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This contribution aims at analysing the current understanding about the influence of Al distribution, zeolite topology, ligands/reagents and oxidation state on ions mobility in Cu-zeolites, and its relevance toward reactivity of the metal sites. The concept of Cu mobilization has been originally observed in the presence of ammonia, favouring the activation of oxygen by formation of NH3 oxo-bridged complexes in zeolites and opening a new perspective about the chemistry in single-site zeolite-based catalysts, in particular in the context of the NH3-mediated Selective Catalytic Reduction of NOx (NH3-SCR) processes. A different mobility of bare Cu+/Cu2+ ions has been documented too, showing for Cu+ a better mobilization than for Cu2+ also in absence of ligands. These concepts can have important consequences for the formation of Cu-oxo species, active and selective in other relevant reactions, such as the direct conversion of methane to methanol. Here, assessing the structure, the formation pathways and reactivity of Cu-oxo mono- or multimeric moieties still represents a challenging playground for chemical scientists. Translating the knowledge about Cu ions mobility and redox properties acquired in the context of NH3-SCR reaction into the field of direct conversion of methane to methanol can have important implications for a better understanding of transition metal ions redox properties in zeolites and for an improved design of catalysts and catalytic processes.
", "funding": [ { "award": { "acronym": "CHASS", "id": "00k4n6c32::955839", "identifiers": [ { "identifier": "https://cordis.europa.eu/projects/955839", "scheme": "url" } ], "number": "955839", "program": "H2020", "title": { "en": "Cu-CHA zeolite-based catalysts for the selective catalytic reduction of NOx in exhaust diesel gas: addressing the issue of Sulfur Stability" } }, "funder": { "id": "00k4n6c32", "name": "European Commission" } }, { "award": { "acronym": "CUBE", "id": "00k4n6c32::856446", "identifiers": [ { "identifier": "https://cordis.europa.eu/projects/856446", "scheme": "url" } ], "number": "856446", "program": "H2020", "title": { "en": "Unravelling the secrets of Cu-based catalysts for C-H activation" } }, "funder": { "id": "00k4n6c32", "name": "European Commission" } } ], "languages": [ { "id": "eng", "title": { "en": "English" } } ], "publication_date": "2022-08-25", "publisher": "Zenodo", "related_identifiers": [ { "identifier": "https://zenodo.org/record/7015254", "relation_type": { "id": "issupplementedby", "title": { "de": "Wird erg\u00e4nzt durch", "en": "Is supplemented by" } }, "resource_type": { "id": "dataset", "title": { "de": "Datensatz", "en": "Dataset" } }, "scheme": "url" } ], "resource_type": { "id": "publication-article", "title": { "de": "Zeitschriftenartikel", "en": "Journal article" } }, "rights": [ { "description": { "en": "The Creative Commons Attribution license allows re-distribution and re-use of a licensed work on the condition that the creator is appropriately credited." }, "icon": "cc-by-icon", "id": "cc-by-4.0", "props": { "scheme": "spdx", "url": "https://creativecommons.org/licenses/by/4.0/legalcode" }, "title": { "en": "Creative Commons Attribution 4.0 International" } } ], "subjects": [ { "subject": "selective catalytic reduction" }, { "subject": "Cu-zeolite" }, { "subject": "ion mobility" }, { "subject": "methane to methanol" }, { "subject": "redox" } ], "title": "Influence of ion mobility on the redox and catalytic properties of Cu ions in zeolites", "version": "Advance Article" }, "parent": { "access": { "owned_by": { "user": 267688 } }, "communities": { "default": "22304dca-c62b-4a16-99d4-041397b7eb28", "entries": [ { "access": { "member_policy": "open", "members_visibility": "public", "record_policy": "open", "review_policy": "open", "visibility": "public" }, "children": { "allow": false }, "created": "2021-11-28T14:48:44.498208+00:00", "custom_fields": {}, "deletion_status": { "is_deleted": false, "status": "P" }, "id": "22304dca-c62b-4a16-99d4-041397b7eb28", "links": {}, "metadata": { "curation_policy": "", "description": "Zenodo Community of the ITN project CHASS, University of Turin (Italy)", "page": "", "title": "CHASS @itnproject" }, "revision_id": 0, "slug": "chassproject", "updated": "2021-12-02T11:21:23.579920+00:00" }, { "access": { "member_policy": "open", "members_visibility": "restricted", "record_policy": "open", "review_policy": "closed", "visibility": "public" }, "children": { "allow": true }, "created": "2022-11-23T15:53:29.436323+00:00", "custom_fields": {}, "deletion_status": { "is_deleted": false, "status": "P" }, "id": "f0a8b890-f97a-4eb2-9eac-8b8a712d3a6c", "links": {}, "metadata": { "curation_policy": "The EU Open Research Repository serves as a repository for research outputs (data, software, posters, presentations, publications, etc) which have been funded under an EU research funding programme such as Horizon Europe, Euratom or earlier Framework Programmes.
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