Michael Badoux
Andreas F.M. Kilbinger
2017-05-17
<p>The polymerization of aromatic para-amino acid ester derivatives was studied using model compounds. Mechanistic and kinetic experiments led to the discovery of some side reactions. Finally, high molecular weight poly(<em>p</em>-benzamide)s were synthesized and characterized. The use of highly reactive pentafluorophenol ester lead to polymers up to molecular weights of around 50 000 Da. Poly(benzamides) carrying both <em>N</em>-alkyl or <em>N</em>-benzyl groups on the amine could be polymerized to high molecular weight.</p>
https://doi.org/10.1021/acs.macromol.7b00515
oai:zenodo.org:3475309
Zenodo
info:eu-repo/semantics/openAccess
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Synthesis of High Molecular Weight Poly(p-benzamide)s
info:eu-repo/semantics/article