Nickel Sulfide Microrockets as Self-Propelled Energy Storage Devices to Power Electronic Circuits “On-Demand”

Miniaturized energy storage devices are essential to power the growing number and variety of microelectronic technologies. Here, a concept of self-propelled microscale energy storage elements that can move, reach, and power electronic circuits is reported. Microrockets consisting of a nickel sulfide (NiS) outer layer and a Pt inner layer are prepared by template-assisted electrodeposition, and designed to store energy through NiS-mediated redox reactions and propel via the Pt-catalyzed decomposition of H2 O2 fuel. Scanning electrochemical microscopy allows visualizing and studying the energy storage ability of a single microrocket, revealing its pseudocapacitive nature. This proves the great potential of such technique in the field of micro/nanomotors. On-demand delivery of energy storage units to electronic circuits has been demonstrated by releasing microrockets on an interdigitated array electrode as an example of electronic circuit. Owing to their self-propulsion ability, they reach the active area of the electrode and, in principle, power its functions. These autonomously moving energy storage devices will be employed for next-generation electronics to store and deliver energy in previously inaccessible locations.


Introduction
Micro/nanomotors are micro/nanomaterials designed to autonomously move. [1,2] They are powered by chemical fuels extracted from their surroundings, for example hydrogen peroxide (H 2 O 2 ) and enzymes, [3,4] or by external energy sources such as light, magnetic, and acoustic fields. [5][6][7] Owing to their active motion, these tiny motors have demonstrated to greatly improve the mixing at the molecular level and to enhance the mass transfer in a wide range of processes that are commonly limited by passive diffusion. [8,9] As a consequence, they have emerged in various research fields, including environmental remediation, [10][11][12][13] sensing, [14][15][16] and biomedicine. [17][18][19] Moreover, they have been employed as self-motile building blocks for electronic applications. Like reparation of cracks in electronic circuits, [20,21] on-site H 2 -generation to power external devices, [22] and actuation of nanoelectromechanical devices. [23] The push toward miniaturized electronic devices has driven the need for the miniaturization of energy storage modules to power their functions. [24,25] Substantial progress has been made in the development of micro-batteries [26][27][28] and micro-supercapacitors. [29][30][31] They constitute a fundamental and irreplaceable component of microelectronic devices. Upon failure of the energy storage unit, such devices cannot perform any operation. Conventional repair techniques are not suitable for the localized delivery of energy storage modules and can affect the other components of the circuit. Therefore, the combination of a strong self-propulsion with excellent energy storage properties on the same element would open new opportunities in the repair and reconfiguration of microcircuits. Autonomously moving graphite-and Bi-based supercapacitive microswimmers have been reported for the removal of metals from water exploiting their charge storage mechanism. [32] In the field of electronics, self-propelled supercapacitors consisting of WS 2 -PANI/Pt microrobots have shown the ability to attach to circuits and enhance their capacity behavior, exhibiting an energy density of 0.07 mWh m −2 and a power density of 120 mW m −2 . [33] In this work, we demonstrate the on-demand delivery of self-motile microscale energy storage devices to electronic circuits with remarkably higher energy and power densities (Scheme 1). Among the various energy storage materials, nickel sulfide (NiS) has been selected due to its high theoretical capacity, good electrical conductivity, excellent redox reversibility, low-cost, and environmental sustainability. [34][35][36][37][38][39][40] Selfpropelled microrockets consisting of a NiS outer layer and a Pt catalytic inner layer were fabricated by template-assisted electrochemical deposition. Their motion due to Pt-catalyzed decomposition of H 2 O 2 fuel was investigated. A new approach based on scanning electrochemical microscopy (SECM) was designed to evaluate the charge stored and delivered by the single microrocket, revealing a pseudocapacitive energy storage mechanism. Our findings prove the great potential of this technique for the characterization of micro/nanomotors. As a proof of concept, microrockets were injected in an electronic circuit, an example microelectronic device, and owing to their self-propulsion, reached the active area of the circuit where they acted as add-on elements for energy storage with an energy density of 3.85 mWh m −2 and a power density of 11.5 W m −2 . Such autonomously moving energy storage units will play an important role in next-generation microelectronics for future on-demand energy delivery to previously inaccessible locations.

Results and Discussion
Advanced microrockets able to move across electronic circuits and store energy were fabricated by template-assisted electrodeposition. Figure 1a illustrates the main steps of the process: 1) the deposition of a NiS outer layer; 2) the deposition of a Pt inner layer; 3) template dissolution to release the microrockets. The NiS layer is the electrochemically active component of the microrocket, having the ability to store and deliver energy through the following redox reaction. [36,41] NiS OH NiSOH e On charging, NiS oxidizes to nickel sulfide hydroxide (NiSOH) with the ejection of an e − , while on discharging NiSOH reduces to NiS with the insertion of an e − .
The inner Pt layer represents the engine of the microrocket, allowing its self-propulsion through the catalytic decomposition of H 2 O 2 into H 2 O and O 2 bubbles. Subsequently, the tubular design of the microrocket, inspired by that of macroscale rockets, results in the generation of a jet-stream of O 2 bubbles which propels it in the opposite direction. [42] Microrockets morphology was studied by scanning electron microscopy (SEM). Their bilayered structure can be easily observed from the cross-view SEM image in Figure 1b. The NiS layer is very thin (≈100 nm) compared to the Pt layer (700-800 nm). A hole with diameter of ≈1 µm is left to enable the fuel to go inside the microrocket and react with the Pt layer. SEM images were recorded at lower magnification to evaluate microrockets uniformity in overall diameter and length ( Figure S1, Supporting Information). All microrockets display a high uniformity in diameter with an average value of ≈3 µm, which is in agreement with the pore size of the template used for their preparation. A remarkable uniformity is noted also for the lateral length (≈15 µm). To identify the minimum critical value of NiS layer thickness prohibiting the collapse of the tubular structure during template removal, microrockets were fabricated by reducing the number of CV cycles for NiS layer deposition from 50 to 20, keeping unaltered the conditions for Pt layer deposition. SEM images reported in Figure S2, Supporting Information, show a non-uniform and thinner (<50 nm) NiS layer, resulting in lower stability and thus broken microrockets after template removal (5-10 µm in lateral length). Consequently, the minimum NiS layer thickness prohibiting the collapse of the tubular structure is ≈100 nm, which can be deposited by 50 CV cycles. Elemental mapping by energy dispersive X-ray spectroscopy (EDX) was performed to confirm the uniform presence of Ni, S, and Pt (Figure 1c-f).
The valence states of Ni and S in the NiS layer were determined by X-ray photoelectron spectroscopy (XPS). Figure 1g reports the XPS spectrum of Ni 2p. Two doublets of peaks and their corresponding satellites are visualized and attributed to Ni 2p 3/2 and Ni 2p 1/2 . According to the literature, the peaks at binding energies of 853.8 and 871.1 eV are related to Ni 2+ , while those at 855.7 and 873.6 eV are associated to Ni 3+ . [34,40,41] The XPS spectrum of S 2p (Figure 1h) shows peaks at 162.3 and 163.5 eV corresponding to S 2− , and peaks at 164.3 and 165.6 eV assigned to S 2 2− . [43,44] The broad signal at 168 eV indicates the existence of surface SO 4 2− . These observations agree well with previous reports on NiS electrode materials. [34,36,40,41,45] Scheme 1. Self-propelled microrockets, consisting of a pseudocapacitive NiS outer layer and a Pt catalytic inner layer, act as autonomously moving energy storage devices to power electronic circuits "on-demand".
www.advancedsciencenews.com www.small-methods.com Microrockets self-propulsion is crucial to prove their ondemand delivery to electronic circuits. The bubble-propelled motion of microrockets is clearly observable in Figure 2a,b where circular trajectories recorded for 1 s in 1 and 3 wt% H 2 O 2 are shown (5 s long videos of microrockets motion are displayed in Movie S1, Supporting Information). It is worth noting that these are representative trajectories, and that microrockets move in random directions and for longer time. Figure 2c reports the average speed of more than 10 different microrockets in various concentrations of H 2 O 2 and in 0.1 wt% sodium dodecyl sulfate (SDS). Microrockets speed increases almost linearly with H 2 O 2 content. In particular, in 1 wt% H 2 O 2 microrockets speed is 75 ± 29 µm s −1 , and it remarkably increases up to 295 ± 17 µm s −1 in 2 wt% H 2 O 2 , and 399 ± 33 µm s −1 in 3 wt% H 2 O 2 .
Once attested microrockets propulsion ability, their energy storage performance was investigated. Generally, energy  www.advancedsciencenews.com www.small-methods.com storage materials are directly grown or deposited on a current collector to form a working electrode, and then tested in the standard electrochemical cell to evaluate their energy storage properties. [46] Here, we implemented a new methodology based on SECM to measure the amount of charge stored and delivered by the single microrocket. SECM is a powerful technique to study electrochemical characteristics of materials with a high spatial resolution. [47,48] SECM setup is schematically illustrated in Figure 3a. The electrochemically active material is placed at the bottom of an electrochemical cell, while the working electrode is an ultra-microelectrode (UME) whose motion can be controlled along x, y, and z directions. Commonly, SECM generates the information by recording the localized interaction between UME tip, a redox mediator and the sample. [49] In "feedback mode", this interaction is influenced by the distance between UME tip and sample, as well as its conductivity. [50] The electrolyte (1 m KOH in our experiments) contains a redox mediator (Fe 2+ /Fe 3+ ) which is oxidized or reduced at the UME tip, resulting in a steady-state current when it is in the bulk of the solution. As the UME tip approaches a material, the current changes. Above an insulating surface, like glass, the diffusion of the redox-active species toward the UME is impeded, www.advancedsciencenews.com www.small-methods.com resulting in a decrease of the current (negative feedback). [51] On the contrary, an increased current is achieved on a conductive surface (positive feedback) which allows, for instance, the spatially resolved imaging of transition metal dichalcogenide materials. [52][53][54] The analysis of single particles by SECM is a challenging yet attractive approach to measure the intrinsic electrochemical properties of microstructures and further improve them. [55,56] Single particle measurements with SECM are typically performed to examine its catalytic properties. [53,57,58] For the study of the energy storage capability of single particles, recently, scanning electrochemical cell microscopy has proven to provide valuable information for energy storage by revealing significant heterogeneity for the Li intercalation into individual LiMn 2 O 4 particles. [59] Therefore, the application of the SECM for single particle measurements in the field of micro/nanomotors for energy storage application represents a natural extension.
First, we used SECM to visualize isolated microrockets landed on the glass at the bottom of the electrochemical cell. Figure 3b reports the SECM imaging of one of them. It can be noted that the size of the microrockets observed by SECM (3 × 10 µm) is quite consistent with the size found by SEM (3 × 15 µm). To contact the single microrocket and carry out cyclic voltammetry (CV) measurements, the UME tip was moved down along the z direction. Figure 3c compares the CV curves obtained by contacting a single microrocket and the glass of the cell, both recorded at 100 mV s −1 scan rate. The CV curve of the glass is flat. Instead, the CV curve of the single microrocket encloses a larger area and is dominated by two faradaic redox peaks. Moreover, at 0.5 V versus Ag/AgCl a pronounced rise of the current is noted, ascribed to the high electrocatalytic activity of Ni-based materials toward the oxygen evolution reaction in alkaline media. [60] Redox peaks in CV are the characteristic signature of battery materials, as frequently reported for NiO and Ni(OH) 2 , [61][62][63][64][65] and are attributed to the redox couple NiS/NiSOH (reaction (1)).
The relationship between peak current and scan rate generally provides more insights on the energy storage mechanism. [61] Specifically, for a battery material the redox reaction is diffusion-controlled, and the peak current results proportional to the square root of the scan rate. Instead, for a "pseudocapacitive" material, the reaction is surface adsorption-controlled and peak current is linear with the scan rate. Thus, CV curves of isolated microrockets were measured at other scan rates (50,200, 300, 400 mV s −1 ) and are shown in Figure 3d. Both oxidation and reduction peak currents are proportional to the scan rate, as displayed in the inset in Figure 3d. This result suggests that despite battery-like redox peaks are present in CV curves, the redox reaction is confined to the surface of the NiS layer or in the near-surface region. This "extrinsic" pseudocapacitance has been previously discovered in nanoscale-engineered battery materials. [61] Given the thinness of the NiS layer (≈100 nm) in our microrockets, such pseudocapacitive behavior is not surprising. It is worth noting that reaction (1) is in principle reversible. Still, reduction peak current is systematically lower than oxidation peak current at all scan rates, indicating that the energy storage process is quasi-reversible. [66] Galvanostatic charge-discharge (GCD) measurements are usually preferred over CV to estimate the charge that conventional electrode materials can store and deliver. [46] SECM setup did not allow employing this approach for the single microrocket due to the presence of the redox mediator in the electrolyte. Hence, charge stored and delivered by the single microrocket were calculated by integrating the oxidation (charge stored) and reduction (charge delivered) peaks in CV curves using the following equation: [63] is the potential versus Ag/AgCl, and ν [V s −1 ] is the scan rate. For peaks integration, linear backgrounds have been considered, as illustrated in Figure 3c for the CV curve acquired at 100 mV s −1 scan rate. This method consented to avoid the possible contribution of the redox mediator. Therefore, measured charge values are ascribed only to the faradaic reactions controlled by the NiS layer. Figure 3e reports the values of stored and delivered charge as a function of the scan rate (values result from the average of 5 different microrockets). Typically, by increasing the scan rate the charge decreases. In fact, at higher scan rates electrolyte ions have less time to penetrate into the active material, consequently less sites are involved in the energy storage process. [67] Surprisingly, the stored charge is almost constant ≈3 nC for all scan rates, while the delivered charge increases from ≈1 nC at 50 mV s −1 to ≈2.5 nC at 400 mV s −1 . As a result, the columbic efficiency, calculated as the ratio between delivered and stored charge, increases with the scan rate. In particular, at 400 mV s −1 a single microrocket is able to deliver ≈80% of the stored charge.
The cycling life of the single microrocket was studied by 100 CV cycles at 200 mV s −1 scan rate. The delivered charge was calculated using equation (2) and reported in Figure 3f. The charge increases cycle by cycle, and after 100 cycles the microrocket is able to deliver 122% of 1st cycle charge, proving an exceptional stability. This increase suggests that the NiS layer is undergoing electrochemical activation during cycling rather than deterioration.
We used an interdigitated array (IDA) electrode to demonstrate the on-demand delivery of energy storage devices to electronic circuits. Microrockets were injected with 0.1 wt% SDS and 3 wt% H 2 O 2 outside of the interdigitated region, as indicated by the green arrow in the photo in Figure 4a. The quartz substrate of the IDA electrode allowed to record a video of microrockets insertion and motion across such region (Movie S2, Supporting Information), and the frame reported in Figure 4a shows the trajectories of several microrockets on the IDA electrode. Microrockets randomly landed on the interdigitated region. Once microrockets self-propulsion stopped due to fuel exhaustion, the solution was replaced with 1 m KOH and the IDA electrode was connected to a potentiostat to perform electrochemical measurements. Figure 4b compares the CV curves of the IDA electrode with and without microrockets injection, recorded at 100 mV s −1 scan rate. There is huge increase of the current and a larger CV in the presence of microrockets. This result confirms that a high number of microrockets successfully moved from the injection point to the interdigitated area, where they were trapped by adhesive force which allowed them www.advancedsciencenews.com www.small-methods.com to resist to the change of electrolyte. CV curves at different scan rates were also collected and reported in Figure 4c. Again, the current of oxidation and reduction peaks is proportional to the scan rate (inset in Figure 4c). Using equation (2), the stored and delivered charge was calculated and plotted versus the scan rate in Figure 4d. Differently from the single microrocket, both decrease with the scan rate. Thus, increasing the number of microrockets leads to an electrochemical behavior similar to standard electrode materials. Particularly, the ratio between the charge of several microrockets and the single microrocket revealed that ≈10 4 active microrockets reached the IDA region, where they store/deliver energy. A cycling test up to 500 CV cycles at 200 mV s −1 scan rate was also conducted, and Figure 4e displays the delivered charge versus cycle number. Similarly to the single microrocket, the charge of the 500th cycle is higher than the 1st one (123%), confirming an excellent stability. The low volume of the electrolyte on IDA electrode did not permit to further explore microrockets cycling stability because of the electrolyte evaporation. Nonetheless, a cycling test up to 1000 cycles for a NiS film on a screen-printed electrode, tested in a conventional electrochemical cell, proves that 134% of the initial charge is retained ( Figure S3, Supporting Information). The IDA electrode allowed to carry out GCD measurements at a constant current of 50, 70, and 100 µA, and the corresponding charge-discharge profiles are shown in Figure 4f. Based on these measurements and the geometrical parameters of the IDA electrode, it was estimated that the presence of microrockets on the circuit results in an energy density of 3.85 mWh m −2 and a power density of 11.5 W m −2 (Supporting Information). Compared to WS 2 -PANI/Pt microrobots where WS 2 nanoparticles are embedded in a PANI layer, [33] the energy density and power density of NiS microrockets are ≈50 and ≈100 times higher, respectively. This improvement is attributed to the uniform deposition of a fully active NiS layer, leading to a higher energy density. In addition, due to the thinness of the NiS layer, NiS microrockets can sustain fast charge/ discharge rates and higher power density. Microrockets navigability is highly desired for electronic applications, as it would allow to precisely guide microrockets toward the interdigitated electrode area reducing the number of microrockets landed onto non-active regions. Despite this aspect has not been considered in the present work, magnetic field-navigable microrockets can be obtained by depositing a thin ferromagnetic layer (Ni, Fe, Co) between Pt and NiS layers. [42] Then, their directionality can be controlled by using an external magnetic field.

Conclusions
In this work we developed self-propelled microrockets composed by a NiS outer layer and a Pt inner layer with the ability to store energy through NiS-mediated redox reaction and to move via the Pt-catalyzed decomposition of H 2 O 2 . The electrochemical features of the single microrocket were characterized by SECM. This represents the first application of SECM technique in the field of micro/nanomotors, proving its great potential in determining the intrinsic properties of such micromachines. It was found that a single microrocket can store a charge of ≈3 nC via a pseudocapacitive mechanism, with scan rate-dependent delivery of up to ≈80% at 400 mV s −1 . Cycling life study indicated that the single microrocket is very stable and increases its electrochemical activity during the first 100 charge-discharge cycles. Microrockets were used as self-motile energy storage devices to power on-demand electronic circuits with an energy density of 3.85 mWh m −2 and a power density of 11.5 W m −2 . This work foresees the employment of autonomously moving energy storage devices in next-generation electronics for future on-demand energy delivery to previously inaccessible locations. This research opens new innovative ways to approach re-configurable electronic devices.

Experimental Section
Microrockets Fabrication: Microrockets composed by a NiS outer layer and a Pt inner layer were prepared by template-assisted electrodeposition. [68] A Whatman Cyclopore polycarbonate membrane (3 µm pore size) served as the template. The membrane was coated on one side with a 90 nm thick Au layer by electron-beam evaporation and stuck on a piece of copper tape to fabricate a working electrode. An electrochemical cell was designed to expose ≈2.54 cm 2 of the working electrode. A Pt counter electrode and an Ag/AgCl (1 m KCl) reference electrode were also used. The three-electrode electrochemical cell was connected to a Metrohm AUTOLAB potentiostat. The solution for NiS electrodeposition (2 ml) consisted of 5 mm NiSO 4 ·6H 2 O (Merck, ≥98%) and 0.5 m thiourea (Merck, ≥99%) in deionized water. [69] The deposition was carried out through 50 cycles of CV between −1.2 and 0.2 V versus Ag/AgCl at a scan rate of 50 mV s −1 . The inner layer of Pt was deposited by chronopotentiometry at −20 mA for 800 s using a commercial Pt plating solution (Singapore). [33] The polycarbonate membrane was detached from the copper tape, rinsed with deionized water, and hand polished with a slurry formed by 5 µm large alumina particles and water to remove the Au layer. Subsequently, the membrane was sonicated for 5 min in deionized water and dissolved in dichloromethane under vigorous agitation to induce polycarbonate dissolution, releasing the microrockets. These were cleaned three times with organic solvents at increasing polarity (dichloromethane, isopropanol, ethanol) and with deionized water. Each cleaning step comprised intense stirring via vortex agitation for 5 min and centrifugation at 5000 rpm for 3 min to separate the solvent from microrockets. Microrockets were finally stored in 1 ml deionized water at room temperature. An additional sample was prepared under the same conditions by reducing the number of CV cycles for NiS deposition from 50 to 20.
Morphological, Elemental, Chemical, and Electrochemical Characterization: Microrockets morphology and elemental composition were characterized by a Tescan MIRA 3 XMU SEM equipped with an EDX detector (Oxford Instruments). The chemical composition was examined by XPS Kratos Analytical Axis Supra, using monochromatic Al K α (1486.7 eV) excitation source. For this purpose, a NiS film was electrodeposited on a commercial screen printed electrode (Zensor, NCZSPE101, graphite working electrode) using the same procedure described above. All peaks were calibrated to the adventitious C 1s peak at 284.8 eV. XPS spectra were fitted using CasaXPS software. A commercial SECM (Sensolytics, Germany) equipped with an AUTOLAB Bipotentiostat (Metrohm, Netherlands) was used for imaging and electrochemical energy storage measurements of the single microrocket. Commercial Pt disc UME (Sensolytics, Germany) with, respectively, 5 and 25 µm electrode diameter and a tip-to-electrode ratio (RG) >10 were used as probes. All measurements were performed in 1 m KOH with 10 mm K 3/4 Fe(CN 6 ) using a Pt counter electrode, and an Ag/AgCl (3 m KCl) reference electrode. Gwyddion 2.55 was used for image processing. Microrockets Motion Behavior: Microrockets self-propulsion was recorded using a Nikon ECLIPSE Ti2 inverted optical microscope equipped with a Hamamatsu digital camera C13440-20CU. In a typical experiment, an aqueous solution of microrockets, 0.1 wt% SDS (Merck, ≥98%) and H 2 O 2 (Merck) at different concentrations (1, 2, 3 wt%), was dropped on a glass slide. NIS Elements Advanced Research software was used to record videos of microrockets at 20 fps. Videos were analyzed using Fiji software to get microrockets trajectories and measure their speed. The reported speed values result from the average of at least 10 different microrockets.
Single Microrocket Electrochemical Measurements: The electrochemical cell of the SECM setup was assembled with a glass side as substrate and filled with ≈5 mL of the mediator solution. A random distribution of the microrockets on the substrate was ensured by the careful addition of 50 µL of the microrocket suspension near the glass slide. Before SECM imaging, the 5 µm diameter UME was approached toward the glass slide with negative feedback and retrieved to imaging distance of ≈7-8 µm. SECM imaging was done in feedback mode with constant height and increment distance of 3 µm, 100 µm s −1 scan speed and 4 ms waiting time. All feedback mode measurements were performed with E UME = 0.5 V. For the analysis of the single microrocket, the 25 µm diameter UME was first used to scan the substrate in feedback mode to localize the microrocket. Afterward, the UME was retrieved and positioned above the microrocket. To establish the contact between microrocket and UME, a feedback mode approach was performed at 50 µm s −1 maximum scan speed and step width of 0.5 µm with 10 ms waiting time, and manually stopped immediately after observing the contact. Afterward, the charging and discharging ability of the single microrocket was tested via CV at different scan rates (50,100,200, 300, 400 mV s −1 ).
Microrockets Motion and Electrochemical Measurements on Electronic Circuits: An IDA electrode (ALS Co., Ltd) was used, consisting of a quartz www.advancedsciencenews.com www.small-methods.com substrate (20 × 12 × 0.5 mm) coated with a Ti adhesion layer (10 nm) and 90 nm thick Au working, counter, and pseudo-reference electrodes. The working electrode was formed by an anode and a cathode made of arrays of fingers (total number of fingers pairs was 65) with width of 10 µm, length of 2 mm and inter-finger spacing of 5 µm. The estimated exposed area of the working electrode was 2.6 mm 2 . An aqueous solution of SDS and H 2 O 2 was dropped on the electrode. Then, microrockets solution (100 µL) was injected close to the edge of the drop, and thus outside of the IDA region. The final concentration of SDS and H 2 O 2 in the drop was 0.1 and 3 wt%, as in motion experiments. Microrockets motion across the IDA electrode was recorded. Then, the drop was replaced with 100 µL of 1 m KOH. The IDA electrode was connected to a potentiostat in single mode. CV measurements were performed between 0 and 0.65 V versus pseudo-reference electrode at scan rates of 50, 100, 200, 300, 400 mV s −1 .
For comparison, the CV curve of a bare IDA electrode in 1 m KOH was acquired in the same potential window at a scan rate of 100 mV s −1 . GCD measurements were performed between 0 and 0.6 V versus pseudoreference electrode at constant currents of 50, 70, and 100 µA.

Supporting Information
Supporting Information is available from the Wiley Online Library or from the author.