There is a newer version of this record available.

Dataset Open Access

Real-time optical and electronic sensing with a β-amino enone linked, triazine-containing 2D covalent organic framework

Kulkarni, Ranjit; Noda, Yu; Barange, Deepak K.; Kochergin, Yaroslav S.; Balcarova, Barbora; Lyu, Pengbo; Nachtigal, Petr; Bojdys, Michael J.


JSON-LD (schema.org) Export

{
  "inLanguage": {
    "alternateName": "eng", 
    "@type": "Language", 
    "name": "English"
  }, 
  "description": "<p>[This repository contains the raw and source data for the manuscript &quot;<strong>Real-time optical and electronic sensing with a &beta;-amino enone linked, triazine-containing 2D covalent organic framework</strong>&quot;.]</p>\n\n<p>Fully-aromatic, two-dimensional covalent organic frameworks (2D COFs) are hailed as candidates for electronic and optical devices, yet to-date few applications emerged that make genuine use of their rational, predictive design principles and permanent pore structure. Here, we present a 2D COF made up of chemoresistant &beta;-amino enone bridges and Lewis-basic triazine moieties that exhibits a dramatic real-time response in the visible spectrum and an increase in bulk conductivity by two orders of magnitude to a chemical trigger - corrosive HCl vapours. The optical and electronic response is fully reversible using a chemical switch (NH<sub>3</sub> vapours) or physical triggers (temperature or vacuum). These findings demonstrate a useful application of fully-aromatic 2D COFs as real-time responsive chemosensors and switches.</p>", 
  "license": "http://creativecommons.org/licenses/by/4.0/legalcode", 
  "creator": [
    {
      "affiliation": "Humboldt-Universit\u00e4t zu Berlin", 
      "@id": "https://orcid.org/0000-0002-8251-1407", 
      "@type": "Person", 
      "name": "Kulkarni, Ranjit"
    }, 
    {
      "affiliation": "Humboldt-Universit\u00e4t zu Berlin", 
      "@id": "https://orcid.org/0000-0003-0715-5534", 
      "@type": "Person", 
      "name": "Noda, Yu"
    }, 
    {
      "affiliation": "Institute of Organic Chemistry and Biochemistry of the CAS", 
      "@id": "https://orcid.org/0000-0003-4286-4192", 
      "@type": "Person", 
      "name": "Barange, Deepak K."
    }, 
    {
      "affiliation": "Humboldt-Universit\u00e4t zu Berlin", 
      "@id": "https://orcid.org/0000-0002-9060-6350", 
      "@type": "Person", 
      "name": "Kochergin, Yaroslav S."
    }, 
    {
      "affiliation": "Institute of Organic Chemistry and Biochemistry of the CAS", 
      "@id": "https://orcid.org/0000-0001-6008-2480", 
      "@type": "Person", 
      "name": "Balcarova, Barbora"
    }, 
    {
      "affiliation": "Charles University in Prague", 
      "@id": "https://orcid.org/0000-0002-1785-9861", 
      "@type": "Person", 
      "name": "Lyu, Pengbo"
    }, 
    {
      "affiliation": "Charles University in Prague", 
      "@id": "https://orcid.org/0000-0002-1628-7275", 
      "@type": "Person", 
      "name": "Nachtigal, Petr"
    }, 
    {
      "affiliation": "Humboldt-Universit\u00e4t zu Berlin", 
      "@id": "https://orcid.org/0000-0002-2592-4168", 
      "@type": "Person", 
      "name": "Bojdys, Michael J."
    }
  ], 
  "url": "https://zenodo.org/record/2634565", 
  "datePublished": "2019-04-09", 
  "keywords": [
    "triazine", 
    "covalent organic framework", 
    "band gap tuning", 
    "gas phase", 
    "protonation"
  ], 
  "@context": "https://schema.org/", 
  "distribution": [
    {
      "contentUrl": "https://zenodo.org/api/files/7625b1b8-d869-45c6-be86-407c7523c3a8/Activation-deactivation for HCl and NH3 vapours (Optical responce).mp4", 
      "@type": "DataDownload", 
      "fileFormat": "mp4"
    }, 
    {
      "contentUrl": "https://zenodo.org/api/files/7625b1b8-d869-45c6-be86-407c7523c3a8/Raw Data-20190409.zip", 
      "@type": "DataDownload", 
      "fileFormat": "zip"
    }, 
    {
      "contentUrl": "https://zenodo.org/api/files/7625b1b8-d869-45c6-be86-407c7523c3a8/Source Data-20190409.zip", 
      "@type": "DataDownload", 
      "fileFormat": "zip"
    }
  ], 
  "identifier": "https://doi.org/10.5281/zenodo.2634565", 
  "@id": "https://doi.org/10.5281/zenodo.2634565", 
  "@type": "Dataset", 
  "name": "Real-time optical and electronic sensing with a \u03b2-amino enone linked, triazine-containing 2D covalent organic framework"
}
739
159
views
downloads
All versions This version
Views 739415
Downloads 159140
Data volume 14.3 GB11.8 GB
Unique views 603337
Unique downloads 4025

Share

Cite as