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Challenges in Sr2FeMoO6−δ Thin Film Deposition

Gunnar Suchaneck; Nikolay Kalanda; Evgenij Artsiukh; Gerald Gerlach


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{
  "inLanguage": {
    "alternateName": "eng", 
    "@type": "Language", 
    "name": "English"
  }, 
  "description": "<p>This work reviews some fundamental issues that are relevant for the fabrication of stable\u2010phase strontium ferromolybdate thin films. The main challenges for strontium ferromolybdate thin film deposition arise from the sensitivity of the material&#39;s magnetic properties to point defect formation: i) Antisite defect formation and oxygen nonstoichiometry should be avoided by precise composition control during film manufacturing; ii) a highly ordered state of the correct phase and B\u2010site cation valence will be obtained only in a very narrow window of growth conditions; iii) to avoid additional antisite disorder with decreasing synthesis temperature, the effective temperature at the film surface should be increased by an energy flux to the growing film surface. Since thin film deposition is nonequilibrium in nature, the review starts with the consideration of equilibrium phase stability. Cation and oxygen stoichiometries are analyzed with regard to their effect on key magnetic properties. Film strain formed due to thermal and lattice mismatch is of great concern since it influences the choice of the substrate. Finally, thin film deposition techniques are valued for their benefits in strontium ferromolybdate thin film technology.</p>", 
  "license": "https://creativecommons.org/licenses/by/4.0/legalcode", 
  "creator": [
    {
      "affiliation": "Solid State Electronics Laboratory, TU Dresden, Dresden, 01062 Germany", 
      "@id": "https://orcid.org/0000-0002-9440-2232", 
      "@type": "Person", 
      "name": "Gunnar Suchaneck"
    }, 
    {
      "affiliation": "SSPA Scientific and Practical Materials Research Center of NAS of Belarus, Division of Cryogenic Research, Minsk, 220072 Belarus", 
      "@id": "https://orcid.org/0000-0001-7679-4968", 
      "@type": "Person", 
      "name": "Nikolay Kalanda"
    }, 
    {
      "affiliation": "SSPA Scientific and Practical Materials Research Center of NAS of Belarus, Division of Cryogenic Research, Minsk, 220072 Belarus", 
      "@type": "Person", 
      "name": "Evgenij Artsiukh"
    }, 
    {
      "affiliation": "Solid State Electronics Laboratory, TU Dresden, Dresden, 01062 Germany", 
      "@id": "https://orcid.org/0000-0002-7062-9598", 
      "@type": "Person", 
      "name": "Gerald Gerlach"
    }
  ], 
  "headline": "Challenges in Sr2FeMoO6\u2212\u03b4 Thin Film Deposition", 
  "image": "https://zenodo.org/static/img/logos/zenodo-gradient-round.svg", 
  "datePublished": "2019-09-08", 
  "url": "https://zenodo.org/record/3665613", 
  "version": "Version of Record", 
  "keywords": [
    "magnetic properties", 
    "point defects", 
    "stoichiometry", 
    "strontium ferromolybdate", 
    "thin films"
  ], 
  "@context": "https://schema.org/", 
  "identifier": "https://doi.org/10.1002/pssb.201900312", 
  "@id": "https://doi.org/10.1002/pssb.201900312", 
  "@type": "ScholarlyArticle", 
  "name": "Challenges in Sr2FeMoO6\u2212\u03b4 Thin Film Deposition"
}
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