Published December 11, 2023
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Copper-cobalt double metal cyanides as green catalysts for phosphoramidate synthesis
Description
Phosphoramidates are common and widespread backbones of a great variety of fine chemicals, pharmaceuticals, additives and natural products. Conventional approaches to their synthesis make use of toxic chlorinated reagents and intermediates, which are sought to be avoided at an industrial scale. Here we report the coupling of phosphites and amines promoted by a Cu3[Co(CN)6]2-based double metal cyanide heterogeneous catalyst using I2 as additive for the synthesis of phosphoramidates.
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Additional details
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- Is published in
- Publication: 10.1038/s42004-023-00927-0 (DOI)
Dates
- Available
-
2023-09-01