(H-8S,H-17R) = 7.3175 J(H-8S,H-17S) = 8.0749 N-10 345.942 C-17 33.5695 H-17R 2.4854 J(H-17R,H-8S) = 7.3175 J(H-17R,H-8R) = 8.7638 J(H-17R,H-17S) = -16.8983 J(H-17R,H-18) = 6.0519 J(H-17R,H-19E) = -1.3041 J(H-17R,H-19Z) = -1.4412 H-17S 2.4806 J(H-17S,H-8S) = 8.0749 J(H-17S,H-8R) = 5.8622 J(H-17S,H-17R) = -16.8983 J(H-17S,H-18) = 7.1243 J(H-17S,H-19E) = -1.0915 J(H-17S,H-19Z) = -1.6222 C-18 139.6648 H-18 5.932 J(H-18,H-17R) = 6.0519 J(H-18,H-17S) = 7.1243 J(H-18,H-19Z) = 17.2394 J(H-18,H-19E) = 10.2936 C-19 118.858 H-19Z 5.1648 J(H-19Z,H-17R) = -1.4412 J(H-19Z,H-17S) = -1.6222 J(H-19Z,H-18) = 17.2394 J(H-19Z,H-19E) = 1.8465 H-19E 5.0909 J(H-19E,H-17R) = -1.3041 J(H-19E,H-17S) = -1.0915 J(H-19E,H-18) = 10.2936 J(H-19E,H-19Z) = 1.8465 DS-GNA Position Chemical shift H Chemical shift Couplings... C-1 84.3226 H-1 5.0041 J(H-1,H-2) = 9.8879 C-2 75.0077 H-2 3.4522 J(H-2,H-1) = 9.8879 J(H-2,H-3) = 8.9253 C-3 79.9647 H-3 3.5648 J(H-3,H-2) = 8.9253 J(H-3,H-4) = 9.2205 C-4 72.0067 H-4 3.4722 J(H-4,H-3) = 9.2205 J(H-4,H-5) = 9.923 C-5 82.843 H-5 3.5538 J(H-5,H-4) = 9.923 J(H-5,H-6S) = 2.2485 J(H-5,H-6R) = 5.7839 C-6 63.4336 H-6R 3.717 J(H-6R,H-5) = 5.7839 J(H-6R,H-6S) = -12.6067 H-6S 3.8984 J(H-6S,H-5) = 2.2485 J(H-6S,H-6R) = -12.6067 C-7 158.694 C-8 33.9104 H-8R 2.7093 J(H-8R,H-8S) = -15.6976 J(H-8R,H-17R) = 5.8512 J(H-8R,H-17S) = 7.0114 H-8S 2.7167 J(H-8S,H-8R) = -15.6976 J(H-8S,H-17R) = 9.8002 J(H-8S,H-17S) = 7.2293 N-10 336.462 C-17 33.8974 H-17R 2.4155 J(H-17R,H-8S) = 9.8002 J(H-17R,H-8R) = 5.8512 J(H-17R,H-17S) = -13.368 J(H-17R,H-18) = 6.5974 J(H-17R,H-19E) = -1.1593 J(H-17R,H-19Z) = -1.562 H-17S 2.4263 J(H-17S,H-8S) = 7.2293 J(H-17S,H-8R) = 7.0114 J(H-17S,H-17R) = -13.368 J(H-17S,H-18) = 6.6208 J(H-17S,H-19E) = -1.2552 J(H-17S,H-19Z) = -1.5689 C-18 139.82 H-18 5.8988 J(H-18,H-17R) = 6.5974 J(H-18,H-17S) = 6.6208 J(H-18,H-19Z) = 17.2259 J(H-18,H-19E) = 10.2809 C-19 118.6585 H-19Z 5.141 J(H-19Z,H-17R) = -1.562 J(H-19Z,H-17S) = -1.5689 J(H-19Z,H-18) = 17.2259 J(H-19Z,H-19E) = 1.8837 H-19E 5.0758 J(H-19E,H-17R) = -1.1593 J(H-19E,H-17S) = -1.2552 J(H-19E,H-18) = 10.2809 J(H-19E,H-19Z) = 1.8837 GRA Position Chemical shift H Chemical shift Couplings... C-1 84.725 H-1 5.0276 J(H-1,H-2) = 9.8961 C-2 74.8823 H-2 3.4483 J(H-2,H-1) = 9.8961 J(H-2,H-3) = 9.002 C-3 79.9776 H-3 3.5526 J(H-3,H-2) = 9.002 J(H-3,H-4) = 9.1593 C-4 72.1033 H-4 3.4492 J(H-4,H-3) = 9.1593 J(H-4,H-5) = 9.8367 C-5 83.0824 H-5 3.5597 J(H-5,H-4) = 9.8367 J(H-5,H-6S) = 2.2233 J(H-5,H-6R) = 5.9431 C-6 63.6114 H-6R 3.698 J(H-6R,H-5) = 5.9431 J(H-6R,H-6S) = -12.6088 H-6S 3.8883 J(H-6S,H-5) = 2.2233 J(H-6S,H-6R) = -12.6088 C-7 166.6598 C-8 34.606 H-8R 2.7953 J(H-8R,H-8S) = -14.7144 J(H-8R,H-17R) = 8.1568 J(H-8R,H-17S) = 9.2756 H-8S 2.7897 J(H-8S,H-8R) = -14.7144 J(H-8S,H-17R) = 5.0333 J(H-8S,H-17S) = 6.5919 N-10 346.18 C-17 28.3292 H-17R 1.9061 J(H-17R,H-8S) = 5.0333 J(H-17R,H-8R) = 8.1568 J(H-17R,H-17S) = -13.3531 J(H-17R,H-18S) = 7.5533 J(H-17R,H-18R) = 7.4683 H-17S 1.8824 J(H-17S,H-8S) = 6.5919 J(H-17S,H-8R) = 9.2756 J(H-17S,H-17R) = -13.3531 J(H-17S,H-18S) = 5.2948 J(H-17S,H-18R) = 7.4205 C-18 24.1367 H-18R 1.8196 J(H-18R,H-17R) = 7.4683 J(H-18R,H-17S) = 7.4205 J(H-18R,H-18S) = -12.0042 J(H-18R,H-19R) = 5.5044 J(H-18R,H-19S) = 9.1477 H-18S 1.8466 J(H-18S,H-17R) = 7.5533 J(H-18S,H-17S) = 5.2948 J(H-18S,H-18R) = -12.0042 J(H-18S,H-19R) = 9.0214 J(H-18S,H-19S) = 6.686 C-19 55.0411 H-19R 2.9185 J(H-19R,H-18S) = 9.0214 J(H-19R,H-18R) = 5.5044 J(H-19R,H-19S) = -13.3586 H-19S 2.9563 J(H-19S,H-18S) = 6.686 J(H-19S,H-18R) = 9.1477 J(H-19S,H-19R) = -13.3586 C-21 39.3269 H-21 2.6924 DS-GRA Position Chemical shift H Chemical shift Couplings... C-1 84.3682 H-1 4.9965 J(H-1,H-2) = 9.8995 C-2 75.0448 H-2 3.4415 J(H-2,H-1) = 9.8995 J(H-2,H-3) = 8.9251 C-3 79.9752 H-3 3.5585 J(H-3,H-2) = 8.9251 J(H-3,H-4) = 9.1952 C-4 72.0829 H-4 3.4544 J(H-4,H-3) = 9.1952 J(H-4,H-5) = 9.966 C-5 82.9473 H-5 3.5557 J(H-5,H-4) = 9.966 J(H-5,H-6S) = 2.2284 J(H-5,H-6R) = 5.9518 C-6 63.5507 H-6R 3.7057 J(H-6R,H-5) = 5.9518 J(H-6R,H-6S) = -12.5834 H-6S 3.8946 J(H-6S,H-5) = 2.2284 J(H-6S,H-6R) = -12.5834 C-7 158.6097 C-8 34.1547 H-8R 2.684 J(H-8R,H-8S) = -15.3678 J(H-8R,H-17R) = 8.9467 J(H-8R,H-17S) = 4.9691 H-8S 2.6849 J(H-8S,H-8R) = -15.3678 J(H-8S,H-17R) = 6.1479 J(H-8S,H-17S) = 8.5877 N-10 337.033 C-17 28.653 H-17R 1.8483 J(H-17R,H-8S) = 6.1479 J(H-17R,H-8R) = 8.9467 J(H-17R,H-17S) = -13.733 J(H-17R,H-18S) = 10.2677 J(H-17R,H-18R) = 5.054 H-17S 1.8236 J(H-17S,H-8S) = 8.5877 J(H-17S,H-8R) = 4.9691 J(H-17S,H-17R) = -13.733 J(H-17S,H-18S) = 5.5689 J(H-17S,H-18R) = 9.8714 C-18 24.0953 H-18R 1.7963 J(H-18R,H-17R) = 5.054 J(H-18R,H-17S) = 9.8714 J(H-18R,H-18S) = -13.3479 J(H-18R,H-19R) = 9.4552 J(H-18R,H-19S) = 6.7326 H-18S 1.8142 J(H-18S,H-17R) = 10.2677 J(H-18S,H-17S) = 5.5689 J(H-18S,H-18R) = -13.3479 J(H-18S,H-19R) = 4.8846 J(H-18S,H-19S) = 9.2349 C-19 55.0263 H-19R 2.9127 J(H-19R,H-18S) = 4.8846 J(H-19R,H-18R) = 9.4552 J(H-19R,H-19S) = -13.418 H-19S 2.9382 J(H-19S,H-18S) = 9.2349 J(H-19S,H-18R) = 6.7326 J(H-19S,H-19R) = -13.418 C-21 39.2896 H-21 2.6987 GRE Position Chemical shift H Chemical shift Couplings... C-1 84.513 H-1 5.0596 J(H-1,H-2) = 9.9004 C-2 74.7751 H-2 3.4716 J(H-2,H-1) = 9.9004 J(H-2,H-3) = 8.9201 C-3 79.8731 H-3 3.5708 J(H-3,H-2) = 8.9201 J(H-3,H-4) = 9.2076 C-4 71.995 H-4 3.4677 J(H-4,H-3) = 9.2076 J(H-4,H-5) = 9.9777 C-5 82.9455 H-5 3.5811 J(H-5,H-4) = 9.9777 J(H-5,H-6S) = 2.2149 J(H-5,H-6R) = 5.9737 C-6 63.4793 H-6R 3.7127 J(H-6R,H-5) = 5.9737 J(H-6R,H-6S) = -12.6152 H-6S 3.9055 J(H-6S,H-5) = 2.2149 J(H-6S,H-6R) = -12.6152 C-7 165.1462 C-8 33.2952 H-8R 2.9483 J(H-8R,H-8S) = -17.747 J(H-8R,H-17R) = 6.9221 J(H-8R,H-17S) = 6.9861 H-8S 2.9523 J(H-8S,H-8R) = -17.747 J(H-8S,H-17R) = 7.472 J(H-8S,H-17S) = 7.0568 N-10 347.629 C-17 31.4656 H-17R 2.7261 J(H-17R,H-8S) = 7.472 J(H-17R,H-8R) = 6.9221 J(H-17R,H-17S) = -15.0413 J(H-17R,H-18) = 7.1162 J(H-17R,H-19) = -1.791 H-17S 2.7376 J(H-17S,H-8S) = 7.0568 J(H-17S,H-8R) = 6.9861 J(H-17S,H-17R) = -15.0413 J(H-17S,H-18) = 6.4611 J(H-17S,H-19) = -1.4115 C-18 144.2535 H-18 6.6057 J(H-18,H-17R) = 7.1162 J(H-18,H-17S) = 6.4611 J(H-18,H-19) = 15.2297 C-19 135.774 H-19 6.5936 J(H-19,H-17R) = -1.791 J(H-19,H-17S) = -1.4115 J(H-19,H-18) = 15.2297 C-21 41.5544 H-21 2.7434 GRH Position Chemical shift H Chemical shift Couplings... C-1 84.7292 H-1 5.0284 J(H-1,H-2) = 9.8978 C-2 74.8384 H-2 3.466 J(H-2,H-1) = 9.8978 J(H-2,H-3) = 8.9132 C-3 79.9636 H-3 3.5671 J(H-3,H-2) = 8.9132 J(H-3,H-4) = 9.2147 C-4 72.0373 H-4 3.4716 J(H-4,H-3) = 9.2147 J(H-4,H-5) = 9.9575 C-5 82.9952 H-5 3.5655 J(H-5,H-4) = 9.9575 J(H-5,H-6S) = 2.2891 J(H-5,H-6R) = 5.7865 C-6 63.5225 H-6R 3.7181 J(H-6R,H-5) = 5.7865 J(H-6R,H-6S) = -12.6229 H-6S 3.9024 J(H-6S,H-5) = 2.2891 J(H-6S,H-6R) = -12.6229 C-7 166.2401 C-8 34.9731 H-8R 2.8 J(H-8R,H-8S) = -15.4956 J(H-8R,H-17R) = 6.2545 J(H-8R,H-17S) = 7.8589 H-8S 2.8204 J(H-8S,H-8R) = -15.4956 J(H-8S,H-17R) = 6.5029 J(H-8S,H-17S) = 8.2421 C-17 32.9793 H-17R 2.5336 J(H-17R,H-8S) = 6.5029 J(H-17R,H-8R) = 6.2545 J(H-17R,H-17S) = -19.0478 J(H-17R,H-18) = 7.604 J(H-17R,H-19) = -1.1685 H-17S 2.5382 J(H-17S,H-8S) = 8.2421 J(H-17S,H-8R) = 7.8589 J(H-17S,H-17R) = -19.0478 J(H-17S,H-18) = 6.4934 J(H-17S,H-19) = -1.323 C-18 127.5983 H-18 5.5596 J(H-18,H-17R) = 7.604 J(H-18,H-17S) = 6.4934 J(H-18,H-19) = 15.0474 C-19 128.0764 H-19 6.214 J(H-19,H-17R) = -1.1685 J(H-19,H-17S) = -1.323 J(H-19,H-18) = 15.0474 C-21 16.6233 H-21 2.2555 DS-GRH Position Chemical shift H Chemical shift Couplings... C-1 84.4429 H-1 4.9926 J(H-1,H-2) = 9.8768 C-2 75.0771 H-2 3.4512 J(H-2,H-1) = 9.8768 J(H-2,H-3) = 8.9302 C-3 80.0362 H-3 3.5658 J(H-3,H-2) = 8.9302 J(H-3,H-4) = 9.232 C-4 72.0846 H-4 3.4707 J(H-4,H-3) = 9.232 J(H-4,H-5) = 10.0169 C-5 82.9182 H-5 3.5541 J(H-5,H-4) = 10.0169 J(H-5,H-6S) = 2.3569 J(H-5,H-6R) = 5.846 C-6 63.5295 H-6R 3.719 J(H-6R,H-5) = 5.846 J(H-6R,H-6S) = -12.5726 H-6S 3.8987 J(H-6S,H-5) = 2.3569 J(H-6S,H-6R) = -12.5726 C-7 158.4391 C-8 34.5608 H-8R 2.6922 J(H-8R,H-8S) = -19.3015 J(H-8R,H-17R) = 4.8633 J(H-8R,H-17S) = 7.0724 H-8S 2.6977 J(H-8S,H-8R) = -19.3015 J(H-8S,H-17R) = 9.3828 J(H-8S,H-17S) = 7.5392 N-10 337.923 C-17 33.3466 H-17R 2.4643 J(H-17R,H-8S) = 9.3828 J(H-17R,H-8R) = 4.8633 J(H-17R,H-17S) = -14.7628 J(H-17R,H-18) = 7.1356 J(H-17R,H-19) = -1.2438 H-17S 2.4792 J(H-17S,H-8S) = 7.5392 J(H-17S,H-8R) = 7.0724 J(H-17S,H-17R) = -14.7628 J(H-17S,H-18) = 6.9669 J(H-17S,H-19) = -1.2132 C-18 128.0454 H-18 5.5307 J(H-18,H-17R) = 7.1356 J(H-18,H-17S) = 6.9669 J(H-18,H-19) = 15.0535 C-19 127.8298 H-19 6.1769 J(H-19,H-17R) = -1.2438 J(H-19,H-17S) = -1.2132 J(H-19,H-18) = 15.0535 C-21 16.7135 H-21 2.2513 GST Position Chemical shift H Chemical shift Couplings... C-1 84.5325 H-1 4.8949 J(H-1,H-2) = 9.8579 C-2 74.7154 H-2 3.443 J(H-2,H-1) = 9.8579 J(H-2,H-3) = 8.9356 C-3 79.8756 H-3 3.498 J(H-3,H-2) = 8.9356 J(H-3,H-4) = 8.9431 C-4 71.9509 H-4 3.4439 J(H-4,H-3) = 8.9431 J(H-4,H-5) = 9.9733 C-5 82.9514 H-5 3.4657 J(H-5,H-4) = 9.9733 J(H-5,H-6S) = 2.1087 J(H-5,H-6R) = 5.648 C-6 63.4152 H-6R 3.6753 J(H-6R,H-5) = 5.648 J(H-6R,H-6S) = -12.6257 H-6S 3.8427 J(H-6S,H-5) = 2.1087 J(H-6S,H-6R) = -12.6257 C-7 166.2064 C-8 36.7608 H-8R 3.0718 J(H-8R,H-8S) = -15.6663 J(H-8R,H-17R) = 8.7444 J(H-8R,H-17S) = 6.5892 H-8S 3.0081 J(H-8S,H-8R) = -15.6663 J(H-8S,H-17R) = 6.4259 J(H-8S,H-17S) = 8.432 N-10 347.092 C-17 35.3999 H-17R 3.0556 J(H-17R,H-8S) = 6.4259 J(H-17R,H-8R) = 8.7444 J(H-17R,H-17S) = -13.9832 H-17S 3.0881 J(H-17S,H-8S) = 8.432 J(H-17S,H-8R) = 6.5892 J(H-17S,H-17R) = -13.9832 C-18 143.4129 C-19 131.6272 H-19 7.3595 J(H-19,H-20) = 7.7581 J(H-19,H-21) = 1.3037 J(H-19,H-22) = 0.5471 J(H-19,H-23) = 1.8726 C-20 131.5907 H-20 7.3946 J(H-20,H-19) = 7.7581 J(H-20,H-21) = 7.4566 J(H-20,H-22) = 1.7095 J(H-20,H-23) = 0.5471 C-21 129.4701 H-21 7.3101 J(H-21,H-19) = 1.3037 J(H-21,H-20) = 7.4566 J(H-21,H-22) = 7.4566 J(H-21,H-23) = 1.3037 C-22 131.5907 H-22 7.3946 J(H-22,H-19) = 0.5471 J(H-22,H-20) = 1.7095 J(H-22,H-21) = 7.4566 J(H-22,H-23) = 7.7581 C-23 131.6272 H-23 7.3595 J(H-23,H-19) = 1.8726 J(H-23,H-20) = 0.5471 J(H-23,H-21) = 1.3037 J(H-23,H-22) = 7.7581 DS-GST Position Chemical shift H Chemical shift Couplings... C-1 84.3234 H-1 4.9064 J(H-1,H-2) = 9.8685 C-2 74.9909 H-2 3.4398 J(H-2,H-1) = 9.8685 J(H-2,H-3) = 8.9537 C-3 79.9599 H-3 3.5185 J(H-3,H-2) = 8.9537 J(H-3,H-4) = 9.1714 C-4 71.9987 H-4 3.4566 J(H-4,H-3) = 9.1714 J(H-4,H-5) = 9.9383 C-5 82.8811 H-5 3.4822 J(H-5,H-4) = 9.9383 J(H-5,H-6S) = 2.1147 J(H-5,H-6R) = 5.6116 C-6 63.427 H-6R 3.6887 J(H-6R,H-5) = 5.6116 J(H-6R,H-6S) = -12.5894 H-6S 3.8527 J(H-6S,H-5) = 2.1147 J(H-6S,H-6R) = -12.5894 C-7 158.2637 C-8 36.3861 H-8R 2.8915 J(H-8R,H-8S) = -15.4435 J(H-8R,H-17R) = 7.2332 J(H-8R,H-17S) = 7.1034 H-8S 2.9314 J(H-8S,H-8R) = -15.4435 J(H-8S,H-17R) = 7.5995 J(H-8S,H-17S) = 7.5065 N-10 337.783 C-17 35.8639 H-17R 2.9963 J(H-17R,H-8S) = 7.5995 J(H-17R,H-8R) = 7.2332 J(H-17R,H-17S) = -15.4337 H-17S 2.9956 J(H-17S,H-8S) = 7.5065 J(H-17S,H-8R) = 7.1034 J(H-17S,H-17R) = -15.4337 C-18 143.47 C-19 131.5688 H-19 7.3097 J(H-19,H-20) = 7.6782 J(H-19,H-21) = 0.0368 J(H-19,H-22) = 0.0048 J(H-19,H-23) = 0.5771 C-20 131.5591 H-20 7.3824 J(H-20,H-19) = 7.6782 J(H-20,H-21) = 7.7617 J(H-20,H-22) = 0.147 J(H-20,H-23) = 0.0048 C-21 129.3934 H-21 7.3021 J(H-21,H-19) = 0.0368 J(H-21,H-20) = 7.7617 J(H-21,H-22) = 7.7617 J(H-21,H-23) = 0.0368 C-22 131.5591 H-22 7.3824 J(H-22,H-19) = 0.0048 J(H-22,H-20) = 0.147 J(H-22,H-21) = 7.7617 J(H-22,H-23) = 7.6782 C-23 131.5688 H-23 7.3097 J(H-23,H-19) = 0.5771 J(H-23,H-20) = 0.0048 J(H-23,H-21) = 0.0368 J(H-23,H-22) = 7.6782 DS-GSY Position Chemical shift H Chemical shift Couplings... C-1 84.2986 H-1 5.0367 J(H-1,H-2) = 9.8809 C-2 75.1142 H-2 3.4495 J(H-2,H-1) = 9.8809 J(H-2,H-3) = 8.9217 C-3 79.9551 H-3 3.5626 J(H-3,H-2) = 8.9217 J(H-3,H-4) = 9.2043 C-4 72.0934 H-4 3.4535 J(H-4,H-3) = 9.2043 J(H-4,H-5) = 9.9514 C-5 82.7739 H-5 3.5606 J(H-5,H-4) = 9.9514 J(H-5,H-6S) = 2.2335 J(H-5,H-6R) = 6.0807 C-6 63.6352 H-6R 3.7084 J(H-6R,H-5) = 6.0807 J(H-6R,H-6S) = -12.544 H-6S 3.9028 J(H-6S,H-5) = 2.2335 J(H-6S,H-6R) = -12.544 C-7 159.6653 C-8 42.1292 H-8 2.9601 J(H-8,H-17R) = 6.1433 J(H-8,H-17S) = 6.8358 J(H-8,H-19) = 6.9794 N-10 343.12 C-17 67.2918 H-17R 3.6697 J(H-17R,H-8) = 6.1433 J(H-17R,H-17S) = -11.0708 H-17S 3.8476 J(H-17S,H-8) = 6.8358 J(H-17S,H-17R) = -11.0708 C-19 18.7972 H-19 1.2274 J(H-19,H-8) = 6.9794 GTL Position Chemical shift H Chemical shift Couplings... C-1 84.209 H-1 4.7103 J(H-1,H-2) = 9.3758 C-2 74.6372 H-2 3.3202 J(H-2,H-1) = 9.3758 J(H-2,H-3) = 8.8217 C-3 79.8071 H-3 3.3356 J(H-3,H-2) = 8.8217 J(H-3,H-4) = 9.5927 C-4 71.6409 H-4 3.4078 J(H-4,H-3) = 9.5927 J(H-4,H-5) = 9.8579 C-5 82.6979 H-5 3.2661 J(H-5,H-4) = 9.8579 J(H-5,H-6S) = 2.3673 J(H-5,H-6R) = 5.1062 C-6 63.1733 H-6R 3.6445 J(H-6R,H-5) = 5.1062 J(H-6R,H-6S) = -12.6658 H-6S 3.6794 J(H-6S,H-5) = 2.3673 J(H-6S,H-6R) = -12.6658 C-7 165.553 C-8 41.0576 H-8R 4.1535 J(H-8R,H-8S) = -20.5679 H-8S 4.1656 J(H-8S,H-8R) = -20.5679 N-10 346.94 C-17 137.9407 C-18 130.9435 H-18 7.4206 J(H-18,H-19) = 7.7811 J(H-18,H-20) = 1.1582 J(H-18,H-21) = 0.5237 J(H-18,H-22) = 1.9502 C-19 132.068 H-19 7.4572 J(H-19,H-18) = 7.7811 J(H-19,H-20) = 7.4434 J(H-19,H-21) = 1.4728 J(H-19,H-22) = 0.5237 C-20 130.4378 H-20 7.3927 J(H-20,H-18) = 1.1582 J(H-20,H-19) = 7.4434 J(H-20,H-21) = 7.4434 J(H-20,H-22) = 1.1582 C-21 132.068 H-21 7.4572 J(H-21,H-18) = 0.5237 J(H-21,H-19) = 1.4728 J(H-21,H-20) = 7.4434 J(H-21,H-22) = 7.7811 C-22 130.9435 H-22 7.4206 J(H-22,H-18) = 1.9502 J(H-22,H-19) = 0.5237 J(H-22,H-20) = 1.1582 J(H-22,H-21) = 7.7811 DS-GTL Position Chemical shift H Chemical shift Couplings... C-1 83.9171 H-1 4.7124 J(H-1,H-2) = 9.6339 C-2 74.861 H-2 3.33 J(H-2,H-1) = 9.6339 J(H-2,H-3) = 8.8279 C-3 79.8904 H-3 3.3344 J(H-3,H-2) = 8.8279 J(H-3,H-4) = 9.1632 C-4 71.7339 H-4 3.4081 J(H-4,H-3) = 9.1632 J(H-4,H-5) = 9.8783 C-5 82.6095 H-5 3.2606 J(H-5,H-4) = 9.8783 J(H-5,H-6S) = 2.2723 J(H-5,H-6R) = 5.2294 C-6 63.2156 H-6R 3.6421 J(H-6R,H-5) = 5.2294 J(H-6R,H-6S) = -12.592 H-6S 3.6885 J(H-6S,H-5) = 2.2723 J(H-6S,H-6R) = -12.592 C-7 157.4603 C-8 40.8075 H-8R 4.0464 J(H-8R,H-8S) = -19.1386 H-8S 4.0493 J(H-8S,H-8R) = -19.1386 N-10 339.69 C-17 138.8825 C-18 130.9076 H-18 7.3617 J(H-18,H-19) = 7.7724 J(H-18,H-20) = 1.2422 J(H-18,H-21) = 0.4561 J(H-18,H-22) = 2.3927 C-19 131.9511 H-19 7.4358 J(H-19,H-18) = 7.7724 J(H-19,H-20) = 7.4703 J(H-19,H-21) = 1.7013 J(H-19,H-22) = 0.4561 C-20 130.1879 H-20 7.3694 J(H-20,H-18) = 1.2422 J(H-20,H-19) = 7.4703 J(H-20,H-21) = 7.4703 J(H-20,H-22) = 1.2422 C-21 131.9511 H-21 7.4358 J(H-21,H-18) = 0.4561 J(H-21,H-19) = 1.7013 J(H-21,H-20) = 7.4703 J(H-21,H-22) = 7.7724 C-22 130.9076 H-22 7.3617 J(H-22,H-18) = 2.3927 J(H-22,H-19) = 0.4561 J(H-22,H-20) = 1.2422 J(H-22,H-21) = 7.7724 PRO Position Chemical shift H Chemical shift Couplings... C-1 84.8335 H-1 5.1146 J(H-1,H-2) = 9.8778 C-2 74.7773 H-2 3.4726 J(H-2,H-1) = 9.8778 J(H-2,H-3) = 9.0057 C-3 79.8612 H-3 3.5704 J(H-3,H-2) = 9.0057 J(H-3,H-4) = 9.2149 C-4 71.9048 H-4 3.4802 J(H-4,H-3) = 9.2149 J(H-4,H-5) = 9.9508 C-5 82.8653 H-5 3.57 J(H-5,H-4) = 9.9508 J(H-5,H-6S) = 2.461 J(H-5,H-6R) = 5.4966 C-6 63.3872 H-6R 3.723 J(H-6R,H-5) = 5.4966 J(H-6R,H-6S) = -12.6205 H-6S 3.8982 J(H-6S,H-5) = 2.461 J(H-6S,H-6R) = -12.6205 C-7 163.5551 C-8 42.1158 H-8R 2.9127 J(H-8R,H-8S) = -15.1908 J(H-8R,H-17) = 7.8513 H-8S 2.9897 J(H-8S,H-8R) = -15.1908 J(H-8S,H-17) = 5.3054 N-10 348.903 C-17 72.6156 H-17 4.6567 J(H-17,H-8S) = 5.3054 J(H-17,H-8R) = 7.8513 J(H-17,H-18) = 6.4567 J(H-17,H-19Z) = -1.4969 J(H-17,H-19E) = -1.3029 C-18 141.1869 H-18 5.973 J(H-18,H-17) = 6.4567 J(H-18,H-19Z) = 17.2398 J(H-18,H-19E) = 10.6936 C-19 119.1353 H-19Z 5.3517 J(H-19Z,H-17) = -1.4969 J(H-19Z,H-18) = 17.2398 J(H-19Z,H-19E) = 1.2581 H-19E 5.2484 J(H-19E,H-17) = -1.3029 J(H-19E,H-18) = 10.6936 J(H-19E,H-19Z) = 1.2581 DS-PRO Position Chemical shift H Chemical shift Couplings... C-1 84.5514 H-1 5.0606 J(H-1,H-2) = 9.8659 C-2 75.0561 H-2 3.4511 J(H-2,H-1) = 9.8659 J(H-2,H-3) = 8.9396 C-3 79.9508 H-3 3.5649 J(H-3,H-2) = 8.9396 J(H-3,H-4) = 9.2161 C-4 71.9886 H-4 3.4739 J(H-4,H-3) = 9.2161 J(H-4,H-5) = 9.9551 C-5 82.8112 H-5 3.5648 J(H-5,H-4) = 9.9551 J(H-5,H-6S) = 2.248 J(H-5,H-6R) = 5.6468 C-6 63.4349 H-6R 3.7187 J(H-6R,H-5) = 5.6468 J(H-6R,H-6S) = -12.6178 H-6S 3.892 J(H-6S,H-5) = 2.248 J(H-6S,H-6R) = -12.6178 C-7 155.3237 C-8 41.795 H-8R 2.8112 J(H-8R,H-8S) = -15.188 J(H-8R,H-17) = 7.5967 H-8S 2.8418 J(H-8S,H-8R) = -15.188 J(H-8S,H-17) = 5.831 N-10 341.789 C-17 73.0855 H-17 4.5603 J(H-17,H-8S) = 5.831 J(H-17,H-8R) = 7.5967 J(H-17,H-18) = 6.2712 J(H-17,H-19Z) = -1.3481 J(H-17,H-19E) = -1.1817 C-18 141.3613 H-18 5.9273 J(H-18,H-17) = 6.2712 J(H-18,H-19Z) = 17.2462 J(H-18,H-19E) = 10.5186 C-19 119.1457 H-19Z 5.3148 J(H-19Z,H-17) = -1.3481 J(H-19Z,H-18) = 17.2462 J(H-19Z,H-19E) = 1.2273 H-19E 5.2261 J(H-19E,H-17) = -1.1817 J(H-19E,H-18) = 10.5186 J(H-19E,H-19Z) = 1.2273 SIN Position Chemical shift H Chemical shift Couplings... C-1 84.5 H-1 5.0441 J(H-1,H-2) = 9.9432 C-2 74.8869 H-2 3.4329 J(H-2,H-1) = 9.9432 J(H-2,H-3) = 9.0086 C-3 80.0026 H-3 3.5208 J(H-3,H-2) = 9.0086 J(H-3,H-4) = 9.2094 C-4 72.0782 H-4 3.4479 J(H-4,H-3) = 9.2094 J(H-4,H-5) = 9.9274 C-5 82.9627 H-5 3.5333 J(H-5,H-4) = 9.9274 J(H-5,H-6S) = 2.2658 J(H-5,H-6R) = 5.8946 C-6 63.5847 H-6R 3.7049 J(H-6R,H-5) = 5.8946 J(H-6R,H-6S) = -12.6271 H-6S 3.8992 J(H-6S,H-5) = 2.2658 J(H-6S,H-6R) = -12.6271 C-7 165.9459 C-8 39.0654 H-8R 3.5207 J(H-8R,H-8S) = -16.6555 J(H-8R,H-17) = 6.5648 J(H-8R,H-18E) = -1.3529 J(H-8R,H-18Z) = -1.4767 H-8S 3.4906 J(H-8S,H-8R) = -16.6555 J(H-8S,H-17) = 5.211 J(H-8S,H-18E) = -1.822 J(H-8S,H-18Z) = -1.8945 N-10 345.65 C-17 135.0021 H-17 6.0193 J(H-17,H-8S) = 5.211 J(H-17,H-8R) = 6.5648 J(H-17,H-18E) = 10.3333 J(H-17,H-18Z) = 17.2712 C-18 121.355 H-18Z 5.3119 J(H-18Z,H-8S) = -1.8945 J(H-18Z,H-8R) = -1.4767 J(H-18Z,H-17) = 17.2712 J(H-18Z,H-18E) = 1.1731 H-18E 5.2685 J(H-18E,H-8S) = -1.822 J(H-18E,H-8R) = -1.3529 J(H-18E,H-17) = 10.3333 J(H-18E,H-18Z) = 1.1731 DS-SIN Position Chemical shift H Chemical shift Couplings... C-1 84.0931 H-1 5.0242 J(H-1,H-2) = 9.9329 C-2 74.9996 H-2 3.4337 J(H-2,H-1) = 9.9329 J(H-2,H-3) = 8.9363 C-3 79.9785 H-3 3.5357 J(H-3,H-2) = 8.9363 J(H-3,H-4) = 9.189 C-4 72.0432 H-4 3.4614 J(H-4,H-3) = 9.189 J(H-4,H-5) = 9.963 C-5 82.7736 H-5 3.54 J(H-5,H-4) = 9.963 J(H-5,H-6S) = 2.2567 J(H-5,H-6R) = 5.9142 C-6 63.4977 H-6R 3.7189 J(H-6R,H-5) = 5.9142 J(H-6R,H-6S) = -12.5835 H-6S 3.9125 J(H-6S,H-5) = 2.2567 J(H-6S,H-6R) = -12.5835 C-7 157.7195 C-8 38.6915 H-8R 3.3972 J(H-8R,H-8S) = -17.0994 J(H-8R,H-17) = 5.2857 J(H-8R,H-18E) = -1.8503 J(H-8R,H-18Z) = -1.9344 H-8S 3.4244 J(H-8S,H-8R) = -17.0994 J(H-8S,H-17) = 6.4746 J(H-8S,H-18E) = -1.2706 J(H-8S,H-18Z) = -1.5677 N-10 337.504 C-17 135.7516 H-17 5.9994 J(H-17,H-8S) = 6.4746 J(H-17,H-8R) = 5.2857 J(H-17,H-18E) = 10.2813 J(H-17,H-18Z) = 17.2954 C-18 120.6635 H-18Z 5.2705 J(H-18Z,H-8S) = -1.5677 J(H-18Z,H-8R) = -1.9344 J(H-18Z,H-17) = 17.2954 J(H-18Z,H-18E) = 1.2666 H-18E 5.2419 J(H-18E,H-8S) = -1.2706 J(H-18E,H-8R) = -1.8503 J(H-18E,H-17) = 10.2813 J(H-18E,H-18Z) = 1.2666 SNB Position Chemical shift H Chemical shift Couplings... C-1 84.2326 H-1 4.7331 J(H-1,H-2) = 9.7385 C-2 74.7015 H-2 3.3325 J(H-2,H-1) = 9.7385 J(H-2,H-3) = 8.8164 C-3 79.8912 H-3 3.3428 J(H-3,H-2) = 8.8164 J(H-3,H-4) = 9.3272 C-4 71.6443 H-4 3.4176 J(H-4,H-3) = 9.3272 J(H-4,H-5) = 9.8907 C-5 82.7585 H-5 3.2495 J(H-5,H-4) = 9.8907 J(H-5,H-6S) = 2.303 J(H-5,H-6R) = 5.1269 C-6 63.155 H-6R 3.6618 J(H-6R,H-5) = 5.1269 J(H-6R,H-6S) = -12.6827 H-6S 3.6808 J(H-6S,H-5) = 2.303 J(H-6S,H-6R) = -12.6827 C-7 165.8558 C-8 40.4058 H-8R 4.0673 J(H-8R,H-8S) = -16.276 H-8S 4.0465 J(H-8S,H-8R) = -16.276 N-10 346.316 C-17 132.3987 C-18 129.7061 H-18 7.2861 J(H-18,H-19) = 8.4718 J(H-18,H-21) = 0.2572 J(H-18,H-22) = 2.886 C-19 118.8253 H-19 6.9316 J(H-19,H-18) = 8.4718 J(H-19,H-21) = 2.5534 J(H-19,H-22) = 0.2572 C-20 157.7448 C-21 118.8253 H-21 6.9316 J(H-21,H-18) = 0.2572 J(H-21,H-19) = 2.5534 J(H-21,H-22) = 8.4718 C-22 129.7061 H-22 7.2861 J(H-22,H-18) = 2.886 J(H-22,H-19) = 0.2572 J(H-22,H-21) = 8.4718 DS-SNB Position Chemical shift H Chemical shift Couplings... C-1 83.9012 H-1 4.731 J(H-1,H-2) = 9.7786 C-2 74.8836 H-2 3.3277 J(H-2,H-1) = 9.7786 J(H-2,H-3) = 8.9613 C-3 79.9328 H-3 3.3532 J(H-3,H-2) = 8.9613 J(H-3,H-4) = 9.1769 C-4 71.697 H-4 3.4174 J(H-4,H-3) = 9.1769 J(H-4,H-5) = 9.9236 C-5 82.6321 H-5 3.243 J(H-5,H-4) = 9.9236 J(H-5,H-6S) = 2.2441 J(H-5,H-6R) = 5.1541 C-6 63.151 H-6R 3.6595 J(H-6R,H-5) = 5.1541 J(H-6R,H-6S) = -12.5865 H-6S 3.6886 J(H-6S,H-5) = 2.2441 J(H-6S,H-6R) = -12.5865 C-7 157.7493 C-8 40.1042 H-8R 3.9703 J(H-8R,H-8S) = -16.4633 H-8S 3.9523 J(H-8S,H-8R) = -16.4633 N-10 338.871 C-17 130.6118 C-18 132.276 H-18 7.2274 J(H-18,H-19) = 8.4366 J(H-18,H-21) = 0.29 J(H-18,H-22) = 2.7288 C-19 118.6763 H-19 6.9138 J(H-19,H-18) = 8.4366 J(H-19,H-21) = 2.7268 J(H-19,H-22) = 0.29 C-20 157.4949 C-21 118.6763 H-21 6.9138 J(H-21,H-18) = 0.29 J(H-21,H-19) = 2.7268 J(H-21,H-22) = 8.4366 C-22 132.276 H-22 7.2274 J(H-22,H-18) = 2.7288 J(H-22,H-19) = 0.29 J(H-22,H-21) = 8.4366