Title: Supplementary Data to Dual clumped isotope thermometry resolves kinetic biases in carbonate formation temperatures

Authors: David Bajnai, Weifu Guo, Christoph Spötl, Tyler B Coplen, Katharina Methner, Niklas Löffler, Emilija Krsnik, Eberhard Gischler, Maximilian Hansen, Daniela Henkel, Gregory D Price, Jacek Raddatz, Denis Scholz, Jens Fiebig

DOI: https://www.doi.org/10.5281/zenodo.3784963

Original publication: Bajnai et al. (2020) Dual clumped isotope thermometry resolves kinetic biases in carbonate formation temperatures, Nature Communications [https://doi.org/10.1038/s41467-020-17501-0]

All files in this dataset: © The Authors, CC-BY 4.0, Please cite the original publication.

Comments or suggestions should be addressed to david.bajnai uni-koeln de

#### Version 1 ####

Supplementary Data 1
The file contains data for all replicate analyses of equilibrated gases, and carbonate reference material (ETH 1, ETH 2, and ETH 3) for the April–August 2019 measurement period. The raw iso-tope values in this file are calculated with a uniform m/z 47.5 scaling factor of -1 for m/z 47–49. The values within were used to calculate the long-term ∆47 (CDES90) and ∆48 (CDES90) values for the standards.

Supplementary Data 2
The file contains data for all replicate analyses of equilibrated gases, carbonate reference material, and samples for the April–August 2019 measurement period. Replicates in this file are identical to those in Supplementary Data 1, except that here, the raw isotope values are calculated with empirically determined m/z 47.5 scaling factors.

Supplementary Data 3
The file contains data for all replicate analyses of equilibrated gases, carbonate reference material, and samples for the September–December 2019 measurement period. Raw isotope values are calculated using empirically determined m/z 47.5 scaling factors.

Supplementary Data 4
The file contains data for all replicate analyses of equilibrated gases, carbonate reference material, and samples for the January–March 2020 measurement period. Raw isotope values are calculated using empirically determined m/z 47.5 scaling factors.

Supplementary Data 5
The file contains the model output data simulating disequilibrium effects in δ18O, ∆63, and ∆64 for the cold-water cor-al, the warm-water coral, and the synthetic speleothem. The model parameters are detailed in the Methods section of the manuscript.

BC_code_v1
The R code used to generate the figures in the manuscript, compile Tables 1 and 2, and calculate Equations 1 to 3.

BC_data_v1
Excel file used by the R code. Values in this file are compiled from the Supplementary Data files.