5763893
doi
10.5281/zenodo.5763893
oai:zenodo.org:5763893
user-gmpavan-lab
user-eu
R. Sasmal
JNCASR
C. Empereur-mot
SUPSI - DTI
D. Bochicchio
SUPSI - DTI
S. V. K. Kompella
JNCASR
K. Sharma
JNCASR
S. Dhiman
JNCASR
B. Sundaram
JNCASR
S. S. Agasti
JNCASR
G. M. Pavan
POLITO - DISAT, SUPSI - DTI
S. J. George
JNCASR
Research Data supporting "Self-Sorted, Random, and Block Supramolecular Copolymers via Sequence Controlled, Multicomponent Self-Assembly"
A. Sarkar
JNCASR
info:eu-repo/semantics/openAccess
Creative Commons Attribution 4.0 International
https://creativecommons.org/licenses/by/4.0/legalcode
multicomponent self-assembly
co-polymers
sequence control
<p>Raw research data supporting the article:</p>
<p>A. Sarkar, R. Sasmal, C. Empereur-mot, D. Bochicchio, S. V. K. Kompella, K. Sharma, S. Dhiman, B. Sundaram*, S. S. Agasti*, <strong>G. M. Pavan</strong>* and S. J. George*<br>
“Self-Sorted, Random and Block Supramolecular Co-polymers via Sequence Controlled, Multicomponent Self-Assembly”<br>
<a href="https://pubs.acs.org/doi/abs/10.1021/jacs.0c01822"><em>J. Am. Chem. Soc.</em> <strong>2020</strong>, <em>142</em>, 7606-7617</a></p>
<p>Multicomponent supramolecular copolymerization promises to construct complex nanostructures with emergent properties. However, even with two monomeric components, various possible outcomes such as self-sorted supramolecular homopolymers, a random (statistical) supramolecular copolymer, an alternate supramolecular copolymer, or a complex supramolecular block copolymer can occur, determined by their intermolecular interactions and monomer exchange dynamics and hence structural prediction is extremely challenging. Herein, we target this challenge and demonstrate unprecedented two-component sequence controlled supramolecular copolymerization by manipulating thermodynamic and kinetic routes in the pathway complexity of selfassembly of the constitutive monomers. Extensive molecular dynamics simulations provided useful mechanistic insights into the monomer exchange rates and free energy of interactions between the monomers that dictate the self-assembly pathway and sequence. The fluorescent nature of core-substituted naphthalene diimide monomers has been further utilized to characterize the three sequences via Structured Illumination Microscopy (SIM).</p>
Zenodo
2020-04-01
info:eu-repo/semantics/other
5763892
user-gmpavan-lab
user-eu
award_title=Modeling approaches toward bioinspired dynamic materials; award_number=818776; award_identifiers_scheme=url; award_identifiers_identifier=https://cordis.europa.eu/projects/818776; funder_id=00k4n6c32; funder_name=European Commission;
1638928128.115097
26278433620
md5:931e4fc3cfcd1d0c1530ed6080dedfd3
https://zenodo.org/records/5763893/files/data_for_10.1021_jacs.0c01822.zip
public
10.5281/zenodo.5763892
isVersionOf
doi