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New Azo-DMOF-1 MOF as a photo-responsive low-energy CO2 adsorbent and its exceptional CO2/N2 separation performance in mixed matrix membranes

Prasetya, Nicholaus; Ladewig, Bradley


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  <dc:creator>Prasetya, Nicholaus</dc:creator>
  <dc:creator>Ladewig, Bradley</dc:creator>
  <dc:date>2018-07-15</dc:date>
  <dc:description>Data repository for manuscript, published in ACS Applied Materials &amp; Interfaces, 2018, 10 (40), pp 34291–34301, http://dx.doi.org/10.1021/acsami.8b12261

Abstract

A new generation-2 light-responsive metal–organic framework (MOF) has been successfully synthesized using Zn as the metal source and both 2-phenyldiazenyl terephthalic acid and 1,4-diazabicyclo[2.2.2]octane (DABCO) as the ligands. It was found that Zn-azo-dabco MOF (Azo-DMOF-1) exhibited a photoresponsive CO2 adsorption both in static and dynamic condition because of the presence of azobenzene functionalities from the ligand. Further application of this MOF was evaluated by incorporating it as a filler in a mixed matrix membrane for CO2/N2 gas separation. Matrimid and polymer of intrinsic microporosity-1 (PIM-1) were used as the polymer matrix. It was found that Azo-DMOF-1 could enhance both the CO2 permeability and selectivity of the pristine polymer. In particular, the Azo-DMOF-1–PIM-1 composite membranes have shown a promising performance that surpassed the 2008 Robeson Upper Bound.</dc:description>
  <dc:identifier>https://zenodo.org/record/1412052</dc:identifier>
  <dc:identifier>10.5281/zenodo.1412052</dc:identifier>
  <dc:identifier>oai:zenodo.org:1412052</dc:identifier>
  <dc:relation>doi:10.1021/acsami.8b12261</dc:relation>
  <dc:relation>doi:10.5281/zenodo.1312360</dc:relation>
  <dc:relation>url:https://zenodo.org/communities/membrane-research</dc:relation>
  <dc:rights>info:eu-repo/semantics/openAccess</dc:rights>
  <dc:rights>http://creativecommons.org/licenses/by/4.0/legalcode</dc:rights>
  <dc:source>ACS Applied Materials &amp; Interfaces 10(40) 34291–34301</dc:source>
  <dc:title>New Azo-DMOF-1 MOF as a photo-responsive low-energy CO2 adsorbent and its exceptional CO2/N2 separation performance in mixed matrix membranes</dc:title>
  <dc:type>info:eu-repo/semantics/other</dc:type>
  <dc:type>dataset</dc:type>
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