Dataset Open Access

Real-time optical and electronic sensing with a β-amino enone linked, triazine-containing 2D covalent organic framework

Kulkarni, Ranjit; Noda, Yu; Barange, Deepak K.; Kochergin, Yaroslav S.; Balcarova, Barbora; Lyu, Pengbo; Nachtigal, Petr; Bojdys, Michael J.


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{
  "publisher": "Zenodo", 
  "DOI": "10.5281/zenodo.2634565", 
  "language": "eng", 
  "title": "Real-time optical and electronic sensing with a \u03b2-amino enone linked, triazine-containing 2D covalent organic framework", 
  "issued": {
    "date-parts": [
      [
        2019, 
        4, 
        9
      ]
    ]
  }, 
  "abstract": "<p>[This repository contains the raw and source data for the manuscript &quot;<strong>Real-time optical and electronic sensing with a &beta;-amino enone linked, triazine-containing 2D covalent organic framework</strong>&quot;.]</p>\n\n<p>Fully-aromatic, two-dimensional covalent organic frameworks (2D COFs) are hailed as candidates for electronic and optical devices, yet to-date few applications emerged that make genuine use of their rational, predictive design principles and permanent pore structure. Here, we present a 2D COF made up of chemoresistant &beta;-amino enone bridges and Lewis-basic triazine moieties that exhibits a dramatic real-time response in the visible spectrum and an increase in bulk conductivity by two orders of magnitude to a chemical trigger - corrosive HCl vapours. The optical and electronic response is fully reversible using a chemical switch (NH<sub>3</sub> vapours) or physical triggers (temperature or vacuum). These findings demonstrate a useful application of fully-aromatic 2D COFs as real-time responsive chemosensors and switches.</p>", 
  "author": [
    {
      "family": "Kulkarni, Ranjit"
    }, 
    {
      "family": "Noda, Yu"
    }, 
    {
      "family": "Barange, Deepak K."
    }, 
    {
      "family": "Kochergin, Yaroslav S."
    }, 
    {
      "family": "Balcarova, Barbora"
    }, 
    {
      "family": "Lyu, Pengbo"
    }, 
    {
      "family": "Nachtigal, Petr"
    }, 
    {
      "family": "Bojdys, Michael J."
    }
  ], 
  "type": "dataset", 
  "id": "2634565"
}
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