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Real-time optical and electronic sensing with a β-amino enone linked, triazine-containing 2D covalent organic framework

Kulkarni, Ranjit; Noda, Yu; Barange, Deepak K.; Kochergin, Yaroslav S.; Balcarova, Barbora; Lyu, Pengbo; Nachtigal, Petr; Bojdys, Michael J.


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  <identifier identifierType="DOI">10.5281/zenodo.2634565</identifier>
  <creators>
    <creator>
      <creatorName>Kulkarni, Ranjit</creatorName>
      <givenName>Ranjit</givenName>
      <familyName>Kulkarni</familyName>
      <nameIdentifier nameIdentifierScheme="ORCID" schemeURI="http://orcid.org/">0000-0002-8251-1407</nameIdentifier>
      <affiliation>Humboldt-Universität zu Berlin</affiliation>
    </creator>
    <creator>
      <creatorName>Noda, Yu</creatorName>
      <givenName>Yu</givenName>
      <familyName>Noda</familyName>
      <nameIdentifier nameIdentifierScheme="ORCID" schemeURI="http://orcid.org/">0000-0003-0715-5534</nameIdentifier>
      <affiliation>Humboldt-Universität zu Berlin</affiliation>
    </creator>
    <creator>
      <creatorName>Barange, Deepak K.</creatorName>
      <givenName>Deepak K.</givenName>
      <familyName>Barange</familyName>
      <nameIdentifier nameIdentifierScheme="ORCID" schemeURI="http://orcid.org/">0000-0003-4286-4192</nameIdentifier>
      <affiliation>Institute of Organic Chemistry and Biochemistry of the CAS</affiliation>
    </creator>
    <creator>
      <creatorName>Kochergin, Yaroslav S.</creatorName>
      <givenName>Yaroslav S.</givenName>
      <familyName>Kochergin</familyName>
      <nameIdentifier nameIdentifierScheme="ORCID" schemeURI="http://orcid.org/">0000-0002-9060-6350</nameIdentifier>
      <affiliation>Humboldt-Universität zu Berlin</affiliation>
    </creator>
    <creator>
      <creatorName>Balcarova, Barbora</creatorName>
      <givenName>Barbora</givenName>
      <familyName>Balcarova</familyName>
      <nameIdentifier nameIdentifierScheme="ORCID" schemeURI="http://orcid.org/">0000-0001-6008-2480</nameIdentifier>
      <affiliation>Institute of Organic Chemistry and Biochemistry of the CAS</affiliation>
    </creator>
    <creator>
      <creatorName>Lyu, Pengbo</creatorName>
      <givenName>Pengbo</givenName>
      <familyName>Lyu</familyName>
      <nameIdentifier nameIdentifierScheme="ORCID" schemeURI="http://orcid.org/">0000-0002-1785-9861</nameIdentifier>
      <affiliation>Charles University in Prague</affiliation>
    </creator>
    <creator>
      <creatorName>Nachtigal, Petr</creatorName>
      <givenName>Petr</givenName>
      <familyName>Nachtigal</familyName>
      <nameIdentifier nameIdentifierScheme="ORCID" schemeURI="http://orcid.org/">0000-0002-1628-7275</nameIdentifier>
      <affiliation>Charles University in Prague</affiliation>
    </creator>
    <creator>
      <creatorName>Bojdys, Michael J.</creatorName>
      <givenName>Michael J.</givenName>
      <familyName>Bojdys</familyName>
      <nameIdentifier nameIdentifierScheme="ORCID" schemeURI="http://orcid.org/">0000-0002-2592-4168</nameIdentifier>
      <affiliation>Humboldt-Universität zu Berlin</affiliation>
    </creator>
  </creators>
  <titles>
    <title>Real-time optical and electronic sensing with a β-amino enone linked, triazine-containing 2D covalent organic framework</title>
  </titles>
  <publisher>Zenodo</publisher>
  <publicationYear>2019</publicationYear>
  <subjects>
    <subject>triazine</subject>
    <subject>covalent organic framework</subject>
    <subject>band gap tuning</subject>
    <subject>gas phase</subject>
    <subject>protonation</subject>
  </subjects>
  <dates>
    <date dateType="Issued">2019-04-09</date>
  </dates>
  <language>en</language>
  <resourceType resourceTypeGeneral="Dataset"/>
  <alternateIdentifiers>
    <alternateIdentifier alternateIdentifierType="url">https://zenodo.org/record/2634565</alternateIdentifier>
  </alternateIdentifiers>
  <relatedIdentifiers>
    <relatedIdentifier relatedIdentifierType="DOI" relationType="IsSupplementTo">10.26434/chemrxiv.7973804</relatedIdentifier>
    <relatedIdentifier relatedIdentifierType="DOI" relationType="IsVersionOf">10.5281/zenodo.2634564</relatedIdentifier>
    <relatedIdentifier relatedIdentifierType="URL" relationType="IsPartOf">https://zenodo.org/communities/zenodo</relatedIdentifier>
  </relatedIdentifiers>
  <rightsList>
    <rights rightsURI="http://creativecommons.org/licenses/by/4.0/legalcode">Creative Commons Attribution 4.0 International</rights>
    <rights rightsURI="info:eu-repo/semantics/openAccess">Open Access</rights>
  </rightsList>
  <descriptions>
    <description descriptionType="Abstract">&lt;p&gt;[This repository contains the raw and source data for the manuscript &amp;quot;&lt;strong&gt;Real-time optical and electronic sensing with a &amp;beta;-amino enone linked, triazine-containing 2D covalent organic framework&lt;/strong&gt;&amp;quot;.]&lt;/p&gt;

&lt;p&gt;Fully-aromatic, two-dimensional covalent organic frameworks (2D COFs) are hailed as candidates for electronic and optical devices, yet to-date few applications emerged that make genuine use of their rational, predictive design principles and permanent pore structure. Here, we present a 2D COF made up of chemoresistant &amp;beta;-amino enone bridges and Lewis-basic triazine moieties that exhibits a dramatic real-time response in the visible spectrum and an increase in bulk conductivity by two orders of magnitude to a chemical trigger - corrosive HCl vapours. The optical and electronic response is fully reversible using a chemical switch (NH&lt;sub&gt;3&lt;/sub&gt; vapours) or physical triggers (temperature or vacuum). These findings demonstrate a useful application of fully-aromatic 2D COFs as real-time responsive chemosensors and switches.&lt;/p&gt;</description>
  </descriptions>
  <fundingReferences>
    <fundingReference>
      <funderName>European Commission</funderName>
      <funderIdentifier funderIdentifierType="Crossref Funder ID">10.13039/501100000780</funderIdentifier>
      <awardNumber awardURI="info:eu-repo/grantAgreement/EC/H2020/678462/">678462</awardNumber>
      <awardTitle>Layered functional materials - beyond 'graphene'</awardTitle>
    </fundingReference>
  </fundingReferences>
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