Journal article Open Access

Methylhydrazinium Lead Bromide: Noncentrosymmetric Three-Dimensional Perovskite with Exceptionally Large Framework Distortion and Green Photoluminescence

Ma̧czka, Mirosl̷aw; Ptak, Maciej; Ga̧gor, Anna; Stefańska, Dagmara; Zarȩba, Jan K.; Sieradzki, Adam


MARC21 XML Export

<?xml version='1.0' encoding='UTF-8'?>
<record xmlns="http://www.loc.gov/MARC21/slim">
  <leader>00000nam##2200000uu#4500</leader>
  <controlfield tag="005">20220113134900.0</controlfield>
  <controlfield tag="001">5845302</controlfield>
  <datafield tag="700" ind1=" " ind2=" ">
    <subfield code="0">(orcid)0000-0002-4639-2367</subfield>
    <subfield code="a">Ptak, Maciej</subfield>
  </datafield>
  <datafield tag="700" ind1=" " ind2=" ">
    <subfield code="a">Ga̧gor, Anna</subfield>
  </datafield>
  <datafield tag="700" ind1=" " ind2=" ">
    <subfield code="a">Stefańska, Dagmara</subfield>
  </datafield>
  <datafield tag="700" ind1=" " ind2=" ">
    <subfield code="0">(orcid)0000-0001-6117-6876</subfield>
    <subfield code="a">Zarȩba, Jan K.</subfield>
  </datafield>
  <datafield tag="700" ind1=" " ind2=" ">
    <subfield code="0">(orcid)0000-0003-4136-5754</subfield>
    <subfield code="a">Sieradzki, Adam</subfield>
  </datafield>
  <datafield tag="856" ind1="4" ind2=" ">
    <subfield code="s">1670770</subfield>
    <subfield code="z">md5:d535146eaa3c1bee0528b127a608bf87</subfield>
    <subfield code="u">https://zenodo.org/record/5845302/files/methylhydrazinium-lead-bromide-noncentrosymmetric-three-dimensional-perovskite-with-exceptionally-large-framework-distortion-and-green-photoluminescence.pdf</subfield>
  </datafield>
  <datafield tag="542" ind1=" " ind2=" ">
    <subfield code="l">open</subfield>
  </datafield>
  <datafield tag="260" ind1=" " ind2=" ">
    <subfield code="c">2020-01-24</subfield>
  </datafield>
  <datafield tag="909" ind1="C" ind2="O">
    <subfield code="p">openaire</subfield>
    <subfield code="o">oai:zenodo.org:5845302</subfield>
  </datafield>
  <datafield tag="909" ind1="C" ind2="4">
    <subfield code="c">1667-1673</subfield>
    <subfield code="n">4</subfield>
    <subfield code="p">Chemistry of Materials</subfield>
    <subfield code="v">32</subfield>
  </datafield>
  <datafield tag="100" ind1=" " ind2=" ">
    <subfield code="0">(orcid)0000-0003-2978-1093</subfield>
    <subfield code="a">Ma̧czka, Mirosl̷aw</subfield>
  </datafield>
  <datafield tag="245" ind1=" " ind2=" ">
    <subfield code="a">Methylhydrazinium Lead Bromide: Noncentrosymmetric Three-Dimensional Perovskite with Exceptionally Large Framework Distortion and Green Photoluminescence</subfield>
  </datafield>
  <datafield tag="540" ind1=" " ind2=" ">
    <subfield code="a">Other (Open)</subfield>
  </datafield>
  <datafield tag="650" ind1="1" ind2="7">
    <subfield code="a">cc-by</subfield>
    <subfield code="2">opendefinition.org</subfield>
  </datafield>
  <datafield tag="520" ind1=" " ind2=" ">
    <subfield code="a">Three-dimensional (3D) lead halide perovskites have emerged as a promising class of coordination polymers for solar cells, photodetectors, and light-emitting devices. These compounds thus far comprise methylammonium, formamidinium, or cesium as cations. In this work, we introduce a new methylhydrazinium 3D perovskite, CH3NH2NH2PbBr3, that crystallizes in the polar P21 structure at room temperature and undergoes a phase transition to the cubic Pm3̅m phase at 418 K. This perovskite exhibits strong second-harmonic generation activity, features switchable dielectric behavior, thermochromism, and two-photon energy upconversion under 800 nm excitation.</subfield>
  </datafield>
  <datafield tag="024" ind1=" " ind2=" ">
    <subfield code="a">10.1021/acs.chemmater.9b05273</subfield>
    <subfield code="2">doi</subfield>
  </datafield>
  <datafield tag="980" ind1=" " ind2=" ">
    <subfield code="a">publication</subfield>
    <subfield code="b">article</subfield>
  </datafield>
</record>
8
7
views
downloads
Views 8
Downloads 7
Data volume 11.7 MB
Unique views 7
Unique downloads 5

Share

Cite as