Published August 1, 2014 | Version 9999147
Journal article Open

Poly(Lactic Acid) Based Flexible Films

Description

Poly(lactic acid) (PLA) is a biodegradable polymer
which has good mechanical properties, however, its brittleness limits
its usage especially in packaging materials. Therefore, in this work,
PLA based polyurethane films were prepared by synthesizing with
different types of isocyanates; methylene diisocyanate (MDI) and
hexamethylene diisocyanates (HDI). For this purpose, PLA based
polyurethane must have good strength and flexibility. Therefore,
polycaprolactone which has better flexibility were prepared with
PLA. An effective way to endow polylactic acid with toughness is
through chain-extension reaction of the polylactic acid pre-polymer
with polycaprolactone used as chain extender. Polyurethane prepared
from MDI showed brittle behaviour, while, polyurethane prepared
from HDI showed flexibility at same concentrations.

Files

9999147.pdf

Files (185.8 kB)

Name Size Download all
md5:f9cf13cabeb42d68d6dc74a8435fa8ad
185.8 kB Preview Download

Additional details

References

  • Park, J.W. and S.S. Im, "Miscibility and morphology in blends of poliy(L-lactic acid) and poly(vinyl acetate-co-vinyl alcohol),"Polym., 2003. 44(15): p. 4341-4354.
  • Rashkov, I., et al., "Synthesis, characterization, and hydrolytic degradation of PLA/PEO/PLA triblock copolymers with short poly(Llactic acid) chains," Macromolecules, 1996. 29(1): p. 50-56.
  • Wang, L., et al., "Reactive compatibilization of biodegradable blends of poly(lactic acid) and poly(epsilon-caprolactone),"Polymer Degradation and Stability, 1998. 59(1-3): p. 161-168.
  • Yokohara, T. and M. Yamaguchi, "Structure and properties for biomassbased polyester blends of PLA and PBS,"European Polymer Journal, 2008. 44(3): p. 677-685.
  • Okubo, K., T. Fujii, and E.T. Thostenson, "Multi-scale hybrid biocomposite: Processing and mechanical characterization of bamboo fiber reinforced PLA with microfibrillatedcellulose,"Composites Part a- Applied Science and Manufacturing, 2009. 40(4): p. 469-475.
  • Mallarde, D., et al., "Hydrolytic degradability of poly(3- hydroxyoctanoate) and of a poly(3-hydroxyoctanoate)/poly(R,S-lactic acid) blend," Polymer, 1998. 39(15): p. 3387-3392.
  • Anderson, K.S., S.H. Lim, and M.A. Hillmyer, "Toughening of polylactide by melt blending with linear low-density polyethylene," Journal of Applied Polymer Science, 2003. 89(14): p. 3757-3768.
  • Zhu, G.Q., et al., "Properties Study of Poly(L-lactic acid)/Polyurethane- Blend Film," Polymer-Plastics Technology and Engineering, 2012. 51(15): p. 1562-1566.
  • Xu, H., et al., "Biodegradable Composites: Ramie Fibre Reinforced PLLA-PCL Composite Prepared by in Situ Polymerization Process,"Polymer Bulletin, 2008. 61(5): p. 663-670. [10] Hiltunen, K., et al., "Synthesis and characterization of lactic acid based telechelic prepolymers, "Macromolecules, 1996. 29(27): p. 8677-8682. [11] Jabbari, E. and M. Khakpour, "Morphology of and release behavior from porous polyurethane microspheres," Biomaterials, 2000. 21(20): p. 2073-2079.