Journal article Open Access

A modified pseudo-steady-state analytical expression for battery modeling

Kudakwashe Chayambuka; Grietus Mulder; Dmitri L. Danilov; Prof. Peter H. L. Notten

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<oai_dc:dc xmlns:dc="" xmlns:oai_dc="" xmlns:xsi="" xsi:schemaLocation="">
  <dc:creator>Kudakwashe Chayambuka</dc:creator>
  <dc:creator>Grietus Mulder</dc:creator>
  <dc:creator>Dmitri L. Danilov</dc:creator>
  <dc:creator>Prof. Peter H. L. Notten</dc:creator>
  <dc:description>The solid-state spherical diffusion equation with flux boundary conditions is a standard problem in lithium-ion battery simulations. If finite difference schemes are applied, many nodes across a discretized battery electrode become necessary, in order to reach a good approximation of solution. Such a grid-based approach can be appropriately avoided by implementing analytical methods which reduce the computational load. The pseudo-steady-state (PSS) method is an exact analytical solution method, which provides accurate solid-state concentrations at all current densities. The popularization of the PSS method, in the existing form of expression, is however constrained by a solution convergence problem. In this short communication, a modified PSS (MPSS) expression is presented which provides uniformly convergent solutions at all times. To minimize computational runtime, a fast MPPS (FMPPS) expression is further developed, which is shown to be faster by approximately three orders of magnitude and has a constant time complexity. Using the FMPSS method, uniformly convergent exact solutions are obtained for the solid-state diffusion problem in spherical active particles.</dc:description>
  <dc:subject>Porous electrodes, Pseudo-steady state, Analytical methods, Spherical diffusion.</dc:subject>
  <dc:title>A modified pseudo-steady-state analytical expression for battery modeling</dc:title>
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