3475233
doi
10.5281/zenodo.3475233
oai:zenodo.org:3475233
Mohammad Yasir
Albert Ruggi
Andreas F.M. Kilbinger
Heterotelechelic Polymers by Ring‐Opening Metathesis and Regioselective Chain Transfer
Peng Liu
info:eu-repo/semantics/openAccess
Creative Commons Attribution 3.0 Unported
https://creativecommons.org/licenses/by/3.0/legalcode
<p>Heterotelechelic polymers were synthesized by a kinetic telechelic ring‐opening metathesis polymerization method relying on the regioselective cross‐metathesis of the propagating Grubbs’ first‐generation catalyst with cinnamyl alcohol derivatives. This procedure allowed the synthesis of hetero‐bis‐end‐functional polymers in a one‐pot setup. The molecular weight of the polymers could be controlled by varying the ratio between cinnamyl alcohol derivatives and monomer. The end functional groups can be changed using different aromatically substituted cinnamyl alcohol derivatives. Different monomers were investigated and the presence of the functional groups was shown by NMR spectroscopy and MALDI‐ToF mass spectrometry. Labeling experiments with dyes were conducted to demonstrate the orthogonal addressability of both chain ends of the heterotelechelic polymers obtained.</p>
Zenodo
2017-12-06
info:eu-repo/semantics/article
3475232
1579540989.665194
649511
md5:c35f1f3288a0a9c850704422ca3c1fd1
https://zenodo.org/records/3475233/files/manuscript.pdf
public
10.5281/zenodo.3475232
isVersionOf
doi