5843241
doi
10.5281/zenodo.5843241
oai:zenodo.org:5843241
A. K. Panda
A. Mahapatra
S. B. Patjoshi
Synthesis of complexes of N-benzoyl-N' -(2-hydroxyphenyl)thiocarbaniide with some bivalent transition metal ions
D. C. Dash
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electronic spectral
octahedral environment
<p>P. G. Department of Chemistry, Sambalpur University, Jyoti Vihar, Burla, Sambalpur-768 019. India</p>
<p><em>E-mail : </em><a href="mailto:dcdash@rediffmail.com">dcdash@rediffmail.com</a></p>
<p><em>Manuscript received 21 May 2001, revised </em>9 <em>November 2001, accepted 21 March 2002</em></p>
<p>A series of binuclear complexes of types [M<sub>2</sub>(BPT)<sub>2</sub>(H<sub>2</sub>O)<sub>4</sub>] and [M<sub>2</sub>(BPT)<sub>2</sub>L<sub>4</sub>], where H<sub>2</sub>BPT = <em>N</em>-benzoyl-<em>N'</em>-(2-hydroxyphenyl)- thiocarbamide, L = pyridine or picolines (a,(3,7), M = Cu<sup>ll</sup>, Co<sup>ll</sup> and Ni<sup>ll</sup> have been synthesized. The ligand acts as a tridentate dibasic donor coordinating through carbonyl oxygen, thiocarbamido sulfur and deprotonated phenolic oxygen to yield the metal complexes in which water is replaceable by pyridine or picolines.</p>
<p>The magnetic and electronic spectral data indicate the complexes to he in an approximately octahedral environment, the symmetry being O<sub>h</sub> for the Co<sup>ll</sup> and D<sub>4h</sub>, for others. Crystal field parameters for the Co<sup>ll</sup> and distortion parameters for the Ni<sup>ll</sup> complexes on the basis of proposed geometry have been calculated.</p>
Zenodo
2002-08-31
info:eu-repo/semantics/article
5843240
1642081737.278209
295637
md5:2beb493801f52c72ad90f49a7cdc0061
https://zenodo.org/records/5843241/files/642-644.pdf
public
10.5281/zenodo.5843240
isVersionOf
doi
Journal of Indian Chemical Society
Vol. 79
Aug 2002
642-644
2002-08-31