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Real-time optical and electronic sensing with a β-amino enone linked, triazine-containing 2D covalent organic framework

Kulkarni, Ranjit; Noda, Yu; Barange, Deepak K.; Kochergin, Yaroslav S.; Balcarova, Barbora; Lyu, Pengbo; Nachtigal, Petr; Bojdys, Michael J.


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        <foaf:name>Bojdys, Michael J.</foaf:name>
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    <dct:title>Real-time optical and electronic sensing with a β-amino enone linked, triazine-containing 2D covalent organic framework</dct:title>
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    <dcat:keyword>triazine</dcat:keyword>
    <dcat:keyword>covalent organic framework</dcat:keyword>
    <dcat:keyword>band gap tuning</dcat:keyword>
    <dcat:keyword>gas phase</dcat:keyword>
    <dcat:keyword>protonation</dcat:keyword>
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    <dct:description>&lt;p&gt;[This repository contains the source data for the manuscript &amp;quot;&lt;strong&gt;Real-time optical and electronic sensing with a &amp;beta;-amino enone linked, triazine-containing 2D covalent organic framework&lt;/strong&gt;&amp;quot; https://nature-research-under-consideration.nature.com/users/37265-nature-communications/posts/47951-a-real-time-optical-and-electronic-chemical-sensor-based-on-a-amino-enone-linked-triazine-containing-2d-covalent-organic-framework]&lt;/p&gt; &lt;p&gt;Fully-aromatic, two-dimensional covalent organic frameworks (2D COFs) are hailed as candidates for electronic and optical devices, yet to-date few applications emerged that make genuine use of their rational, predictive design principles and permanent pore structure. Here, we present a 2D COF made up of chemoresistant &amp;beta;-amino enone bridges and Lewis-basic triazine moieties that exhibits a dramatic real-time response in the visible spectrum and an increase in bulk conductivity by two orders of magnitude to a chemical trigger - corrosive HCl vapours. The optical and electronic response is fully reversible using a chemical switch (NH&lt;sub&gt;3&lt;/sub&gt; vapours) or physical triggers (temperature or vacuum). These findings demonstrate a useful application of fully-aromatic 2D COFs as real-time responsive chemosensors and switches.&lt;/p&gt;</dct:description>
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