September 12, 2017 Journal article Open Access

Artem Shylo; Aleksandr Doroshkevich; Tetyana Konstantinova

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  <identifier identifierType="DOI">10.5281/zenodo.3693928</identifier>
  <creators>
    <creator>
      <creatorName>Artem Shylo</creatorName>
    </creator>
    <creator>
      <creatorName>Aleksandr Doroshkevich</creatorName>
    </creator>
    <creator>
      <creatorName>Tetyana Konstantinova</creatorName>
    </creator>
  </creators>
  <titles>
    <title>INFLUENCE OF A PULSED MAGNETIC FIELD ON THE ELECTRICAL  PROPERTIES OF NANOPOWDER SYSTEM BASED ON ZIRCONIA</title>
  </titles>
  <publisher>Zenodo</publisher>
  <publicationYear>2017</publicationYear>
  <dates>
    <date dateType="Issued">2017-09-12</date>
  </dates>
  <resourceType resourceTypeGeneral="Text">Journal article</resourceType>
  <alternateIdentifiers>
    <alternateIdentifier alternateIdentifierType="url">https://zenodo.org/record/3693928</alternateIdentifier>
  </alternateIdentifiers>
  <relatedIdentifiers>
    <relatedIdentifier relatedIdentifierType="DOI" relationType="IsVersionOf">10.5281/zenodo.3693927</relatedIdentifier>
  </relatedIdentifiers>
  <rightsList>
    <rights rightsURI="https://creativecommons.org/licenses/by/4.0/legalcode">Creative Commons Attribution 4.0 International</rights>
    <rights rightsURI="info:eu-repo/semantics/openAccess">Open Access</rights>
  </rightsList>
  <descriptions>
    <description descriptionType="Abstract">&lt;p&gt;A &amp;nbsp;technique &amp;nbsp;for &amp;nbsp;studying &amp;nbsp;of &amp;nbsp;electrical &amp;nbsp;characteristics &amp;nbsp;based &amp;nbsp;on &amp;nbsp;electrochemical &amp;nbsp;impedance&amp;nbsp;&lt;br&gt;
spectroscopy of sealed nanopowder compact sets from a powder based on ZrO2 was proposed.&amp;nbsp;&lt;br&gt;
The possibility of using this technique for studying of influence of pulsed magnetic field on a&amp;nbsp;&lt;br&gt;
charge state of the surface of zirconia nanoparticles is shown. It is established that the action of a&amp;nbsp;&lt;br&gt;
weak pulsed &amp;nbsp;magnetic &amp;nbsp;field leads to redistribution of free &amp;nbsp;charge carriers between the volume&amp;nbsp;&lt;br&gt;
and &amp;nbsp;the &amp;nbsp;surface &amp;nbsp;of &amp;nbsp;nanoparticles. &amp;nbsp;In &amp;nbsp;particular, &amp;nbsp;different &amp;nbsp;processing &amp;nbsp;times &amp;nbsp;lead &amp;nbsp;to &amp;nbsp;different&amp;nbsp;&lt;br&gt;
impedance behaviour: treatment of a pulsed magnetic field with a pulse repetition frequency f =&amp;nbsp;&lt;br&gt;
1 Hz and an exposure time t &amp;lt;15 min leads to an irreversible decrease in the conductivity of the&amp;nbsp;&lt;br&gt;
nanoparticle surface by two times (from 3.47 &amp;bull; 10-5 to 1.72 &amp;bull; 10-5 Ohm-1 &amp;bull; m-1), and processing&amp;nbsp;&lt;br&gt;
with exposure time 15 &amp;lt;t &amp;lt;90 min leads to its increase by 10 times. Thus, the treatment of PMF&amp;nbsp;&lt;br&gt;
causes &amp;nbsp;formation &amp;nbsp;in &amp;nbsp;the &amp;nbsp;near-surface &amp;nbsp;zone &amp;nbsp;of &amp;nbsp;nanoparticles &amp;nbsp;of &amp;nbsp;a &amp;nbsp;region &amp;nbsp;depleted &amp;nbsp;of &amp;nbsp;charge&amp;nbsp;&lt;br&gt;
carriers.&lt;/p&gt;</description>
  </descriptions>
  <fundingReferences>
    <fundingReference>
      <funderName>European Commission</funderName>
      <funderIdentifier funderIdentifierType="Crossref Funder ID">10.13039/501100000780</funderIdentifier>
      <awardNumber awardURI="info:eu-repo/grantAgreement/EC/H2020/691010/">691010</awardNumber>
      <awardTitle>Advanced Humidity to Electricity Converter</awardTitle>
    </fundingReference>
  </fundingReferences>
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