Dataset for: Linda M.J. Kooijmans, Wu Sun, Juho Aalto, Kukka-Maaria Erkkilä, Kadmiel Maseyk, Ulli Seibt, Timo Vesala, Ivan Mammarella, and Huilin Chen: Influences of light and humidity on carbonyl sulfide-based estimates of photosynthesis. Please contact Linda Kooijmans (l.m.j.kooijmans@rug.nl) and Huilin Chen (Huilin.Chen@rug.nl) when you have interest in using this dataset in a presentation or publication. Content: Measurements between February and July 2017 in Hyytiälä, Finland of: branch fluxes and mole fractions of COS and CO2; LRU; eddy-covariance fluxes of COS and CO2; COS-based GPP estimates and GPP based on nighttime respiration extrapolated to the daytime; stomatal conductance; internal conductance; meteorological information. More information on the measurement and calculation procedures used to obtain this dataset can be found in "Influences of light and humidity on carbonyl sulfide-based estimates of photosynthesis." Notes: 1. Data are corrected for blank emissions. 2. Periods with problematic flux data are marked as "NA". 3. Relative humidity (RH) in the chambers is determined from H2O concentrations after chamber opening (ambient levels). ################################################## Data columns: time: time in Finnish winter time (UTC+2) Fb.cos.1: COS branch flux, chamber 1 (pmol m-2 s-1) Fb.cos.2: COS branch flux, chamber 2 (pmol m-2 s-1) Fb.co2.1: CO2 branch flux, chamber 1 (umol m-2 s-1) Fb.co2.2: CO2 branch flux, chamber 2 (umol m-2 s-1) Fb.h2o.1: H2O branch flux, chamber 1 (mmol m-2 s-1) Fb.h2o.2: H2O branch flux, chamber 2 (mmol m-2 s-1) flag_b1 : flux quality flag for chamber 1 (1 = good, 0 = do not use, e.g. because of blank measurements; flagging is already applied to the data) flag_b2 : flux quality flag for chamber 2 (1 = good, 0 = do not use, e.g. because of blank measurements; flagging is already applied to the data) LRU.1 : LRU calculated from COS and CO2 branch fluxes and concentrations in chamber 1 (LRU = Fb.cos/Fb.co2*CO2.18/COS.18) LRU.2 : LRU calculated from COS and CO2 branch fluxes and concentrations in chamber 2 (LRU = Fb.cos/Fb.co2*CO2.18/COS.18) Fec.cos : Storage-corrected eddy-covariance flux of COS (pmol m-2 s-1) Fec.co2 : Storage-corrected eddy-covariance flux of CO2 (umol m-2 s-1) GPPcos : COS-based GPP using Fec.cos, COS.18, CO2.18 and LRU based on a PAR-dependent fit (LRU = 607.26/PAR+0.57). An average soil flux of -2.7 pmol m-2 s-1 is subtracted from Fec.cos (umol m-2 s-1) GPPnee : GPP based on extrapolating nighttime respiration to the daytime (Reichstein et al., 2005) (umol m-2 s-1) gs.1 : Stomatal conductance in chamber 1 (mol m-2 s-1) gs.2 : Stomatal conductance in chamber 2 (mol m-2 s-1) flag.gs.bb : Indicator if gs.1 and gs.2 are calculated from Fb.co2 using the Ball-Berry model (1 = calculated by Ball-Berry model, 0 = calculated by Fb.h2o) flag.gs.h2o : Indicator if gs.1 and gs.2 are calculated from Fb.h2o (1 = calculated from Fb.h2o, 0 = calculated by Ball-Berry model) gi.1 : Internal conductance in chamber 1 (mol m-2 s-1) gi.2 : Internal conductance in chamber 2 (mol m-2 s-1) COS.18 : COS mole fraction at 18 m (measured in an open chamber) (ppt) CO2.18 : CO2 mole fraction at 18 m (measured in an open chamber) (ppm) H2O.18 : H2O mole fraction at 18 m (measured in an open chamber) (%) PAR.tow : Photosynthetic Active Radiation measured in the tall tower (umol m-2 s-1) PAR.1 : Photosynthetic Active Radiation measured at chamber 1 (umol m-2 s-1) PAR.2 : Photosynthetic Active Radiation measured at chamber 2 (umol m-2 s-1) RH.tow : Relative humidity measured at 17 m in the tall tower (%) RH.1 : Relative humidity in chamber 1 (%) RH.2 : Relative humidity in chamber 2 (%) T.tow : Temperature measured at 17 m in the tall tower (degree Celcius) Tch.1 : Temperature in chamber 1 (degree Celcius) Tch.2 : Temperature in chamber 2 (degree Celcius) Press : Pressure measured in the tall tower (hPa) vpd.1 : Vapour pressure deficit in chamber 1 (kPa) vpd.2 : Vapour pressure deficit in chamber 2 (kPa) solarangle : Solar elevation angle (degrees) ########################################## time,Fb.cos.1,Fb.cos.2,Fb.co2.1,Fb.co2.2,Fb.h2o.1,Fb.h2o.2,flag_b1,flag_b2,LRU.1,LRU.2,Fec.cos,Fec.co2,GPPcos,GPPnee,gs.1,gs.2,flag.gs.bb,flag.gs.h2o,gi.1,gi.2,COS.18,CO2.18,H2O.18,PAR.tow,PAR.1,PAR.2,RH.tow,RH.1,RH.2,T.tow,Tch.1,Tch.2,Press,vpd.1,vpd.2,solarangle 2017-02-15 19:00:00,0.0278859690672423,-0.162347058823529,0.0712795454545455,0.0378658823529412,0.00375984848484849,0.00685882352941176,1,1,NA,NA,-5.665375,0.208,NA,0.02,NA,NA,0,1,NA,NA,NA,NA,0.421870476836158,NA,0.6808,0.560333333333333,70.044,72.8761518595112,74.1898899663167,-0.829333,-1.728487,-0.682605,1005.1307,0.158970109820162,0.148916015499635,-13.664170195685 2017-02-15 20:00:00,-0.0818136584677611,-0.0061529411764706,0.0748136363636364,0.0310882352941176,0.00304469696969697,0.00685529411764706,1,1,NA,NA,-6.69955,0.573,NA,-0.343,NA,NA,0,1,NA,NA,NA,NA,0.430356143220339,NA,0.667,0.802833333333333,70.355,74.124747817411,73.6303538823132,-0.665,-1.292857,-0.276667,1004.33067,0.15204478360703,0.156855630397231,-20.6774272813559 2017-02-15 21:00:00,-0.0150764922668441,-0.251567058823529,0.0860984848484848,0.0482117647058824,0.00370909090909091,0.00807764705882353,1,1,NA,NA,2.67045,1.081,NA,-0.851,NA,NA,0,1,NA,NA,NA,NA,0.442203270621469,NA,0.626111111111111,0.524262295081967,75.1206666666667,78.6215483679834,76.2545547585472,-0.716111,-1.168417,-0.357,1002.96623333333,0.126191390750828,0.140541986484206,-27.3134355680478 2017-02-15 22:00:00,0.041998026075869,-0.243834117647059,0.0721530303030303,0.0428070588235294,0.0023969696969697,0.00823058823529412,1,1,NA,NA,-5.233405,0.254,NA,-0.025,NA,NA,0,1,NA,NA,NA,NA,0.469987136158192,NA,0.4508,0.451,79.544,82.8554927035329,81.7057585077837,-0.961333,-1.108739,-0.501849,1002.0833,0.0987268412526571,0.107168535657503,-33.1109236316794 2017-02-15 23:00:00,-0.17413355322257,-0.171977647058824,0.0723681818181818,0.0325929411764706,0.00282045454545455,0.00826,1,1,NA,NA,-3.082645,0.232,NA,-0.005,NA,NA,0,1,NA,NA,NA,NA,0.478049275706215,NA,0.3496,0.7995,80.738,83.6239225290076,83.7591732338806,-1.032,-1.113445,-0.67375,1001.78202,0.0940277835026793,0.0939612917728581,-37.5420462541391 2017-02-16 00:00:00,-0.217317996060002,-0.294118823529412,0.072475,0.0469788235294118,0.00302651515151515,0.00905294117647059,1,1,-2.59273310186087,-5.41341133807225,-3.099455,0.226,NA,0,NA,NA,0,1,NA,NA,482.904667264015,417.553133988003,0.410751774576271,0.715402333333333,0.751333333333333,0.477213114754098,82.3546666666667,73.6943784823544,72.7770846700291,-1.15144433333333,-1.121917,-0.6895,1000.81055,0.149631408752908,0.157602144844937,-40.0747379711042 2017-02-16 01:00:00,-0.096451188848011,-0.286450588235294,0.0670401515151515,0.0412376470588235,0.00249621212121212,0.00946588235294118,1,1,-1.25405605883758,-6.05480546101161,-3.004775,0.225,NA,0,NA,NA,0,1,NA,NA,479.646807268438,418.086275106749,0.420681624576271,0.519667,0.368,0.9735,83.93,75.1160201699161,74.4843978300947,-1.245,-1.121008,-0.768992,1000.13464,0.141324442885545,0.146944763619425,-40.3326794060705 2017-02-16 02:00:00,-0.36088936856853,-0.305843529411765,0.0645962121212121,0.045915294117647,0.00298939393939394,0.00891764705882353,1,1,-4.83718868570689,-5.76723858562284,2.535405,0.4215,NA,-0.197,NA,NA,0,1,NA,NA,483.681645991945,418.779679088591,0.425857998022598,0.4902,0.3312,0.6355,84.703,76.1332762169576,76.3207280041874,-1.312,-1.131765,-0.941333,999.81933,0.133847207180531,0.13468976389272,-38.2727669688494 2017-02-16 03:00:00,-0.0352315580751679,-0.186865882352941,0.0561787878787879,0.04866,0.00182272727272727,0.00877647058823529,1,1,-0.552329399582616,-3.38217898464109,-11.228795,0.362,NA,-0.139,NA,NA,0,1,NA,NA,475.883347387211,419.120769867537,0.422226904237288,0.567989,0.527722222222222,0.436885245901639,84.856,75.8053640665554,76.2533367282135,-1.54055533333333,-1.166583,-1.062917,999.065426666667,0.134325594809797,0.13397521299969,-34.2086289602655 2017-02-16 04:00:00,-0.297606103228299,-0.178649411764706,0.0690401515151515,0.04156,0.00339621212121212,0.00943529411764706,1,1,-3.72793136320429,-3.71752469235706,-2.09551,0.2205,NA,0,NA,NA,0,1,NA,NA,483.964874661044,418.544512813196,0.417190257909605,0.6891,0.6578,0.806333333333333,86.224,77.2360407565543,76.760905770351,-1.805667,-1.298824,-1.258908,998.313,0.124169557312722,0.129320781867126,-28.653471596332 2017-02-16 05:00:00,-0.0941532016480097,-0.371462352941176,0.062105303030303,0.0564070588235294,0.00255606060606061,0.0091,1,1,-1.31119597822605,-5.69564025754743,-0.49598,0.2185,NA,0,NA,NA,0,1,NA,NA,483.969308085866,418.580528355129,0.424167285875707,0.6459165,0.7636,1.10333333333333,88.425,80.1037208312879,79.6433969752233,-1.9713335,-1.378655,-1.434083,997.79715,0.107592861172074,0.111874085790025,-22.1438994229591 2017-02-16 06:00:00,-0.199950657319551,-0.152211764705882,0.0459378787878788,0.0245317647058824,0.00316818181818182,0.00674941176470588,1,1,-3.71970354861518,-5.30244119605122,-10.642565,0.217,NA,0,NA,NA,0,1,NA,NA,490.157011598085,418.881953124819,0.422001093502825,0.522111333333333,0.375666666666667,0.275573770491803,92.1146666666667,82.0773193134352,81.902939569383,-2.252222,-1.4355,-1.737333,997.194983333333,0.0945958769656425,0.0973397816009755,-15.1562001949627 2017-02-16 07:00:00,-0.130512022936144,-0.250022352941176,0.073930303030303,0.0285141176470588,0.00269166666666667,0.00451294117647059,1,1,-1.54714231958828,-7.68459761338858,-2.436395,0.215,NA,0,NA,NA,0,1,NA,NA,478.247502385758,419.135977768969,0.436415547740113,1.589,0.8004,0.519333333333333,94.394,83.7069605902853,84.1223646985127,-2.460333,-1.502857,-1.826471,996.74036,0.0850390282885868,0.084932603214675,-8.10096324134265 2017-02-16 08:00:00,-0.0304507008941245,-0.0896964705882353,0.019925,0.0232141176470588,0.00163787878787879,0.00183764705882353,1,1,-1.34964426209186,-3.41227106014659,2.890045,0.1875,NA,0.0255,NA,NA,0,1,NA,NA,474.958326161174,419.445804504137,0.439565928248588,15.7770165,12.7834,7.81083333333333,96.435,86.3016037341613,84.9192434194829,-2.6878335,-1.548235,-2.099333,996.40218,0.0707701248772901,0.0793679420745825,-1.34849068741496 2017-02-16 09:00:00,-0.100643335000651,-0.156056470588235,-0.0111280303030303,-0.00974117647058823,0.00188333333333333,0.000775294117647059,1,1,7.99092740990626,14.1547054096589,-1.54523,0.1385,-0.090193922625233,0.074,NA,NA,1,0,NA,NA,474.457115076121,419.205941601157,0.43856983220339,56.5329446666667,36.7348333333333,26.4931147540984,96.166,86.5887480226274,85.5777303472825,-2.78366666666667,-1.50475,-2.26575,995.697333333333,0.0690877418794373,0.0755879443625787,4.74468347593218 2017-02-16 10:00:00,-0.0719414774784122,-0.209122352941176,-0.0161742424242424,-0.0242023529411765,0.00626287878787879,0.00412117647058823,1,1,3.85547573668933,7.48971748985912,-4.02729,0.115,0.167641451124103,0.096,NA,NA,1,0,NA,NA,483.893319747287,419.44227122621,0.432126442372882,96.50743,57.6058,42.516,94.476,85.4657875853493,85.732351435345,-2.878667,-1.426303,-2.244622,995.31165,0.0757927675328483,0.0752787778043811,9.82279255979643 2017-02-16 11:00:00,0.082355483970323,-0.166565882352941,-0.0243083333333333,-0.0357576470588235,0.0111590909090909,0.0119023529411765,1,1,-2.94075616736948,4.04332631397127,3.886645,0.045,-1.27651591838721,0.1665,NA,NA,1,0,NA,NA,482.353695163926,418.684887971667,0.4163535259887,155.378415,103.5092,73.526,92.09,79.1765319359869,83.0164396359015,-2.8486665,-1.227311,-2.084667,994.99553,0.114384224356328,0.0911374761035099,13.5413179093958 2017-02-16 12:00:00,-0.21290496424069,-0.161561176470588,-0.0137507575757576,-0.0429470588235294,0.00860681818181818,0.01108,1,1,13.6467916528627,3.31569808774754,-9.6887,-0.0375,1.74352528062143,0.25,NA,NA,1,0,NA,NA,474.758688951461,418.450721245338,0.365308066384181,204.985356666667,117.020166666667,89.8373770491803,87.703,69.9421823526193,69.7936031225809,-2.65844466666667,-1.054667,-1.705833,994.228666666667,0.160214854835112,0.165937209193588,15.6066652505194 2017-02-16 13:00:00,0.122319923099236,0.150207058823529,-0.0692242424242424,-0.0762294117647059,0.00869166666666667,0.0146870588235294,1,1,-1.56195594469266,-1.74179711333892,1.76332,-0.1575,-1.43229517158563,0.3715,NA,NA,1,0,NA,NA,473.82011891719,418.835312067423,0.349865378531073,278.0404,175.5866,166.162833333333,87.614,65.5524848741149,65.1225545231679,-2.431667,-0.745966,-1.216218,993.53265,0.201455868921327,0.200567677145084,15.8364017325579 2017-02-16 15:00:00,0.0425916863341481,-0.126770588235294,0.0500590909090909,0.101838823529412,0.00609469696969697,-0.000508235294117647,1,1,0.792182449775482,-1.15901343863897,-0.6594,1.323,-0.153054119422225,-1.108,NA,NA,1,0,NA,NA,468.312398620351,436.032635182713,0.363032941525424,51.275812,34.6239444444444,32.6549180327869,88.5326666666667,69.0060962454425,66.2297027964967,-2.398111,-1.1335,-1.778917,992.43245,0.164215397256239,0.183277917124654,10.8745379863807 2017-02-16 17:00:00,-0.0442723973056257,0.111197647058824,0.0505416666666667,0.0367588235294118,0.004025,0.00933882352941176,1,1,-0.775647356896152,2.67864296915773,-7.891375,0.211,0.0129855445569995,0.003,NA,NA,1,0,NA,NA,472.68589062929,418.555907497842,0.392389600847457,1.7182,0.6164,1.10683333333333,93.79,77.8961319665716,78.1287674078284,-2.563167,-1.42042,-2.181583,991.1512,0.114472739635925,0.114521972859103,0.235691254561472 2017-02-16 18:00:00,0.142781327152394,-0.139965882352941,0.0561537878787879,0.0421552941176471,0.00465075757575758,0.00938588235294118,1,1,2.26608875447824,-2.95906578860663,1.57554,0.2135,NA,0,NA,NA,0,1,NA,NA,470.6786801859,419.47790013106,0.348270492937853,0.700255666666667,0.483,0.699016393442623,93.8793333333333,70.238430756867,69.7415548537367,-2.53400033333333,-1.4715,-2.295083,990.288316666667,0.154198162781394,0.157333515151262,-6.3737688238795 2017-02-16 19:00:00,-0.134986524184375,-0.377134117647059,0.0569909090909091,0.0521317647058823,0.00364848484848485,0.00876705882352941,1,1,-2.15212023644221,-6.57317352932301,-2.42333,0.214,NA,0,NA,NA,0,1,NA,NA,462.88714197245,420.587942764964,0.354846900282486,0.420733,0.598,0.826833333333333,93.974,69.8541185905486,70.6181936133718,-2.52,-1.496303,-2.165294,990.01465,0.156257443290016,0.154307850747568,-13.3672031454012 2017-02-16 20:00:00,0.0786350263912901,-0.0840494117647059,0.052769696969697,0.0491035294117647,0.00363257575757576,0.00797176470588235,1,1,1.53874580106584,-1.76749182384833,-2.45096,0.214,NA,0,NA,NA,0,1,NA,NA,409.334186400449,422.681715487969,0.354234263276836,0.502317,0.644,0.580833333333333,94.556,69.5352811868693,70.1345305272799,-2.519667,-1.504118,-2.166167,989.486,0.159458929655016,0.156942966435512,-20.378005136069 2017-02-16 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