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Real-time optical and electronic sensing with a β-amino enone linked, triazine-containing 2D covalent organic framework

Kulkarni, Ranjit; Noda, Yu; Barange, Deepak K.; Kochergin, Yaroslav S.; Balcarova, Barbora; Lyu, Pengbo; Nachtigal, Petr; Bojdys, Michael J.


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    "description": "<p>[This repository contains the raw and source data for the manuscript &quot;<strong>Real-time optical and electronic sensing with a &beta;-amino enone linked, triazine-containing 2D covalent organic framework</strong>&quot;.]</p>\n\n<p>Fully-aromatic, two-dimensional covalent organic frameworks (2D COFs) are hailed as candidates for electronic and optical devices, yet to-date few applications emerged that make genuine use of their rational, predictive design principles and permanent pore structure. Here, we present a 2D COF made up of chemoresistant &beta;-amino enone bridges and Lewis-basic triazine moieties that exhibits a dramatic real-time response in the visible spectrum and an increase in bulk conductivity by two orders of magnitude to a chemical trigger - corrosive HCl vapours. The optical and electronic response is fully reversible using a chemical switch (NH<sub>3</sub> vapours) or physical triggers (temperature or vacuum). These findings demonstrate a useful application of fully-aromatic 2D COFs as real-time responsive chemosensors and switches.</p>", 
    "license": {
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    "title": "Real-time optical and electronic sensing with a \u03b2-amino enone linked, triazine-containing 2D covalent organic framework", 
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      "triazine", 
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    "publication_date": "2019-04-09", 
    "creators": [
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        "affiliation": "Humboldt-Universit\u00e4t zu Berlin", 
        "name": "Kulkarni, Ranjit"
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        "affiliation": "Humboldt-Universit\u00e4t zu Berlin", 
        "name": "Noda, Yu"
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        "orcid": "0000-0003-4286-4192", 
        "affiliation": "Institute of Organic Chemistry and Biochemistry of the CAS", 
        "name": "Barange, Deepak K."
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        "affiliation": "Humboldt-Universit\u00e4t zu Berlin", 
        "name": "Kochergin, Yaroslav S."
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        "affiliation": "Institute of Organic Chemistry and Biochemistry of the CAS", 
        "name": "Balcarova, Barbora"
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      {
        "orcid": "0000-0002-1785-9861", 
        "affiliation": "Charles University in Prague", 
        "name": "Lyu, Pengbo"
      }, 
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        "affiliation": "Charles University in Prague", 
        "name": "Nachtigal, Petr"
      }, 
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        "orcid": "0000-0002-2592-4168", 
        "affiliation": "Humboldt-Universit\u00e4t zu Berlin", 
        "name": "Bojdys, Michael J."
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