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New Azo-DMOF-1 MOF as a photo-responsive low-energy CO2 adsorbent and its exceptional CO2/N2 separation performance in mixed matrix membranes

Prasetya, Nicholaus; Ladewig, Bradley


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{
  "publisher": "Zenodo", 
  "DOI": "10.5281/zenodo.1412052", 
  "container_title": "ACS Applied Materials & Interfaces", 
  "title": "New Azo-DMOF-1 MOF as a photo-responsive low-energy CO2 adsorbent and its exceptional CO2/N2 separation performance in mixed matrix membranes", 
  "issued": {
    "date-parts": [
      [
        2018, 
        7, 
        15
      ]
    ]
  }, 
  "abstract": "<p>Data repository for manuscript, published in <em>ACS Applied Materials &amp; Interfaces</em>, <strong>2018</strong>, <em>10</em> (40), pp 34291&ndash;34301, <a href=\"https://dx.doi.org/10.1021/acsami.8b12261\">http://dx.doi.org/10.1021/acsami.8b12261</a></p>\n\n<p><strong>Abstract</strong></p>\n\n<p>A new generation-2 light-responsive metal&ndash;organic framework (MOF) has been successfully synthesized using Zn as the metal source and both 2-phenyldiazenyl terephthalic acid and 1,4-diazabicyclo[2.2.2]octane (DABCO) as the ligands. It was found that Zn-azo-dabco MOF (Azo-DMOF-1) exhibited a photoresponsive CO<sub>2</sub> adsorption both in static and dynamic condition because of the presence of azobenzene functionalities from the ligand. Further application of this MOF was evaluated by incorporating it as a filler in a mixed matrix membrane for CO<sub>2</sub>/N<sub>2</sub> gas separation. Matrimid and polymer of intrinsic microporosity-1 (PIM-1) were used as the polymer matrix. It was found that Azo-DMOF-1 could enhance both the CO<sub>2</sub> permeability and selectivity of the pristine polymer. In particular, the Azo-DMOF-1&ndash;PIM-1 composite membranes have shown a promising performance that surpassed the 2008 Robeson Upper Bound.</p>", 
  "author": [
    {
      "family": "Prasetya, Nicholaus"
    }, 
    {
      "family": "Ladewig, Bradley"
    }
  ], 
  "page": "34291\u201334301", 
  "volume": "10", 
  "type": "dataset", 
  "issue": "40", 
  "id": "1412052"
}
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