Published December 11, 2023 | Version v1
Poster Open

Copper-cobalt double metal cyanides as green catalysts for phosphoramidate synthesis

  • 1. KULeuven

Description

Phosphoramidates are common and widespread backbones of a great variety of fine chemicals, pharmaceuticals, additives and natural products. Conventional approaches to their synthesis make use of toxic chlorinated reagents and intermediates, which are sought to be avoided at an industrial scale. Here we report the coupling of phosphites and amines promoted by a Cu3[Co(CN)6]2-based double metal cyanide heterogeneous catalyst using I2 as additive for the synthesis of phosphoramidates.

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Additional details

Related works

Is published in
Publication: 10.1038/s42004-023-00927-0 (DOI)

Funding

C-PlaNeT – Circular Plastics Network for Training 859885
European Commission

Dates

Available
2023-09-01