Journal article Open Access

A π-conjugated, covalent phosphinine framework

Huang, Jieyang; Tarábek, Ján; Kulkarni, Ranjit; Wang, Cui; Dračínský, Martin; Smales, Glen J.; Tian, Yu; Ren, Shijie; Pauw, Brian R.; Resch-Genger, Ute; Bojdys, Michael J.


DataCite XML Export

<?xml version='1.0' encoding='utf-8'?>
<resource xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" xmlns="http://datacite.org/schema/kernel-4" xsi:schemaLocation="http://datacite.org/schema/kernel-4 http://schema.datacite.org/meta/kernel-4.1/metadata.xsd">
  <identifier identifierType="DOI">10.5281/zenodo.3342571</identifier>
  <creators>
    <creator>
      <creatorName>Huang, Jieyang</creatorName>
      <givenName>Jieyang</givenName>
      <familyName>Huang</familyName>
      <nameIdentifier nameIdentifierScheme="ORCID" schemeURI="http://orcid.org/">0000-0001-8169-7054</nameIdentifier>
      <affiliation>Humboldt-Universität zu Berlin</affiliation>
    </creator>
    <creator>
      <creatorName>Tarábek, Ján</creatorName>
      <givenName>Ján</givenName>
      <familyName>Tarábek</familyName>
      <affiliation>Institute of Organic Chemistry and Biochemistry of the CAS</affiliation>
    </creator>
    <creator>
      <creatorName>Kulkarni, Ranjit</creatorName>
      <givenName>Ranjit</givenName>
      <familyName>Kulkarni</familyName>
      <affiliation>Humboldt-Universität zu Berlin</affiliation>
    </creator>
    <creator>
      <creatorName>Wang, Cui</creatorName>
      <givenName>Cui</givenName>
      <familyName>Wang</familyName>
      <affiliation>Bundesanstalt für Materialforschung und -prüfung (BAM)</affiliation>
    </creator>
    <creator>
      <creatorName>Dračínský, Martin</creatorName>
      <givenName>Martin</givenName>
      <familyName>Dračínský</familyName>
      <affiliation>Institute of Organic Chemistry and Biochemistry of the CAS</affiliation>
    </creator>
    <creator>
      <creatorName>Smales, Glen J.</creatorName>
      <givenName>Glen J.</givenName>
      <familyName>Smales</familyName>
      <affiliation>Federal Institute for Materials Research and Testing (BAM)</affiliation>
    </creator>
    <creator>
      <creatorName>Tian, Yu</creatorName>
      <givenName>Yu</givenName>
      <familyName>Tian</familyName>
      <affiliation>Sichuan University</affiliation>
    </creator>
    <creator>
      <creatorName>Ren, Shijie</creatorName>
      <givenName>Shijie</givenName>
      <familyName>Ren</familyName>
      <affiliation>Sichuan University</affiliation>
    </creator>
    <creator>
      <creatorName>Pauw, Brian R.</creatorName>
      <givenName>Brian R.</givenName>
      <familyName>Pauw</familyName>
      <affiliation>Federal Institute for Materials Research and Testing (BAM)</affiliation>
    </creator>
    <creator>
      <creatorName>Resch-Genger, Ute</creatorName>
      <givenName>Ute</givenName>
      <familyName>Resch-Genger</familyName>
      <affiliation>Bundesanstalt für Materialforschung und -prüfung (BAM)</affiliation>
    </creator>
    <creator>
      <creatorName>Bojdys, Michael J.</creatorName>
      <givenName>Michael J.</givenName>
      <familyName>Bojdys</familyName>
      <nameIdentifier nameIdentifierScheme="ORCID" schemeURI="http://orcid.org/">0000-0002-2592-4168</nameIdentifier>
      <affiliation>Humboldt-Universität zu Berlin</affiliation>
    </creator>
  </creators>
  <titles>
    <title>A π-conjugated, covalent phosphinine framework</title>
  </titles>
  <publisher>Zenodo</publisher>
  <publicationYear>2019</publicationYear>
  <subjects>
    <subject>phosphinine</subject>
    <subject>conjugated microporous polymer</subject>
    <subject>photocatalysis</subject>
    <subject>heteroatom</subject>
  </subjects>
  <dates>
    <date dateType="Issued">2019-07-19</date>
  </dates>
  <resourceType resourceTypeGeneral="Text">Journal article</resourceType>
  <alternateIdentifiers>
    <alternateIdentifier alternateIdentifierType="url">https://zenodo.org/record/3342571</alternateIdentifier>
  </alternateIdentifiers>
  <relatedIdentifiers>
    <relatedIdentifier relatedIdentifierType="DOI" relationType="IsVersionOf">10.5281/zenodo.3342570</relatedIdentifier>
  </relatedIdentifiers>
  <rightsList>
    <rights rightsURI="http://creativecommons.org/licenses/by/4.0/legalcode">Creative Commons Attribution 4.0 International</rights>
    <rights rightsURI="info:eu-repo/semantics/openAccess">Open Access</rights>
  </rightsList>
  <descriptions>
    <description descriptionType="Abstract">&lt;p&gt;Structural modularity of polymer frameworks is a key advantage of covalent organic polymers, however, only C, N, O, Si and S have found their way into their building blocks so far. Here, we expand the toolbox available to polymer and materials chemists by one additional nonmetal, phosphorus. Starting with a building block that contains a &amp;lambda;&lt;sup&gt;5&lt;/sup&gt;-phosphinine (C&lt;sub&gt;5&lt;/sub&gt;P) moiety, we evaluate a number of polymerisation protocols, finally obtaining a &amp;pi;-conjugated, covalent phosphinine-based framework (CPF-1) &lt;em&gt;via&lt;/em&gt; Suzuki-Miyaura coupling. CPF-1 is a weakly porous polymer glass (72.4&amp;nbsp;m&lt;sup&gt;2&lt;/sup&gt;&amp;nbsp;g&lt;sup&gt;-1&lt;/sup&gt; N&lt;sub&gt;2&lt;/sub&gt; BET at 77&amp;nbsp;K) with green fluorescence (&amp;lambda;&lt;sub&gt;max&lt;/sub&gt; 546&amp;nbsp;nm) and extremely high thermal stability. The polymer catalyzes hydrogen evolution from water under UV and visible light irradiation without the need for additional co-catalyst at a rate of 33.3&amp;nbsp;&amp;mu;mol&amp;nbsp;h&lt;sup&gt;-1&lt;/sup&gt;&amp;nbsp;g&lt;sup&gt;-1&lt;/sup&gt;. Our results demonstrate for the first time the incorporation of the phosphinine motif into a complex polymer framework. Phosphinine-based frameworks show promising electronic and optical properties that might spark future interest in their applications in light-emitting devices and heterogeneous catalysis.&lt;/p&gt;</description>
  </descriptions>
  <fundingReferences>
    <fundingReference>
      <funderName>European Commission</funderName>
      <funderIdentifier funderIdentifierType="Crossref Funder ID">10.13039/501100000780</funderIdentifier>
      <awardNumber awardURI="info:eu-repo/grantAgreement/EC/H2020/678462/">678462</awardNumber>
      <awardTitle>Layered functional materials - beyond 'graphene'</awardTitle>
    </fundingReference>
  </fundingReferences>
</resource>
202
130
views
downloads
All versions This version
Views 202203
Downloads 130130
Data volume 140.8 MB140.8 MB
Unique views 180181
Unique downloads 108108

Share

Cite as