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New Azo-DMOF-1 MOF as a photo-responsive low-energy CO2 adsorbent and its exceptional CO2/N2 separation performance in mixed matrix membranes

Prasetya, Nicholaus; Ladewig, Bradley


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  <identifier identifierType="DOI">10.5281/zenodo.1412052</identifier>
  <creators>
    <creator>
      <creatorName>Prasetya, Nicholaus</creatorName>
      <givenName>Nicholaus</givenName>
      <familyName>Prasetya</familyName>
      <nameIdentifier nameIdentifierScheme="ORCID" schemeURI="http://orcid.org/">0000-0003-3794-0613</nameIdentifier>
      <affiliation>Barrer Centre, Imperial College London</affiliation>
    </creator>
    <creator>
      <creatorName>Ladewig, Bradley</creatorName>
      <givenName>Bradley</givenName>
      <familyName>Ladewig</familyName>
      <nameIdentifier nameIdentifierScheme="ORCID" schemeURI="http://orcid.org/">0000-0002-2135-1913</nameIdentifier>
      <affiliation>Barrer Centre, Imperial College London</affiliation>
    </creator>
  </creators>
  <titles>
    <title>New Azo-DMOF-1 MOF as a photo-responsive low-energy CO2 adsorbent and its exceptional CO2/N2 separation performance in mixed matrix membranes</title>
  </titles>
  <publisher>Zenodo</publisher>
  <publicationYear>2018</publicationYear>
  <dates>
    <date dateType="Issued">2018-07-15</date>
  </dates>
  <resourceType resourceTypeGeneral="Dataset"/>
  <alternateIdentifiers>
    <alternateIdentifier alternateIdentifierType="url">https://zenodo.org/record/1412052</alternateIdentifier>
  </alternateIdentifiers>
  <relatedIdentifiers>
    <relatedIdentifier relatedIdentifierType="DOI" relationType="IsCitedBy">10.1021/acsami.8b12261</relatedIdentifier>
    <relatedIdentifier relatedIdentifierType="DOI" relationType="IsVersionOf">10.5281/zenodo.1312360</relatedIdentifier>
    <relatedIdentifier relatedIdentifierType="URL" relationType="IsPartOf">https://zenodo.org/communities/membrane-research</relatedIdentifier>
  </relatedIdentifiers>
  <rightsList>
    <rights rightsURI="http://creativecommons.org/licenses/by/4.0/legalcode">Creative Commons Attribution 4.0 International</rights>
    <rights rightsURI="info:eu-repo/semantics/openAccess">Open Access</rights>
  </rightsList>
  <descriptions>
    <description descriptionType="Abstract">&lt;p&gt;Data repository for manuscript, published in &lt;em&gt;ACS Applied Materials &amp;amp; Interfaces&lt;/em&gt;, &lt;strong&gt;2018&lt;/strong&gt;, &lt;em&gt;10&lt;/em&gt; (40), pp 34291&amp;ndash;34301, &lt;a href="https://dx.doi.org/10.1021/acsami.8b12261"&gt;http://dx.doi.org/10.1021/acsami.8b12261&lt;/a&gt;&lt;/p&gt;

&lt;p&gt;&lt;strong&gt;Abstract&lt;/strong&gt;&lt;/p&gt;

&lt;p&gt;A new generation-2 light-responsive metal&amp;ndash;organic framework (MOF) has been successfully synthesized using Zn as the metal source and both 2-phenyldiazenyl terephthalic acid and 1,4-diazabicyclo[2.2.2]octane (DABCO) as the ligands. It was found that Zn-azo-dabco MOF (Azo-DMOF-1) exhibited a photoresponsive CO&lt;sub&gt;2&lt;/sub&gt; adsorption both in static and dynamic condition because of the presence of azobenzene functionalities from the ligand. Further application of this MOF was evaluated by incorporating it as a filler in a mixed matrix membrane for CO&lt;sub&gt;2&lt;/sub&gt;/N&lt;sub&gt;2&lt;/sub&gt; gas separation. Matrimid and polymer of intrinsic microporosity-1 (PIM-1) were used as the polymer matrix. It was found that Azo-DMOF-1 could enhance both the CO&lt;sub&gt;2&lt;/sub&gt; permeability and selectivity of the pristine polymer. In particular, the Azo-DMOF-1&amp;ndash;PIM-1 composite membranes have shown a promising performance that surpassed the 2008 Robeson Upper Bound.&lt;/p&gt;</description>
  </descriptions>
</resource>
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