Dataset Open Access

New Azo-DMOF-1 MOF as a photo-responsive low-energy CO2 adsorbent and its exceptional CO2/N2 separation performance in mixed matrix membranes

Prasetya, Nicholaus; Ladewig, Bradley


JSON Export

{
  "files": [
    {
      "links": {
        "self": "https://zenodo.org/api/files/196b2caf-6c4b-4a91-848a-80c9cf7bd3d1/Azo-DMOF-1%20building%20unit.cmdx"
      }, 
      "checksum": "md5:533fbbefcc764cb89d057d50168e9c71", 
      "bucket": "196b2caf-6c4b-4a91-848a-80c9cf7bd3d1", 
      "key": "Azo-DMOF-1 building unit.cmdx", 
      "type": "cmdx", 
      "size": 92297
    }, 
    {
      "links": {
        "self": "https://zenodo.org/api/files/196b2caf-6c4b-4a91-848a-80c9cf7bd3d1/SEM%20particle%201.tif"
      }, 
      "checksum": "md5:74a2dfa87a6d3e108a0f6cb414538580", 
      "bucket": "196b2caf-6c4b-4a91-848a-80c9cf7bd3d1", 
      "key": "SEM particle 1.tif", 
      "type": "tif", 
      "size": 1485340
    }, 
    {
      "links": {
        "self": "https://zenodo.org/api/files/196b2caf-6c4b-4a91-848a-80c9cf7bd3d1/Zenodo%20File.xlsx"
      }, 
      "checksum": "md5:1228afdebb4097e7eb15218b6470657d", 
      "bucket": "196b2caf-6c4b-4a91-848a-80c9cf7bd3d1", 
      "key": "Zenodo File.xlsx", 
      "type": "xlsx", 
      "size": 1167998
    }, 
    {
      "links": {
        "self": "https://zenodo.org/api/files/196b2caf-6c4b-4a91-848a-80c9cf7bd3d1/Zn-bdc-dabco.tiff"
      }, 
      "checksum": "md5:1698b2f1c1e80307004d83abc4726a51", 
      "bucket": "196b2caf-6c4b-4a91-848a-80c9cf7bd3d1", 
      "key": "Zn-bdc-dabco.tiff", 
      "type": "tiff", 
      "size": 487020
    }
  ], 
  "owners": [
    37905
  ], 
  "doi": "10.5281/zenodo.1412052", 
  "stats": {
    "version_unique_downloads": 8.0, 
    "unique_views": 40.0, 
    "views": 45.0, 
    "downloads": 25.0, 
    "unique_downloads": 8.0, 
    "version_unique_views": 67.0, 
    "volume": 18776162.0, 
    "version_downloads": 25.0, 
    "version_views": 81.0, 
    "version_volume": 18776162.0
  }, 
  "links": {
    "doi": "https://doi.org/10.5281/zenodo.1412052", 
    "conceptdoi": "https://doi.org/10.5281/zenodo.1312360", 
    "thumb250": "https://zenodo.org/api/iiif/v2/196b2caf-6c4b-4a91-848a-80c9cf7bd3d1:8b594023-e664-42d2-9ab7-1a790c538798:SEM%20particle%201.tif/full/250,/0/default.jpg", 
    "bucket": "https://zenodo.org/api/files/196b2caf-6c4b-4a91-848a-80c9cf7bd3d1", 
    "conceptbadge": "https://zenodo.org/badge/doi/10.5281/zenodo.1312360.svg", 
    "html": "https://zenodo.org/record/1412052", 
    "latest_html": "https://zenodo.org/record/1412052", 
    "badge": "https://zenodo.org/badge/doi/10.5281/zenodo.1412052.svg", 
    "latest": "https://zenodo.org/api/records/1412052"
  }, 
  "conceptdoi": "10.5281/zenodo.1312360", 
  "created": "2018-09-09T10:59:40.829482+00:00", 
  "updated": "2019-04-09T14:04:02.519915+00:00", 
  "conceptrecid": "1312360", 
  "revision": 5, 
  "id": 1412052, 
  "metadata": {
    "access_right_category": "success", 
    "doi": "10.5281/zenodo.1412052", 
    "description": "<p>Data repository for manuscript, published in <em>ACS Applied Materials &amp; Interfaces</em>, <strong>2018</strong>, <em>10</em> (40), pp 34291&ndash;34301, <a href=\"https://dx.doi.org/10.1021/acsami.8b12261\">http://dx.doi.org/10.1021/acsami.8b12261</a></p>\n\n<p><strong>Abstract</strong></p>\n\n<p>A new generation-2 light-responsive metal&ndash;organic framework (MOF) has been successfully synthesized using Zn as the metal source and both 2-phenyldiazenyl terephthalic acid and 1,4-diazabicyclo[2.2.2]octane (DABCO) as the ligands. It was found that Zn-azo-dabco MOF (Azo-DMOF-1) exhibited a photoresponsive CO<sub>2</sub> adsorption both in static and dynamic condition because of the presence of azobenzene functionalities from the ligand. Further application of this MOF was evaluated by incorporating it as a filler in a mixed matrix membrane for CO<sub>2</sub>/N<sub>2</sub> gas separation. Matrimid and polymer of intrinsic microporosity-1 (PIM-1) were used as the polymer matrix. It was found that Azo-DMOF-1 could enhance both the CO<sub>2</sub> permeability and selectivity of the pristine polymer. In particular, the Azo-DMOF-1&ndash;PIM-1 composite membranes have shown a promising performance that surpassed the 2008 Robeson Upper Bound.</p>", 
    "license": {
      "id": "CC-BY-4.0"
    }, 
    "title": "New Azo-DMOF-1 MOF as a photo-responsive low-energy CO2 adsorbent and its exceptional CO2/N2 separation performance in mixed matrix membranes", 
    "journal": {
      "volume": "10", 
      "issue": "40", 
      "pages": "34291\u201334301", 
      "title": "ACS Applied Materials & Interfaces"
    }, 
    "relations": {
      "version": [
        {
          "count": 2, 
          "index": 1, 
          "parent": {
            "pid_type": "recid", 
            "pid_value": "1312360"
          }, 
          "is_last": true, 
          "last_child": {
            "pid_type": "recid", 
            "pid_value": "1412052"
          }
        }
      ]
    }, 
    "communities": [
      {
        "id": "membrane-research"
      }
    ], 
    "publication_date": "2018-07-15", 
    "creators": [
      {
        "orcid": "0000-0003-3794-0613", 
        "affiliation": "Barrer Centre, Imperial College London", 
        "name": "Prasetya, Nicholaus"
      }, 
      {
        "orcid": "0000-0002-2135-1913", 
        "affiliation": "Barrer Centre, Imperial College London", 
        "name": "Ladewig, Bradley"
      }
    ], 
    "access_right": "open", 
    "resource_type": {
      "type": "dataset", 
      "title": "Dataset"
    }, 
    "related_identifiers": [
      {
        "scheme": "doi", 
        "relation": "isCitedBy", 
        "identifier": "10.1021/acsami.8b12261"
      }, 
      {
        "scheme": "doi", 
        "relation": "isVersionOf", 
        "identifier": "10.5281/zenodo.1312360"
      }
    ]
  }
}
81
25
views
downloads
All versions This version
Views 8145
Downloads 2525
Data volume 18.8 MB18.8 MB
Unique views 6740
Unique downloads 88

Share

Cite as