Dataset Open Access

New Azo-DMOF-1 MOF as a photo-responsive low-energy CO2 adsorbent and its exceptional CO2/N2 separation performance in mixed matrix membranes

Prasetya, Nicholaus; Ladewig, Bradley


MARC21 XML Export

<?xml version='1.0' encoding='UTF-8'?>
<record xmlns="http://www.loc.gov/MARC21/slim">
  <leader>00000nmm##2200000uu#4500</leader>
  <controlfield tag="005">20190409140402.0</controlfield>
  <controlfield tag="001">1412052</controlfield>
  <datafield tag="700" ind1=" " ind2=" ">
    <subfield code="u">Barrer Centre, Imperial College London</subfield>
    <subfield code="0">(orcid)0000-0002-2135-1913</subfield>
    <subfield code="a">Ladewig, Bradley</subfield>
  </datafield>
  <datafield tag="856" ind1="4" ind2=" ">
    <subfield code="s">92297</subfield>
    <subfield code="z">md5:533fbbefcc764cb89d057d50168e9c71</subfield>
    <subfield code="u">https://zenodo.org/record/1412052/files/Azo-DMOF-1 building unit.cmdx</subfield>
  </datafield>
  <datafield tag="856" ind1="4" ind2=" ">
    <subfield code="s">1485340</subfield>
    <subfield code="z">md5:74a2dfa87a6d3e108a0f6cb414538580</subfield>
    <subfield code="u">https://zenodo.org/record/1412052/files/SEM particle 1.tif</subfield>
  </datafield>
  <datafield tag="856" ind1="4" ind2=" ">
    <subfield code="s">1167998</subfield>
    <subfield code="z">md5:1228afdebb4097e7eb15218b6470657d</subfield>
    <subfield code="u">https://zenodo.org/record/1412052/files/Zenodo File.xlsx</subfield>
  </datafield>
  <datafield tag="856" ind1="4" ind2=" ">
    <subfield code="s">487020</subfield>
    <subfield code="z">md5:1698b2f1c1e80307004d83abc4726a51</subfield>
    <subfield code="u">https://zenodo.org/record/1412052/files/Zn-bdc-dabco.tiff</subfield>
  </datafield>
  <datafield tag="542" ind1=" " ind2=" ">
    <subfield code="l">open</subfield>
  </datafield>
  <datafield tag="260" ind1=" " ind2=" ">
    <subfield code="c">2018-07-15</subfield>
  </datafield>
  <datafield tag="909" ind1="C" ind2="O">
    <subfield code="p">openaire_data</subfield>
    <subfield code="p">user-membrane-research</subfield>
    <subfield code="o">oai:zenodo.org:1412052</subfield>
  </datafield>
  <datafield tag="909" ind1="C" ind2="4">
    <subfield code="c">34291–34301</subfield>
    <subfield code="n">40</subfield>
    <subfield code="p">ACS Applied Materials &amp; Interfaces</subfield>
    <subfield code="v">10</subfield>
  </datafield>
  <datafield tag="100" ind1=" " ind2=" ">
    <subfield code="u">Barrer Centre, Imperial College London</subfield>
    <subfield code="0">(orcid)0000-0003-3794-0613</subfield>
    <subfield code="a">Prasetya, Nicholaus</subfield>
  </datafield>
  <datafield tag="245" ind1=" " ind2=" ">
    <subfield code="a">New Azo-DMOF-1 MOF as a photo-responsive low-energy CO2 adsorbent and its exceptional CO2/N2 separation performance in mixed matrix membranes</subfield>
  </datafield>
  <datafield tag="980" ind1=" " ind2=" ">
    <subfield code="a">user-membrane-research</subfield>
  </datafield>
  <datafield tag="540" ind1=" " ind2=" ">
    <subfield code="u">http://creativecommons.org/licenses/by/4.0/legalcode</subfield>
    <subfield code="a">Creative Commons Attribution 4.0 International</subfield>
  </datafield>
  <datafield tag="650" ind1="1" ind2="7">
    <subfield code="a">cc-by</subfield>
    <subfield code="2">opendefinition.org</subfield>
  </datafield>
  <datafield tag="520" ind1=" " ind2=" ">
    <subfield code="a">&lt;p&gt;Data repository for manuscript, published in &lt;em&gt;ACS Applied Materials &amp;amp; Interfaces&lt;/em&gt;, &lt;strong&gt;2018&lt;/strong&gt;, &lt;em&gt;10&lt;/em&gt; (40), pp 34291&amp;ndash;34301, &lt;a href="https://dx.doi.org/10.1021/acsami.8b12261"&gt;http://dx.doi.org/10.1021/acsami.8b12261&lt;/a&gt;&lt;/p&gt;

&lt;p&gt;&lt;strong&gt;Abstract&lt;/strong&gt;&lt;/p&gt;

&lt;p&gt;A new generation-2 light-responsive metal&amp;ndash;organic framework (MOF) has been successfully synthesized using Zn as the metal source and both 2-phenyldiazenyl terephthalic acid and 1,4-diazabicyclo[2.2.2]octane (DABCO) as the ligands. It was found that Zn-azo-dabco MOF (Azo-DMOF-1) exhibited a photoresponsive CO&lt;sub&gt;2&lt;/sub&gt; adsorption both in static and dynamic condition because of the presence of azobenzene functionalities from the ligand. Further application of this MOF was evaluated by incorporating it as a filler in a mixed matrix membrane for CO&lt;sub&gt;2&lt;/sub&gt;/N&lt;sub&gt;2&lt;/sub&gt; gas separation. Matrimid and polymer of intrinsic microporosity-1 (PIM-1) were used as the polymer matrix. It was found that Azo-DMOF-1 could enhance both the CO&lt;sub&gt;2&lt;/sub&gt; permeability and selectivity of the pristine polymer. In particular, the Azo-DMOF-1&amp;ndash;PIM-1 composite membranes have shown a promising performance that surpassed the 2008 Robeson Upper Bound.&lt;/p&gt;</subfield>
  </datafield>
  <datafield tag="773" ind1=" " ind2=" ">
    <subfield code="n">doi</subfield>
    <subfield code="i">isCitedBy</subfield>
    <subfield code="a">10.1021/acsami.8b12261</subfield>
  </datafield>
  <datafield tag="773" ind1=" " ind2=" ">
    <subfield code="n">doi</subfield>
    <subfield code="i">isVersionOf</subfield>
    <subfield code="a">10.5281/zenodo.1312360</subfield>
  </datafield>
  <datafield tag="024" ind1=" " ind2=" ">
    <subfield code="a">10.5281/zenodo.1412052</subfield>
    <subfield code="2">doi</subfield>
  </datafield>
  <datafield tag="980" ind1=" " ind2=" ">
    <subfield code="a">dataset</subfield>
  </datafield>
</record>
86
25
views
downloads
All versions This version
Views 8650
Downloads 2525
Data volume 18.8 MB18.8 MB
Unique views 7245
Unique downloads 88

Share

Cite as