Journal article Open Access
Nikolay Kalanda; Marta Yarmolich; Maksim Kutuzau; Alexander Gurskii; Maria do RosárioTeixeira Soares; Mindaugas Andrulevičius; Brigita Abakevičienė; Sigitas Tamulevičius
{ "inLanguage": { "alternateName": "eng", "@type": "Language", "name": "English" }, "description": "<p>The sequence of phase transformations during the crystallization of SrBaFeMoO<sub>6–δ </sub>by the solid-phase technique from a stoichiometric mixture of simple oxides SrCO<sub>3</sub> + BaCO<sub>3</sub> + 0.5Fe<sub>2</sub>O<sub>3</sub> + MoO<sub>3</sub>was studied. It has been established that the synthesis of barium – strontium ferromolybdate proceeds through a series of sequential - parallel stages. It was found that to minimize the effect of intermediate reaction products, it is necessary to use combined synthesis modes. As a result of using combined synthesis modes for annealing for 20 hours and T = 1443 K in vacuum of 10<sup>-5</sup>Torr at the pressure of residual oxygen gas 10<sup>-8 </sup>Pa, it was possible to obtain a single-phase barium – strontium ferromolybdate compound with superstructural ordering of iron and molybdenum cations.</p>", "license": "https://creativecommons.org/licenses/by/4.0/legalcode", "creator": [ { "affiliation": "Scientific-Practical Materials Research Centre of NAS of Belarus, P.Brovka Str. 19, Minsk 220072, Belarus", "@type": "Person", "name": "Nikolay Kalanda" }, { "affiliation": "Scientific-Practical Materials Research Centre of NAS of Belarus, P.Brovka Str. 19, Minsk 220072, Belarus", "@type": "Person", "name": "Marta Yarmolich" }, { "affiliation": "Scientific-Practical Materials Research Centre of NAS of Belarus, P.Brovka Str. 19, Minsk 220072, Belarus", "@type": "Person", "name": "Maksim Kutuzau" }, { "affiliation": "Belarusian State University of Informatics and Radioelectronics, P.Brovka Str. 6, Minsk 220013, Belarus", "@type": "Person", "name": "Alexander Gurskii" }, { "affiliation": "LCA/CICECO, Universidade de Aveiro, 3810-193 Aveiro, Portugal", "@type": "Person", "name": "Maria do Ros\u00e1rioTeixeira Soares" }, { "affiliation": "Institute of Materials Science, Kaunas University of Technology, Bar\u0161auskoStr. 59, Kaunas LT-51423, Lithuania", "@type": "Person", "name": "Mindaugas Andrulevi\u010dius" }, { "affiliation": "Department of Physics, Kaunas University of Technology, Studentu Str. 50, Kaunas LT-51368, Lithuania", "@type": "Person", "name": "Brigita Abakevi\u010dien\u0117" }, { "affiliation": "Institute of Materials Science, Kaunas University of Technology, Bar\u0161auskoStr. 59, Kaunas LT-51423, Lithuania", "@type": "Person", "name": "Sigitas Tamulevi\u010dius" } ], "headline": "Degree of phase transformations in the conditions of polythermal synthesis of Sr2\u2013xBaxFeMoO6\u2013\u03b4", "image": "https://zenodo.org/static/img/logos/zenodo-gradient-round.svg", "datePublished": "2020-04-30", "url": "https://zenodo.org/record/3700064", "version": "Author Accepted Manuscript", "keywords": [ "magnetic metal oxide compound", "double perovskite", "polythermal synthesis", "differential thermal analysis", "thermogravimetric analysis", "crystallization rate", "sequence and degree of phase transformations" ], "@context": "https://schema.org/", "identifier": "https://doi.org/10.5281/zenodo.3700064", "@id": "https://doi.org/10.5281/zenodo.3700064", "@type": "ScholarlyArticle", "name": "Degree of phase transformations in the conditions of polythermal synthesis of Sr2\u2013xBaxFeMoO6\u2013\u03b4" }
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