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New Azo-DMOF-1 MOF as a photo-responsive low-energy CO2 adsorbent and its exceptional CO2/N2 separation performance in mixed matrix membranes

Prasetya, Nicholaus; Ladewig, Bradley


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        <foaf:name>Ladewig, Bradley</foaf:name>
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    <dct:title>New Azo-DMOF-1 MOF as a photo-responsive low-energy CO2 adsorbent and its exceptional CO2/N2 separation performance in mixed matrix membranes</dct:title>
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    <dct:description>&lt;p&gt;Data repository for manuscript, published in &lt;em&gt;ACS Applied Materials &amp;amp; Interfaces&lt;/em&gt;, &lt;strong&gt;2018&lt;/strong&gt;, &lt;em&gt;10&lt;/em&gt; (40), pp 34291&amp;ndash;34301, &lt;a href="https://dx.doi.org/10.1021/acsami.8b12261"&gt;http://dx.doi.org/10.1021/acsami.8b12261&lt;/a&gt;&lt;/p&gt; &lt;p&gt;&lt;strong&gt;Abstract&lt;/strong&gt;&lt;/p&gt; &lt;p&gt;A new generation-2 light-responsive metal&amp;ndash;organic framework (MOF) has been successfully synthesized using Zn as the metal source and both 2-phenyldiazenyl terephthalic acid and 1,4-diazabicyclo[2.2.2]octane (DABCO) as the ligands. It was found that Zn-azo-dabco MOF (Azo-DMOF-1) exhibited a photoresponsive CO&lt;sub&gt;2&lt;/sub&gt; adsorption both in static and dynamic condition because of the presence of azobenzene functionalities from the ligand. Further application of this MOF was evaluated by incorporating it as a filler in a mixed matrix membrane for CO&lt;sub&gt;2&lt;/sub&gt;/N&lt;sub&gt;2&lt;/sub&gt; gas separation. Matrimid and polymer of intrinsic microporosity-1 (PIM-1) were used as the polymer matrix. It was found that Azo-DMOF-1 could enhance both the CO&lt;sub&gt;2&lt;/sub&gt; permeability and selectivity of the pristine polymer. In particular, the Azo-DMOF-1&amp;ndash;PIM-1 composite membranes have shown a promising performance that surpassed the 2008 Robeson Upper Bound.&lt;/p&gt;</dct:description>
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