%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%
% File for gas-phase mechanism RACM2
%
% Reference: see below
%
% Modifications:
%
% 2009/08/28(YS): Modification for the SOA model
% 2010/02/26(Youngseob KIM): the rate constant of R066 is corrected by 
% 					   the recommendation of IUPAC from 2.50E-22 to 1.0E-22
% 2010/03/03(Youngseob KIM): SOA formations modified to consider NOx dependencies 
% 2010/03/04(YK): Two reactions added (TOLP+HO2 and XYLP + HO2) 
%
%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%
!! **********************************************************************
!!  FILE:        RACM2.5Gb.mch final frozen (I hope) 
!!  DATE:        December 2, 2007 
!!  VERSION:     2.5.F9 - include PAN photo and changing ORA1+HO prods 
!!  ID: RACM Version 2.5F9, December 23, 2008
!!  LAST UPDATE: DEC 23, 2008, 4:00 PM
!!  --------------------------------------------------------------------
!!  Based on REGIONAL ATMOSPHERIC CHEMISTRY MECHANISM  (RACM)  Version 1.3
!!  Reference: W.R. Stockwell, F. Kirchner, M. Kuhn, and S. Seefeld, "A 
!!  New Mechanism for Regional Atmospheric Chemistry Modeling", J. of
!!  Geophys. Res., 1997.
!!  --------------------------------------------------------------------
!!  FOR MORE INFORMATION REGARDING THIS MECHANISM CONTACT:
!!  William R. Stockwell or Wendy Goliff
!!  Division of Atmospheric Sciences
!!  Desert Research Institute
!!  2215 Raggio Parkway
!!  Reno, NV 89512-1095
!!  E-MAIL:      wstock@dri.edu or Wendy.Goliff@dri.edu
!!  Telephone:   (775) 674-7058 or (775) 674-7026
!!  FAX:         (775) 674-7060
! **********************************************************************
! The RACM2 mechanism is based upon the earlier Regional Atmospheric
! Chemistry Mechanism (RACM) mechanism.  It is intended to be valid for 
! conditions ranging from remote to polluted and from the Earth's
! surface through the upper troposphere.  The RACM2 mechanism includes
! 275 reactions and 89 species: 17 stable inorganic species, 4 
! inorganic intermediates, 32 stable organic species (4 of these are
! primarily of biogenic origin) and 24 organic intermediates.
! **********************************************************************
!
! Modifications for Version 2.0  (Feb. 14, 2000) 
!
!
SET UNIT GAS MOLCM3
SET TABULATION 11 DEGREES 0. 10. 20. 30. 40. 50. 60. 70. 78. 86. 90.
% R001 
NO2             ->      O3P    +     NO
KINETIC PHOTOLYSIS   0.931026E-02  0.921901E-02  0.890995E-02  0.837928E-02  0.760031E-02  0.652988E-02  0.510803E-02  0.329332E-02  0.174121E-02  0.511393E-03  0.163208E-03
!  --- C.S. AND Q.Y. NASA 2006
% R002 
O3              ->      O1D    +     O2
KINETIC PHOTOLYSIS   0.352348E-04  0.339820E-04  0.301078E-04  0.242445E-04  0.172587E-04  0.102977E-04  0.463950E-05  0.128749E-05  0.290804E-06  0.487557E-07  0.185350E-07
! --- CROSS SECTIONS: NASA 2006
! QUANTUM YIELDS: NASA 2006
% R003 
O3              ->      O3P    +     O2
KINETIC PHOTOLYSIS   0.492758E-03  0.489069E-03  0.476368E-03  0.454585E-03  0.423344E-03  0.381150E-03  0.324899E-03  0.247082E-03  0.160308E-03  0.397670E-04  0.557331E-05
!8.87492E-05  8.69750E-05  8.29119E-05  7.55582E-05  6.44918E-05  5.21011E-05  3.98963E-05  2.75217E-05  1.61441E-05  !1.32389E-05  9.60889E-06
! --- CROSS SECTIONS: NASA 2006
! QUANTUM YIELDS: ASSUMED TO BE 1-Q.Y.(O3->O1D)
% R004 
HONO            ->      HO     +     NO
KINETIC PHOTOLYSIS   0.204671E-02  0.202572E-02  0.195491E-02  0.183337E-02  0.165516E-02  0.141113E-02  0.109002E-02  0.689444E-03  0.361035E-03  0.108950E-03  0.346516E-04
!  --- CROSS SECTIONS: NASA 2006
% R005 
HNO3            ->      HO     +     NO2
KINETIC PHOTOLYSIS   0.747531E-06  0.729946E-06  0.674094E-06  0.585322E-06  0.470402E-06  0.339698E-06  0.208199E-06  0.964783E-07  0.382903E-07  0.830301E-08  0.224170E-08
! --- CROSS SECTIONS: NASA 2006
! QUANTUM YIELDS: ASSUMED TO BE UNITY OVER UV ABSORPTION RANGE
% R006 
HNO4            -> 0.80 HO2  +  0.80 NO2 +  0.20  HO + 0.20 NO3
KINETIC PHOTOLYSIS   0.503836E-05  0.492337E-05  0.455701E-05  0.397119E-05  0.320567E-05  0.232384E-05  0.142322E-05  0.648606E-06  0.246502E-06  0.469613E-07  0.118499E-07
! --- CROSS SECTIONS: NASA 2006 - Q.Y. assumed to be 1
! as done by Molina - STOICHIOMETRY NASA 2006 ABOVE 200 NM
% R007 
NO3             ->      NO     +     O2
KINETIC PHOTOLYSIS   0.265649E-01  0.264102E-01  0.258524E-01  0.249074E-01  0.235172E-01  0.215841E-01  0.188522E-01  0.147419E-01  0.971212E-02  0.225719E-02  0.250693E-03 
!  --- C.S. AND Q.Y. NASA 2006
% R008 
NO3             ->      NO2    +     O3P
KINETIC PHOTOLYSIS   0.212996      0.211689      0.207152      0.199076      0.187348      0.170929      0.147742      0.113042      0.718608E-01  0.162667E-01  0.252856E-02
!  --- C.S. AND Q.Y. NASA 2006
% R009 
H2O2            ->      HO     +     HO
KINETIC PHOTOLYSIS   0.839458E-05  0.825592E-05  0.780494E-05  0.706032E-05  0.603528E-05  0.475883E-05  0.329698E-05  0.180604E-05  0.842157E-06  0.221356E-06  0.624535E-07
! --- C.S. NASA 2006  Q.Y. is believed to be unity
% R010 
HCHO            ->      H2     +     CO
KINETIC PHOTOLYSIS   0.466946E-04  0.460643E-04  0.439841E-04  0.404765E-04  0.354845E-04  0.289656E-04  0.210065E-04  0.121895E-04  0.597941E-05  0.166295E-05  0.476221E-06 
! --- CROSS SECTIONS AND QY: NASA 2006
% R011 
HCHO            ->      HO2    +     HO2    +     CO
KINETIC PHOTOLYSIS   0.322056E-04  0.316290E-04  0.297592E-04  0.266797E-04  0.224649E-04  0.172798E-04  0.114907E-04  0.587024E-05  0.250654E-05  0.553383E-06  0.139443E-06
! --- CROSS SECTIONS AND QY: NASA 2006
% R012 
ACD             ->      MO2    +     HO2    +     CO
KINETIC PHOTOLYSIS   0.610507E-05  0.595723E-05  0.548715E-05  0.473800E-05  0.376612E-05  0.266260E-05  0.156576E-05  0.668185E-06  0.236179E-06  0.423517E-07  0.111857E-07
! --- CROSS SECTIONS AND QY: NASA 2006
! --- USE REACTION 1 IN NASA 2006 ONLY
% R013 
ALD             ->      ETHP   +     HO2    +     CO
KINETIC PHOTOLYSIS    3.33230E-05  3.25001E-05  3.05718E-05  2.72085E-05  2.23195E-05  1.75064E-05  1.31494E-05  8.91010E-06  4.87297E-06  4.07420E-06  2.91244E-06
! --- CROSS SECTIONS: NASA 2006
! --- NASA 2006 HAS NO RECOMMENDATION FOR QY
! --- HEICKLEN ET AL. 1986 FOR QY
% R014 
ACT             ->      ACO3   +     MO2
KINETIC PHOTOLYSIS   3.75547E-06  3.61571E-06  3.29098E-06  2.74387E-06  2.01174E-06  1.41825E-06  9.89407E-07  6.22747E-07  2.60195E-07  2.30611E-07  1.52424E-07
! --- ACETONE
! --- CROSS SECTIONS: NASA 2006
% R015 
MEK             ->      ACO3  +  0.50 ETHP +  0.50  MO2
KINETIC PHOTOLYSIS   2.32094E-05  2.26238E-05  2.12508E-05  1.88562E-05  1.53810E-05  1.19876E-05  8.96004E-06  6.04283E-06  3.25604E-06  2.72663E-06  1.93833E-06
! --- CH3COC2H5
! --- CROSS SECTIONS:  Yujing and Mellouki 2000 
! --- QUANTUM YIELDS:  0.34 Raben and Moortgat 1996
% R016 
KET             ->      ACO3   +     ETHP
KINETIC PHOTOLYSIS   0.106563E-05  0.104198E-05  0.966425E-06  0.844984E-06  0.685160E-06  0.499504E-06  0.308206E-06  0.142186E-06  0.551369E-07  0.111617E-07  0.290941E-08
!2.32094E-05  2.26238E-05  2.12508E-05  1.88562E-05  1.53810E-05  1.19876E-05  8.96004E-06  6.04283E-06  3.25604E-06  !2.72663E-06  1.93833E-06
! --- SPECIES TREATED AS CH3COC2H5
! --- CROSS SECTIONS:  Yujing and Mellouki 2000 
! --- QUANTUM YIELDS:  0.34 Raben and Moortgat 1996
% R017 
HKET            ->      ACO3    +    HCHO    +    HO2
KINETIC PHOTOLYSIS   0.106563E-05  0.104198E-05  0.966425E-06  0.844984E-06  0.685160E-06  0.499504E-06  0.308206E-06  0.142186E-06  0.551369E-07  0.111617E-07  0.290941E-08
!2.32094E-05  2.26238E-05  2.12508E-05  1.88562E-05  1.53810E-05  1.19876E-05  8.96004E-06  6.04283E-06  3.25604E-06  !2.72663E-06  1.93833E-06
! --- RATE CONSTANT TAKEN FROM KET
! PRODUCTS FROM HYDROXYACETONE
% R018 
MACR            -> 0.66 HO2 +  0.33 MACP + 0.67 CO + //
                      0.67 HCHO +  0.67 ACO3 +  0.34  HO + //
                      0.34 XO2
KINETIC PHOTOLYSIS   0.176977E-05  0.174636E-05  0.166900E-05  0.153840E-05  0.135225E-05  0.110852E-05  0.809392E-06  0.474670E-06  0.235099E-06  0.668358E-07  0.197291E-07
! --- NASA 2006
% R019 
MVK             -> 0.7  UALD +  0.7  CO +   0.3   MO2 + 0.3  MACP
KINETIC PHOTOLYSIS   1.61228E-06  1.58741E-06  1.53020E-06  1.43026E-06  1.27595E-06  1.08988E-06  8.71601E-07  6.24106E-07  4.00412E-07  3.28779E-07  2.48407E-07
! --- NASA 2006
% R020 
UALD            -> 1.22 CO  +   .434 ALD +  0.35  HCHO + //
                      .216 KET  +   1.22 HO2 +  .784  ACO3
KINETIC PHOTOLYSIS   2.09640E-05  2.07371E-05  2.02323E-05  1.93650E-05  1.79813E-05  1.60391E-05  1.32945E-05  9.77963E-06  6.76709E-06  5.51234E-06  4.28552E-06
! --- BASED UPON CROTONALDEHYDE
! --- MAGNERON ET AL. 2002
% R021 
GLY             -> 2.00 HO2  +  2.00 CO
KINETIC PHOTOLYSIS   1.05316E-04  1.04155E-04  1.01551E-04  9.70650E-05  9.00485E-05  8.07463E-05  6.80330E-05  5.05570E-05  3.62574E-05  2.91495E-05  2.30528E-05
! --- REACTION (1) IN NASA 2006
! --- C.S. AND Q.Y.: NASA 2006
% R022 
GLY             -> 1.00 H2   +  2.00 CO   
KINETIC PHOTOLYSIS   1.16562E-05  1.14377E-05  1.09291E-05  1.00376E-05  8.68964E-06  7.19340E-06  5.61656E-06  3.94228E-06  2.39170E-06  1.97474E-06  1.46205E-06
! --- REACTION (2) IN NASA 2006
! --- C.S. AND Q.Y.: NASA 2006
% R023 
GLY             -> 1.00 HCHO +  2.00 CO   
KINETIC PHOTOLYSIS   5.05456E-05  4.97388E-05  4.78764E-05  4.46129E-05  3.95885E-05  3.36475E-05  2.68457E-05  1.91777E-05  1.22537E-05  1.00539E-05  7.59130E-06
! --- REACTION (3) IN NASA 2006
! --- C.S. AND Q.Y.: NASA 2006
% R024 
MGLY            ->      ACO3   +    HO2   +     CO
KINETIC PHOTOLYSIS   0.120477E-03  0.119066E-03  0.114362E-03  0.106443E-03  0.951654E-04  0.803121E-04  0.616157E-04  0.390953E-04  0.204535E-04  0.566664E-05  0.177264E-05
! --- C.S. AND Q.Y.: NASA 2006
% R025 
DCB1            -> 2.0  XO2  +   1.5  HO2 +  0.5   ACO3 + //
                           CO  +   0.5  GLY +  0.5   MGLY
KINETIC PHOTOLYSIS   0.120477E-03  0.119066E-03  0.114362E-03  0.106443E-03  0.951654E-04  0.803121E-04  0.616157E-04  0.390953E-04  0.204535E-04  0.566664E-05  0.177264E-05
!--- Photolysis treated like MGLY.
% R026 
DCB2            -> 2.0  XO2  +  1.5  HO2  + 0.5   ACO3 + //
                           CO  +   0.5  GLY +  0.5   MGLY
KINETIC PHOTOLYSIS   0.120477E-03  0.119066E-03  0.114362E-03  0.106443E-03  0.951654E-04  0.803121E-04  0.616157E-04  0.390953E-04  0.204535E-04  0.566664E-05  0.177264E-05
!Photolysis treated like MGLY.
% R027 
DCB3            ->      ACO3   +     HO2    +     CO + OLIP
KINETIC PHOTOLYSIS   0.120477E-03  0.119066E-03  0.114362E-03  0.106443E-03  0.951654E-04  0.803121E-04  0.616157E-04  0.390953E-04  0.204535E-04  0.566664E-05  0.177264E-05
! --- treat as MGLY, ADD OLIP FOR MASS BALANCE (12/14/05)
% R028 
BALD            ->      CHO    +     HO2    +     CO
KINETIC PHOTOLYSIS   6.09951E-05  6.03113E-05  5.87884E-05  5.61778E-05  5.20341E-05  4.62878E-05  3.82686E-05  2.81028E-05  1.93450E-05  1.57686E-05  1.22336E-05
! --- SAPRC07 FOR C.S. AND Q.Y.
! --- ZHU AND CRONIN 2000 FOR PRODUCTS
% R029 
OP1             ->      HCHO   +     HO2    +     HO
KINETIC PHOTOLYSIS   0.570462E-05  0.561354E-05  0.531667E-05  0.482525E-05  0.414587E-05  0.329411E-05  0.230820E-05  0.128524E-05  0.608525E-06  0.163756E-06  0.471643E-07
! --- CROSS SECTIONS: NASA 2006
! Q.Y. =1 (NASA 2006)
% R030 
OP2             ->      ALD    +     HO2    +     HO
KINETIC PHOTOLYSIS   0.570462E-05  0.561354E-05  0.531667E-05  0.482525E-05  0.414587E-05  0.329411E-05  0.230820E-05  0.128524E-05  0.608525E-06  0.163756E-06  0.471643E-07
!  --- CROSS SECTIONS AND Q.Y. AS OP1
% R031 
PAA             ->      MO2    +     HO
KINETIC PHOTOLYSIS   0.222443E-05  0.218748E-05  0.206735E-05  0.186913E-05  0.159652E-05  0.125753E-05  0.870017E-06  0.475757E-06  0.221534E-06  0.581609E-07  0.164095E-07
! --- CROSS SECTIONS: NASA 2006
% R032 
ONIT            -> 0.20 ALD  +  0.80 KET  +    HO2 + NO2
KINETIC PHOTOLYSIS   0.337909E-05  0.330632E-05  0.307366E-05  0.269949E-05  0.220592E-05  0.162928E-05  0.102758E-05  0.491847E-06  0.199146E-06  0.422739E-07  0.108005E-07
! --- Talukdar et al. 1997 
% R033 
PAN             ->      ACO3    +    NO2
KINETIC PHOTOLYSIS   9.31954E-07  9.13823E-07  8.63482E-07  7.76606E-07  6.49116E-07  5.22031E-07  4.00326E-07  2.76791E-07  1.61794E-07  1.34426E-07  9.88679E-08
! --- JPL 2006
% R034 
PAN             ->      MO2    +     CO2    +     NO3
KINETIC PHOTOLYSIS   6.01194E-07  5.88553E-07  5.57097E-07  5.02767E-07  4.23318E-07  3.42599E-07  2.63862E-07  1.83051E-07  1.07748E-07  8.94267E-08  6.58031E-08
! --- JPL 2006
% END OF THE PHOTOLYSIS REACTIONS
%
% R035 O3P +  O2        ->      O3
O3P    ->      O3
KINETIC TB O2 SPEC -1
!SPECIAL RWK(#) = CM*5.74E-34*(TEMP/300)**(-2.6)
!  --- IUPAC WEB VERSION OCTOBER 2006
!  --- WEIGHTED AVERAGE OF N2 AND O2 RATE CONSTANTS
% R036 O3P +  O3        ->  2.0 O2
O3P +  O3        ->
KINETIC ARR2  8.00E-12  2060.0
!  --- IUPAC WEB VERSION OCTOBER 2006
% R037 O1D +  N2        ->      O3P   +      N2
O1D      ->      O3P
KINETIC TB N2 ARR2   1.80E-11   -107.0
!  --- IUPAC WEB VERSION OCTOBER 2006
%
% R038 O1D +  O2        ->      O3P   +      O2
O1D      ->      O3P
KINETIC TB O2 ARR2   3.20E-11  -67
!  --- IUPAC WEB VERSION OCTOBER 2006
% R039 O1D +  H2O       ->      HO    +      HO
O1D      ->    2. HO
KINETIC TB H2O ARR1  2.20E-10
!  --- IUPAC WEB VERSION OCTOBER 2006
% R040 O3  +   HO       ->      HO2   +      O2
O3  +   HO       ->      HO2
KINETIC ARR2   1.70E-12    940.0
!  --- IUPAC WEB VERSION OCTOBER 2006
% R041 O3  +  HO2       ->      HO    +   2.   O2
O3  +  HO2       ->      HO
KINETIC ARR2    1.00E-14   490.0
!  --- NASA 2006
% R042 HO  +  HO2       ->      H2O   +      O2
HO  +  HO2       ->  
KINETIC ARR2   4.80E-11   -250.0
!  --- IUPAC WEB VERSION OCTOBER 2006
% R043 H2O2 +  HO        ->      HO2   +      H2O
H2O2 +  HO        ->      HO2 
KINETIC ARR2   2.90E-12   160.0
!  --- IUPAC WEB VERSION OCTOBER 2006
% R044 HO2 +  HO2       ->      H2O2   +     O2
HO2 +  HO2       ->      H2O2 
KINETIC SPEC -2
!SPECIAL RWK(#) = 2.2E-13*EXP(600./TEMP) +1.90E-33*CM*EXP(980./TEMP)
!  --- IUPAC WEB VERSION OCTOBER 2006
% R045 HO2 +  HO2 +  H2O ->      H2O2   +     H2O   +      O2
HO2 +  HO2  ->      H2O2
KINETIC TB H2O SPEC -3 
!SPECIAL RWK(#) = 3.08E-34*EXP(2800./TEMP)+2.59E-54*CM*EXP(3180./TEMP)
!  --- IUPAC WEB VERSION OCTOBER 2006
% R046 O3P +  NO        ->      NO2
O3P +  NO        ->      NO2
KINETIC TROE4   9.00E-32   1.5   3.00E-11   0.0
!  --- NASA 2006
% R047 O3P +  NO2       ->      NO    +      O2
O3P +  NO2       ->      NO 
KINETIC ARR2     5.50E-12   -188.0
!  --- IUPAC WEB VERSION OCTOBER 2006
% R048 O3P +  NO2       ->      NO3
O3P +  NO2       ->      NO3
KINETIC TROE4   2.50E-31   1.8   2.20E-11   0.7
!  --- NASA 2006
% R049 HO +   NO        ->      HONO
HO +   NO        ->      HONO
KINETIC TROE4   7.00E-31   2.6   3.60E-11   0.1
!  --- NASA 2006
% R050 HO +   NO2       ->      HNO3
HO  +  NO2       ->      HNO3
KINETIC TROE4    1.80E-30   3.00  2.80E-11   0.0
!  --- NASA 2006
% R051 HO +   NO3       ->      NO2    +     HO2
HO +   NO3       ->      NO2    +     HO2
KINETIC ARR1  2.00E-11
!  --- IUPAC WEB VERSION OCTOBER 2006
% R052 HO2 +  NO        ->      NO2    +     HO
HO2 +  NO        ->      NO2    +     HO
KINETIC ARR2   3.60E-12    -270.0
!  --- IUPAC WEB VERSION OCTOBER 2006
% R053 HO2 +  NO2       ->      HNO4
HO2 +  NO2       ->      HNO4
KINETIC TROE4   2.0E-31   3.4   2.90E-12   1.1
!  --- NASA 2006
% 
% R054 
HNO4            ->      HO2    +     NO2
KINETIC RCFE   2.00E-31   3.4   2.90E-12   1.1  4.76D26  10900.
!  --- NASA 2006
% the inverse of the equilibrium constant taken: Stockwell et al, 1997 
%
% R055 
HO2 +  NO3       ->  0.3 HNO3 +   0.7 NO2 +   0.7  HO
KINETIC ARR1   4.00E-12 
! --- IUPAC WEB VERSION OCTOBER 2006
! PRODUCTS LA BRAS 1997
%
% R056 HO +   HONO      ->      H2O   +      NO2
HO +   HONO      ->      NO2
KINETIC ARR2  2.50E-12   -260.0
!  --- IUPAC WEB VERSION OCTOBER 2006
% R057 HO +   HNO3      ->      NO3   +      H2O
HO +   HNO3      ->      NO3
KINETIC SPEC -4
!SPECIAL TMP0 = 2.4E-14*EXP(460/TEMP)
!SPECIAL TMP2 = 2.4E-17*EXP(2199/TEMP)
!SPECIAL TMP3 = 6.5E-34*EXP(1335/TEMP)*CM
!SPECIAL RWK(#) = TMP0 + TMP3/(1+TMP3/TMP2)
!  --- IUPAC WEB VERSION OCTOBER 2006
% R058 HO +   HNO4      ->      NO2   +      H2O   +      O2
HO +   HNO4      ->      NO2
KINETIC ARR2  1.30E-12  -380.0
! --- NASA 2006
! PRODUCTS USELMAN ET AL. IN NITROGENEOUS AIR POLLUTANTS
! CHEMICAL AND BIOLOGICAL IMPLICATIONS
% R059 O3 +   NO        ->      NO2   +      O2
O3 +   NO        ->      NO2 
KINETIC ARR2  1.40E-12  1310.0
!  --- IUPAC WEB VERSION OCTOBER 2006
% R060 O3 +   NO2       ->      NO3   +      O2
O3 +   NO2       ->      NO3
KINETIC ARR2   1.40E-13   2470.0
!  --- IUPAC WEB VERSION OCTOBER 2006
% R061 NO +   NO +   O2  ->      NO2   +      NO2
NO +   NO   ->      NO2   +      NO2
KINETIC TB O2 ARR2   3.30E-39   -530.0
!  --- IUPAC WEB VERSION OCTOBER 2006
% R062 NO3 +  NO        ->      NO2   +      NO2
NO3 +  NO        ->      NO2   +      NO2
KINETIC ARR2   1.80E-11  -110.0
!  --- IUPAC WEB VERSION OCTOBER 2006
% R063 NO3 +  NO2       ->      NO    +      NO2    +     O2
NO3 +  NO2       ->      NO    +      NO2
KINETIC ARR2 4.50E-14  1260.0
!  --- NASA 2006
% R064 NO3 +  NO2       ->      N2O5
NO3 +  NO2       ->      N2O5
KINETIC TROE4   2.00E-30  4.4  1.40E-12  0.7
!  --- NASA 2006
% 
% R065
N2O5            ->      NO2   +      NO3
KINETIC RCFE   2.20E-30  3.9  1.50E-12  0.7   3.70D26    11000.0
!  --- NASA 2006
% the inverse of the equilibrium constant taken: Stockwell et al, 1997
% 
% R066 N2O5 +  H2O       ->      HNO3   +     HNO3
N2O5        ->      HNO3   +     HNO3
KINETIC TB H2O ARR1  1.00E-22
!  --- IUPAC WEB VERSION OCTOBER 2006
% Corrected constant (YK): see the notice above
% 
% R067 NO3 +  NO3       ->      NO2   +      NO2   +      O2
NO3 +  NO3       ->      NO2   +      NO2
KINETIC ARR2  8.50E-13   2450.0
!  --- NASA 2006
%
% R068 HO +   H2        ->      H2O   +      HO2
HO         ->      HO2
KINETIC TB H2  ARR2   7.70E-12   2100.0
!  --- IUPAC WEB VERSION OCTOBER 2006
% R069 HO +   SO2       ->      SULF   +     HO2
HO +   SO2       ->      SULF   +     HO2
KINETIC TROE4  3.30E-31   4.3  1.60E-12  0.0
!  --- NASA 2006
% R070 CO +   HO        ->      HO2   +      CO2
CO +   HO        ->      HO2
KINETIC SPEC -5
!SPECIAL  RWK(#) = 1.44E-13*(1.+0.8*CM/4E19)
!  --- IUPAC WEB VERSION OCTOBER 2006
% R071 CH4 +  HO        ->      MO2   +      H2O
CH4 +  HO        ->      MO2
KINETIC ARR2   1.85E-12  1690.0
!  --- IUPAC WEB VERSION OCTOBER 2006
% R072 ETH +  HO        ->      ETHP    +    H2O
ETH +  HO        ->      ETHP
KINETIC ARR2  6.90E-12   1000.0
!  --- ETH REPRESENTS ETHANE
!  --- IUPAC WEB VERSION OCTOBER 2006
% R073 MOH +  HO        ->      HO2    +     HCHO
MOH +  HO        ->      HO2    +     HCHO  
KINETIC ARR2   2.85E-12   345.0
! --- METHANOL RATE BASED ON IUPAC 2006
%R 074 EOH +  HO        ->      HO2    +     ACD
EOH +  HO        ->      HO2    +     ACD
KINETIC ARR2   3.00E-12    20.0
! --- ETHANOL RATE BASED ON IUPAC 2006
% R075 ROH +  HO        -> .719 ALD +   .184 ACD    +     HO2
ROH +  HO        -> .719 ALD +   .184 ACD    +     HO2
KINETIC ARR2   2.60E-12    200.0
! --- BASED ON 2-PROPANOL - IUPAC 2006
% 
% R076 
ACE +  HO  -> .350 ORA1 + .350 CO + .650 GLY + .650 HO + .350 HO2
KINETIC TROE4   5.50E-30   0.0   8.30E-13   -2.0
! --- ACE REPRESENTS ACETYLENE
! --- PRODUCTS HATAKEYAMA ET AL 1986
! --- HO2 YIELD FROM BOHN AND ZETZSCH 1998
! --- RATE BASED ON JPL 2006
% R077 HC3 +  HO        ->      HC3P   
HC3 +  HO        ->      HC3P   
KINETIC ARR2    7.68E-12    370.0
! --- HC3 REPRESENTS ALKANES AND SIMILAR
! SPECIES OF "LOW" REACTIVITY, HO RATE CONSTANT LESS THAN 3.4E-12
! BUT GREATER THAN ETHANE AT 2.7E-13 (AT 298.15 1 ATM).
! FOR EXAMPLE PROPANE, BUTANE, 
! RATE CONSTANT IS TAKEN AS AVERAGE FOR US EMISSIONS
% R078 HC5 +  HO        ->      HC5P   +     H2O
HC5 +  HO        ->      HC5P    
KINETIC ARR2   1.01E-11   245.0
! --- HC5 REPRESENTS ALKANES OF "MEDIUM" REACTIVITY
! RATE CONSTANT IS TAKEN AS AVERAGE FOR US EMISSIONS
! FOR SPECIES WITH HO RATE CONSTANTS BETWEEN
! 3.4E-12 AND 6.8E-12 AT 298, 1 ATM
! E/R TAKEN TO BE SIMILAR TO N-OCTANE ATKINSON 1986
! XO2 FACTOR ACCOUNT FOR EXTRA NO TO NO2 CONVERSIONS
! XO2 IS MOVED TO THE HC5P REACTIONS
% 
% R079 (H2O as a product)
HC8 +  HO  -> .951 HC8P +  .025 ALD +  .024  HKET + .049 HO2 + //
              0.048 AnBlP
KINETIC ARR2  2.82E-11  273.0
! --- HC8 REPRESENTS ALKANES OF HIGH REACTIVITY
! FOR SPECIES WITH HO RATE CONSTANTS GREATER THAN 6.8E-12 AT 298, 1 ATM
! RATE CONSTANT IS TAKEN AS AVERAGE FOR US EMISSIONS
! XO2 IS MOVED TO THE HC8P REACTIONS
% SOA modification (YS)
%
% R080 
ETE +  HO        ->      ETEP
KINETIC TROE4   1.00E-28   4.5  8.80E-12  .85
! --- RATE BASED ON JPL 2006
! --- ETE REPRESENTS ETHENE
% R081 
OLT +  HO        ->      OLTP + 0.0016 AnBlP
KINETIC ARR2  5.72E-12  -500.0
! --- OLT REPRESENTS PROPENE, TERMINAL ALKENES.
! RATE CONSTANT IS TAKEN AS AVERAGE FOR US EMISSIONS
% SOA modification (YS)
%
% R082 
OLI +  HO        ->      OLIP  +  0.003 AnBlP
KINETIC ARR2   1.33E-11   -500.0
! --- OLI REPRESENTS T-2-BUTENE AND INTERNAL ALKENES
! RATE CONSTANT IS TAKEN AS AVERAGE FOR US EMISSIONS
% SOA modification (YS)
%
% R083 
DIEN + HO        ->      OLIP
KINETIC ARR2  1.48E-11   -448.0
!  --- RATE CONSTANT ATKINSON AND AREY 2003
% R084 
ISO +  HO        ->      ISOP + //
                         0.232 BiISO1 + 0.0288 BiISO2  
KINETIC ARR2  2.54E-11    -410.  
!2.54E-11  -408  k(298) = 9.97E-11
!  --- GEIGER ET AL. 2003
% SOA module (YK)
%
% R085 
API +  HO        ->      APIP  +  //
                         0.164 BiA0D + 0.117 BiA1D + 0.076 BiA2D
KINETIC ARR2   1.21E-11    -440.0
!  --- IUPAC WEB VERSION OCTOBER 2006
% SOA modification (YS)
%
% R086 
LIM +  HO        ->      LIMP + //
                  0.407 BiA0D + 0.173 BiA1D + 0.003 BiA2D + 0.024 BiBmP
KINETIC ARR2   4.20E-11   -401.0
!  --- GILL AND HITES 2002
% SOA modification (YS)
%
% R087 
ISHP +  HO        ->      MACR   +     HO  
KINETIC ARR1   1.00E-10 
!  --- GEIGER ET AL. 2003
% R088 
ISON +  HO        ->      NALD   +     HACE  
KINETIC ARR1   1.30E-11  
!  --- GEIGER ET AL. 2003
% R089 
MAHP +  HO        ->      MACP      
KINETIC ARR1   3.00E-11 
!  --- GEIGER ET AL. 2003
% R090 
HACE +  HO        ->      MGLY    +    HO2        
KINETIC ARR1   3.00E-12
!  --- GEIGER ET AL. 2003
% R091 
NALD +  HO        ->      HCHO   +     NO2   +      CO
KINETIC ARR2   5.60E-12    -270.
!  --- GEIGER ET AL. 2003
% R092 
ETEG +  HO        ->      ALD    +     HO2         
KINETIC ARR1   1.47E-11 
!  --- ASCHMANN AND ATKINSON 1998 (ROOM TEMP ONLY)
!  --- THIS IS THE DOMINANT LOSS MECHANISM FOR ETEG
% R093 
BEN +  HO   -> .352 BENP +  .118 UALD + .530  PHEN + .648 HO2
KINETIC ARR2   2.33E-12   193.0
! --- BASED ON THE MCM V3.1
%
% R094 
TOL +  HO   -> .060 TLP1 +  .890 TR2 +  .050  CSL + .050 HO2 
KINETIC ARR2   1.81E-12    -354.
! --- NEW MECHANISM FOR TOL BASED ON CALVERT 2002 FOR TOL
%
% R095 
TLP1 +  NO        -> 1.00 NO2  +  1.00 BALD
KINETIC ARR1   4.00E-12 
! -- RATE CONST FROM HC5P + NO
! --- NEW MECHANISM FOR TOL BASED ON CALVERT 2002 FOR TOL
% 
% R096 
TR2             -> .280 DCB2 +  .280 EPX +  .010  CSL + //
                      .280 TOLP +  .150 PER1 + .290  HO2 + //
                      .280 HO
KINETIC ARR1  1.00E+03
! --- NEW MECHANISM FOR TOL BASED ON CALVERT 2002 FOR TOL
% 
% R097 
TOLP            -> .490 DCB2 +  .010 HO2 +  .010  CSL + //
                      .490 HO  +   .500 PER1 
KINETIC ARR1   1.00E+03 
! --- NEW MECHANISM FOR TOL BASED ON CALVERT 2002 FOR TOL
% R098 
TOLP + NO  -> 0.95 DCB2 +  0.95 NO2 +  0.95  HO2 + .050 ONIT + //
              0.053 AnBlP + 0.336 AnBmP  
KINETIC ARR2  2.70E-12   -360.
! RATE CONST FROM TOLP + NO
! --- NEW MECHANISM FOR TOL BASED ON CALVERT 2002 FOR TOL
% SOA formaton : Florian (2010/03/03)
% 
% R099 
PER1 + NO        -> 0.95 DCB1 +  0.95 NO2 +  0.95  MGLY + //
                      0.95 HO2 +   .050 ONIT  
KINETIC ARR2  2.70E-12   -360.
! RATE CONST FROM TOLP + NO
! --- NEW MECHANISM FOR TOL BASED ON CALVERT 2002 FOR TOL
%
% R100 
XYO +  HO        -> .060 XYL1 +  .890 XYO2 + .050  CSL + //
                      .050 HO2
KINETIC ARR1   1.37E-11
!  --- BASED ON XYL
%
% R101 
XYL +  HO        -> .060 XYL1 +  .890 XY2 +  .050  CSL + //
                      .050 HO2
KINETIC ARR1  2.13E-11
! --- NEW MECHANISM FOR TOL BASED ON CALVERT 2002 FOR TOL
%
% R102 
XYL1 + NO        -> 1.00 NO2  +  1.00 BALD
KINETIC ARR1   4.00E-12
! -- RATE CONST FROM HC5P + NO
! --- NEW MECHANISM FOR TOL BASED ON CALVERT 2002 FOR TOL
%
% R103 
XY2             -> .224 DCB2 +  .840 EPX +  .010  CSL + //
                      .308 XYLP +  .150 PER2 + .308  HO2 + //
                      .308 HO
KINETIC ARR1  1.00E+03
! --- NEW MECHANISM FOR TOL BASED ON CALVERT 2002 FOR TOL
%
% R104 
XYO2            -> .224 DCB2 +  .840 EPX +  .010  CSL + //
                      .308 XYOP +  .150 PER2 + .308  HO2 + //
                      .308 HO
KINETIC ARR1  1.00E+03
! --- NEW MECHANISM FOR TOL BASED ON CALVERT 2002 FOR TOL
%
% R105 
XYLP            -> .490 DCB2 +  .010 HO2 +  .010  CSL + //
                      .490 HO  +   .500 PER2 
KINETIC ARR1  1.00E+03
! --- NEW MECHANISM FOR TOL BASED ON CALVERT 2002 FOR TOL
%
% R106 
XYOP            -> .490 DCB2 +  .010 HO2 +  .010  CSL + //
                      .490 HO  +   .500 PER2 
KINETIC ARR1  1.00E+03
! --- NEW MECHANISM FOR TOL BASED ON CALVERT 2002 FOR TOL
%
% R107 
XYLP + NO        -> 0.95 DCB2 +  0.95 NO2 +  0.95  HO2 + //
                      .050 ONIT + //
                      0.023 AnBlP + 0.32 AnBmP  
KINETIC ARR2   2.70E-12   -360.
! RATE CONST FROM TOLP + NO
! --- NEW MECHANISM FOR TOL BASED ON CALVERT 2002 FOR TOL
% SOA formation : Florian (2010/03/03)
%
% R108 
PER2 + NO        -> 0.95 DCB1 +  0.95 NO2 +  0.95  MGLY + //
                      0.95 HO2 +   .050 ONIT + 1.95  DCB3 
KINETIC ARR2  2.70E-12   -360.
! RATE CONST FROM TOLP + NO
! --- NEW MECHANISM FOR TOL BASED ON CALVERT 2002 FOR TOL
% R109 BALD + HO        ->      BALP  +      H2O
BALD + HO        ->      BALP
KINETIC ARR2  5.32E-12    -243.
! --- Ferri et al. 2001 and Semaduni et al. 1995
%
% R110 
BALP + NO        ->      BAL1   +     NO2   
KINETIC ARR1  4.00E-12
! --- Ferri et al. 2001
% R111 
BAL1 + NO        ->      BAL2   +     NO2   
KINETIC ARR1  4.00E-12
! --- Ferri et al. 2001
% R112 
BAL2 + NO2       ->      ONIT       
KINETIC ARR1   2.00E-11 
! --- Ferri et al. 2001 - rate constant Carter 2000
%
% R113 
PHEN + HO        -> 0.07 CHO +   0.20 ADDC +  0.73 MCT + //
                      0.73 HO2 + //
                      0.014 AnBlP + 0.09 AnBmP
KINETIC ARR2   6.75E-12   -405.
!  --- DEGRADATION COMBINED WITH CSL FROM MCMV3.1
% modification for SOA formation (YS:2009/10/06)
%
% R114 
CSL +  HO        -> 0.07 CHO +   0.20 ADDC +  0.73 MCT + //
                      0.73 HO2 + //
                     0.014 AnBlP + 0.09 AnBmP
KINETIC ARR1   4.65E-11
!  --- PRODUCTS AND RATE CONSTANT FROM MCM V3.1 
% SOA modification
%
% R115 
MCT +  HO        ->      MCTO
KINETIC ARR1  2.05E-10
!PRODUCTS FROM MCM V3.1
% R116 
MCT +  NO3       ->      MCTO   +     HNO3
KINETIC ARR1  2.01E-10
! --- PRODUCTS FROM MCM V3.1
% R117 
MCTO + O3        ->      MCTP
KINETIC ARR1   2.86E-13
!PRODUCTS FROM MCM V3.1
% R118 
MCTO + NO2       ->      ONIT
KINETIC ARR1   2.08E-12
!PRODUCTS FROM MCM V3.1
% R119 
MCTP + NO        ->      MCTO   +     NO2
KINETIC ARR2   2.70E-12     -360.
!PRODUCTS FROM MCM V3.1
% R120 
MCTP + MO2       ->      HCHO   +     HO2     +    MCTO 
KINETIC ARR2   3.56E-14     -708. 
! --- PRODUCTS FROM MCM V3.1
% R121 
MCTP + ACO3      ->      MO2    +     HO2    +     MCTO
KINETIC ARR2   7.40E-13     -708.
! --- PRODUCTS FROM MCM V3.1
% R122 
MCTP + HO2       ->      OP2
KINETIC ARR2  3.75E-13     -980.
! --- PRODUCTS FROM MCM V3.1
% R123 
MCTP + NO3       ->      MCTO   +     NO2
KINETIC ARR1   1.20E-12
% R124 HCHO + HO        ->      HO2    +     CO    +      H2O
HCHO + HO        ->      HO2    +     CO
KINETIC ARR2  5.50E-12     -125.0
!  --- NASA 2006
% R125 ACD +  HO        ->      ACO3  +      H2O
ACD +  HO        ->      ACO3
KINETIC ARR2  4.38E-12   -366.0
!  --- Sivakuman and Crowley, 2002
% R126 ALD +  HO        ->      RCO3  +      H2O
ALD +  HO        ->      RCO3
KINETIC ARR2   5.10E-12   -405.0
!  --- IUPAC 2006 PROPANAL RATE (WEB VERSION OCTOBER 2006) 
%
% R127 ACT +  HO        ->      ACTP   +     H2O
ACT +  HO        ->      ACTP 
KINETIC SPEC -8 
!SPECIAL RWK(#) = 1.39E-13+3.72E-11*EXP(-2044./TEMP)
! --- ACETONE RATE TAKEN FROM GIERCZAK ET AL., 2003
%
% R128 MEK +  HO        ->      MEKP   +     H2O
MEK +  HO        ->      MEKP
KINETIC ARR2  1.30E-12     25.0
! --- METHYL ETHYL KETONE
! --- IUPAC WEB VERSION OCTOBER 2006
% R129 KET +  HO        ->      KETP   +     H2O
KET +  HO        ->      KETP
KINETIC ARR2  2.80E-12   - 10.0
! --- KETONE TREATED AS DIETHYL KETONE
! WALLINGTON AND KURYLO, 1987
% R130 HKET + HO        ->      HO2   +      MGLY   +     H2O
HKET + HO        ->      HO2   +      MGLY
KINETIC ARR1  3.00E-12
!  --- ORLANDO ET AL. 1999
% R131 GLY +  HO        ->      HO2  +  2.0  CO     +     H2O
GLY +  HO        ->      HO2  +  2.0  CO 
KINETIC ARR1  1.10E-11
! --- ATKINSON AND AREY 2003 RECOMMENDS 40% O2-ADDITION,
! BUT IT DOESN'T SEEM RESONABLE TO ADD THIS TO ACO3 BECAUSE
! OF MUCH FASTER HO-REACTION AND PHOTOLYSIS OF THE RESULTING
! PEROXYNITRATE, THE PRODUCTS OF THE NO REACTION OF THE
! PEROXY RADICAL AND OF THE REACTIONS OF THE PEROXYNITRATE
! ARE RELATIVELY SIMILAR TO THE PRODUCTS GIVEN ABOVE
% R132 MGLY + HO        ->      ACO3    +    CO    +      H2O
MGLY + HO        ->      ACO3    +    CO
KINETIC ARR2   9.26E-13   -830.
!  --- ATKINSON ET AL. 2006 RECOMMENDED ROOM TEMP K
!  --- WITH TYNDALL ET AL. 1995 E/R
% R133 
MACR + HO        -> 1.0  MACP   
KINETIC ARR2  1.86E-11  -176.
!1.86E-11  -176  3.36E-11
!  --- GEIGER ET AL. 2003
% R134 
MVK +  HO        ->      MVKP
KINETIC ARR2   2.60E-12   -610.
!4.14E-12  -453  1.89E-11
!  --- ATKINSON AND AREY 2003
% R135 
UALD + HO        -> .313 ACO3 +  .687 UALP
KINETIC ARR2   5.77E-12   -533.0
!  --- BASED ON CROTONALDEHYDE C4H6O
!  --- MAGNERON ET AL. 2002
%
% R136 
EPX +  HO        ->      XO2   +      HO2  +   ALD + //
                           CO
KINETIC ARR2   2.8E-11    -175.
!  --- CARTER 2000 -- WAS DCB1
% R137 
DCB2 + HO        ->      XO2   +      ACO3   +     ALD
KINETIC ARR2  2.8E-11    -175.
!  --- CARTER 2000
% R138 
DCB1 + HO        ->      XO2    +     ACO3   +     ALD
KINETIC ARR2   2.8E-11    -175.
!  --- CARTER 2000 - WAS DCB3
% R139 DCB3 + HO        ->      ACO3  +      CO    +      H2O
DCB3 + HO        ->      ACO3  +      CO 
KINETIC ARR1   1.00E-13
!  --- CARTER 2000 - a new DCB3 - same products and rate as MGLY
! --- bigger decrease in rate constant
% R140 
OP1 +  HO        -> .65  MO2  +  .35  HCHO + 0.35  HO
KINETIC ARR2   2.90E-12   -190.0
!  --- ATKINSON AND AREY 2003
%
% R141 
OP2 +  HO        -> 0.44 HC3P +  0.08 ALD +  0.49  HO + //
                      0.07 XO2 +   0.41 KET
KINETIC ARR2   3.40E-12   -190.0
!  --- ESTIMATED FOR PROPYL HYDROPEROXIDE
%
% R142 
PAA +  HO        -> 0.65 ACO3 +  0.35 HO  +  0.35  HCHO + //
                      0.35 XO2
KINETIC ARR2   2.93E-12   -190.0
!  --- FROM OP1 + HO
!  --- Yields corrected according to Kirchner communication
% R143 PAN +  HO    ->   HCHO  +    NO3   +  XO2 +  H2O
PAN +  HO    ->   HCHO  +    NO3   +  XO2
KINETIC ARR1   4.00E-14
!  --- UPPER LIMIT NASA 2006
% R144 PPN +  HO    ->   HCHO  +   NO3  +    XO2 +  H2O
PPN +  HO    ->   HCHO  +   NO3  +    XO2
KINETIC ARR1   4.00E-14
!  --- UPPER LIMIT NASA 2006 (same as PAN)
% R145 
MPAN + HO        -> 1.00 HACE +  1.00 NO2
KINETIC ARR1   3.20E-11
! --- ORLANDO ET AL. 2002
% R146 ONIT + HO        ->      HC3P   +     NO2   +      H2O
ONIT + HO        ->      HC3P   +     NO2 
KINETIC ARR2   5.31E-12   260.0
! --- RATE CONSTANT TAKEN TO BE AS HC3,
! DECOMPOSITION ASSUMED
% R147 ORA1 + HO        ->      HO2   +      CO2
ORA1 + HO        ->      HO2
KINETIC ARR1   4.50E-13
! --- SINGLETON ET AL. 1988
% R148 
ORA2 + HO        -> 0.64 MO2 +   0.64 CO2 +  0.36  ORAP
KINETIC ARR2   2.20E-14   -1012.0
! --- BUTKOVSKAYA ET AL. 2004 AND SMEDT ET AL. 2005
% R149 
HCHO + NO3       ->      HO2    +     HNO3   +     CO
KINETIC ARR2   2.00E-12    2440.0
! --- RATE CONST ATKINSON ET AL. 2006 ATMOS CHEM PHYS V6
!  (ACTUAL TEMP DEPENDENCE UNKNOWN)
% R150 
ACD +  NO3       ->      ACO3   +     HNO3
KINETIC ARR2   1.40E-12   1900.0
!  --- NASA 2006
% R151 
ALD +  NO3       ->      RCO3   +     HNO3
KINETIC ARR2   3.76E-12   1900.0
!  ---  (BASED ON PROPANAL)
!  ---  USED PREFERRED VALUE OF K(298) ATKINSON ET AL.
!  ---  TO FIND A FACTOR USING ACD E/R
% R152 
GLY +  NO3       ->      HNO3   +     HO2 +  2.0   CO
KINETIC ARR2   2.90E-12   1900.0
! --- ASSUMED TO BE THE SAME AS 2*K(ALD)-K(ETH)
! E/R FROM ALD + NO3
% R153 
MGLY + NO3       ->      HNO3   +     ACO3    +    CO
KINETIC ARR2   3.76E-12   1900.0
!  --- ASSUMED TO SAME AS ALD + NO3 
%
% R154 (0.5 CO2 as a product)
EPX +  NO3       -> 1.50 HO2 +   0.50 HO  +  1.50  CO + //
                   GLY +   0.50  NO2 + 0.50 HNO3
KINETIC ARR2   2.87E-13   1000.0
! --- RATE K: BIERBACH ET AL.1994,
! E/R: MEAN OF OL11 AND ALD. Products from DCB1 + O3 -- WAS DCB1
% R155 
PHEN + NO3       -> 0.5  HNO3 +  0.4  CHO +  0.5   ADCN + //
                      0.1  ADDC + //
                      0.04 AnBlP + 0.12 AnBmP
KINETIC ARR1   3.78E-12
!  --- CARTER 2000
% modification for SOA formation (YS: 2009/10/06)
%
% R156 
CSL +  NO3       -> 0.5  HNO3 +  0.4  CHO +  0.5   ADCN + //
                      0.1  ADDC + //
                      0.04 AnBlP + 0.12 AnBmP
KINETIC ARR1   1.06E-12
!  ---PRODUCTS FROM MCM V3.1 
% SOA modification (YS)
%
% R157 
ADCN +  NO        ->      GLY +   2.00 NO2   +      OP2
KINETIC ARR2   2.70E-12   -360.
!  --- PRODUCTS FROM MCM V3.1
% R158 
ADCN +  NO3       ->      OP2   +      GLY +  2.0   NO2 
KINETIC ARR1   1.20E-12
!  --- PRODUCTS FROM MCM V3.1
% R159 
ADCN +  MO2       ->      HCHO  +      HO2 +  0.7   OP2 + //
                      0.7  GLY +   0.7  NO2 +  0.3   ONIT
KINETIC ARR1   3.56E-14
!  --- PRODUCTS FROM MCM V3.1
% R160 
ADCN + ACO3      ->      MO2   +      HO2 +  0.7   OP2 + //
                      0.7  GLY +   0.7  NO2 +  0.3   ONIT
KINETIC ARR2   7.40E-13   -708.
! --- PRODUCTS FROM MCM V3.1
%
% R161 
ADCN + HO2       ->      OP2
KINETIC ARR2  3.75E-13   -980.     
! --- PRODUCTS FROM MCM V3.1
% R162 
ETE +  NO3       -> 0.80 OLNN +  0.20 OLND
KINETIC ARR3   4.88E-18  2.  2282.0
!  --- RATE K ATKINSON AND AREY 2003
% R163 
OLT +  NO3       -> 0.43 OLNN +  0.57 OLND + //
                    0.0016 AnBlP
KINETIC ARR2   1.79E-13    450.0
!  --- DIFFICULT TO LUMP BECAUSE OF VERY DIFFERENT K
% SOA modification (YS)
%
% R164 
OLI +  NO3       -> 0.11 OLNN +  0.89 OLND + //
                    0.003 AnBlP
KINETIC ARR2   8.64E-13    -450.
!  --- DIFFICULT TO LUMP BECAUSE OF VERY DIFFERENT K
% SOA modification (YS)
%
% R165 
DIEN + NO3       -> 0.90 OLNN +  0.10 OLND + 0.90  MACR
KINETIC ARR1   1.00E-13
! From ATKINSON AND AREY 2003, Value for 298
% R166 
ISO +  NO3       -> 1.00 ISON
KINETIC ARR2   3.03E-12     446.
! --- GEIGER ET AL. 2003
% R167 
MACR + NO3       -> 0.5  MACP +  0.5  HNO3 + 0.5   CO + //
                      0.5  HO2  +  0.5  ONIT + 0.5   XO2
KINETIC ARR1   3.40E-12
! --- ATKINSON ET AL. 2006
% R168 
UALD + NO3       -> .668 CO  +  .332  HCHO + .332  ALD + //
                           ONIT  +      HO2   +      XO2
KINETIC ARR2   5.02E-13    1076.0
!  --- BASED ON CROTONALDEHYDE
!  --- SALGADO ET AL. 2008
% R169 
API +  NO3       -> 0.10 OLNN +  0.90 OLND + //
                    0.8 BiBmP
KINETIC ARR2   1.19E-12   -490.0
!  --- ATKINSON AND AREY 2003
% SOA module (YK)
%
% R170 
LIM +  NO3       -> 0.13 OLNN +  0.87 OLND + //
                    0.309 BiA0D + 0.02 BiA1D 
KINETIC ARR1   1.22E-11 
!  --- ATKINSON AND AREY 2003
% SOA module (YK)
%
% R171 
MPAN + NO3       -> 1.00 MACP +  1.00 NO2
KINETIC ARR2   2.20E-14    500.0
!  -- ACTS LIKE A PEROXY RADICAL -- BASED ON GEIGER ET AL. 2003
% R172 (0.13 H2 as a product)
ETE +  O3        ->      HCHO +  0.43 CO  +  0.37  ORA1 + //
                      0.26 HO2   +  0.12  HO
KINETIC ARR2  9.14E-15   2580.0
!  --- RATE CONSTANT AND PRODUCTS FROM ATKINSON 1994
!  --- RATE CONSTANT UNCHANGED IN IUPAC 2006
% R173 (0.05 H2 as a product)
OLT +  O3        -> 0.64 HCHO +  0.44 ALD +  0.37  CO + //
                      0.14 ORA1 +  0.10 ORA2 + 0.25  HO2 + //
                      0.40 HO  +   0.03 KET +  0.03  KETP + //
                      0.06 CH4  +  0.03  ETH + //
                      .006 H2O2 +  0.19 MO2 +  0.10  ETHP + //
                      0.0016 AnBlP 
KINETIC ARR2   4.33E-15   1800.0
!  --- RATE CONSTANT AND PRODUCTS ESTIMATED FROM ATKINSON 1994
!  --- RATE CONSTANT IS TAKEN AS AVERAGE FOR US EMISSIONS
% SOA modification (YS)
%
% R174 
OLI +  O3        -> 0.02 HCHO  + 0.99 ALD  + 0.16  KET + //
                      0.30 CO  +   .011 H2O2 + 0.14  ORA2 + //
                      0.07 CH4  +  0.22 HO2  + 0.63  HO + //
                      0.23 MO2  +  0.12 KETP + 0.06  ETH + //
                      0.18 ETHP + //
                      0.003 AnBlP
KINETIC ARR2   4.40E-15   845.0
!  --- RATE CONSTANT AND PRODUCTS ESTIMATED FROM ATKINSON 1994
!  --- RATE CONSTANT IS TAKEN AS AVERAGE FOR US EMISSIONS
% SOA modification (YS)
%
% R175 (0.05 H2 as a product)
DIEN + O3        -> 0.90 HCHO +  0.39 MACR + 0.36  CO + //
                      0.15 ORA1 +  0.09 O3P +  0.30  HO2 + //
                      0.35 OLT  +  0.28 HO  + // 
                      0.15 ACO3 +  0.03 MO2 +  0.02  KETP + //
                      0.13 XO2  +  .001 H2O2
KINETIC ARR2   1.34E-14    2283.0
! --- RATE CONSTANT ATKINSON AND AREY 2003
! PRODUCTS SAME AS FOR ISO + O3
% R176 
ISO +  O3        -> 0.58 HCHO +  .461 MACR + .189  MVK + //
                      0.28 ORA1 +  0.25 HO  +  0.25  HO2 + //
                      0.14 CO  +    0.1 ACO3 + 0.08  MO2 + //
                      0.09 H2O2 +  0.1  MACP
KINETIC ARR2   7.86E-15   1913.
!7.86E-15  1912  1.29E-17
!  --- GEIGER ET AL. 2003
!  --- MACR-MVK split according to Carter 1996
% R177 
MACR + O3        -> 0.10 ACO3 +  0.90 MGLY + 0.32  HO2 + //
                      0.22 CO  +   0.19 HO  +  0.45  ORA1
KINETIC ARR2   1.36E-15   2112.0
! --- MACR= METHACROLEIN, ATKINSON 1994
!  --- GEIGER ET AL. 2003
% R178 (0.17CO2 as a product) 
MVK +  O3        -> 0.67 ORA1 +  0.11 HO  +  0.11  HO2 + //
                      0.11 CO  +    0.95  MGLY + //
                      0.05 HCHO +  0.05 HO  +  0.05  XO2 + //
                      0.05 HCHO +  0.05 ACO3
KINETIC ARR2   7.51E-16   1520.
!7.51E-16  1520  4.59E-18
! --- CARTER SAPRAC-99
% R179 
UALD + O3        -> .476 HO  +   .072 HO2 +  .168  MO2 + //
                      .237 ACO3 +  0.1  XO2 +  .243  CO + //
                      .218 HCHO +  .062 ALD +  .278  KET + //
                      .031 GLY  +  .653 MGLY  + .044  ORA1
KINETIC ARR1   1.66E-18
!  --- BASED ON CROTONALDEHYDE
!  --- K AVE OF GROSJEAN AND GROSJEAN 1998 AND SATO ET
!  --- AL. 2004
% R180 
API +  O3        -> 0.65 ALD  +  0.53 KET +  0.14  CO + //
                      0.20 ETHP +  0.42 KETP + 0.85  HO + //
                      0.10 HO2  +  0.02 H2O2 + //
                      0.127 BiA0D + 0.142 BiA1D + 0.044 BiA2D
KINETIC ARR2   5.00E-16    530.0
!  --- ATKINSON AND AREY 2003
% SOA modification (YS)
%
% R181 
LIM  + O3        -> 0.04 HCHO +  0.46 OLT +  0.14  CO + //
                      0.16 ETHP +  0.42 KETP + 0.85  HO + //
                      0.10 HO2  +  0.02 H2O2 + 0.79  MACR + //
                      0.01 ORA1 +  0.07 ORA2 + //
                      0.197 BiA0D + 0.094 BiA1D
KINETIC ARR2   2.95E-15     783.0
!  --- ATKINSON AND AREY 2003
% SOA modification (YS)
%
% R182 (0.5 CO2 as a product) 
EPX + O3        -> 1.5  HO2 +   0.5  HO +   1.5   CO + //
                      GLY
KINETIC ARR1   1.0E-16
!  --- CARTER 2000 -- increased A-FACT to be more like to OLI+O3 - WAS DCB1
!  --- increase rate constant by a factor of 5
% R183 
DCB3 + O3        -> 1.0  HO2  +  0.5  HO  +   1.5  CO + //
                      0.5  CO2  +  0.25 ORA1 +  0.25 ORA2 + //
                     0.11  PAA +   2.48 MGLY
KINETIC ARR1   8.0E-17
!  --- new reaction for DCB3 - lower rate const by one order of magnitude
% R184 
CHO +  NO2       ->      ONIT
KINETIC ARR1   2.00E-11
!  --- CARTER 2000
% R185 
ACO3 + NO2       ->      PAN
KINETIC TROE4    8.50E-29   6.5   1.10E-11  1.0
!  --- Tyndall et al. 2001
% R186 
RCO3 + NO2       ->      PPN
KINETIC TROE4   8.50E-29   6.5   1.10E-11   1.0
!  --- Tyndall et al. 2001 for PAN (based upon ACD scheme)
% 
% R187 
PAN             ->      ACO3   +     NO2
KINETIC RCFE  9.70E-29 5.6 9.30E-12  1.5  1.16D28   13954.
!  --- NASA 2006
% the inverse of the equilibrium constant taken: Stockwell et al, 1997
% 
% R188 
PPN             ->      RCO3   +     NO2
KINETIC RCFE  9.70E-29 5.6 9.30E-12  1.5  1.16D28   13954.
!  --- NASA 2006 for PAN
% the inverse of the equilibrium constant taken: Stockwell et al, 1997
%
% R189 
MACP + NO2       ->      MPAN
KINETIC ARR2   2.80E-12   -181.
!2.80E-12  -181  5.14E-12
% R190 
MPAN            ->      MACP    +    NO2
KINETIC ARR2   1.60E+16   13486.
!1.60E+16  13486  3.63E-04
! --- GEIGER ET AL. 2003 -- RATE CONST FROM ROBERTS AND BERTMAN 1992
!  --- AS USED BY CARTER AND ATKINSON 1996
% R191 
MO2  + NO        ->      HCHO   +     HO2    +     NO2
KINETIC ARR2   2.80E-12   -300.0
!  --- NASA 2006
% R192 
ETHP + NO        ->      ACD    +     HO2    +     NO2
KINETIC ARR2   2.60E-12    -365.0
!  --- NASA 2006
% R193 
HC3P + NO        -> .047 HCHO +  .233 ALD +  .623  ACT + //
                      .063 GLY  +  .742 HO2 +  .150  MO2 + //
                      .048 ETHP +  .048 XO2 +  .059  ONIT + //
                      .941 NO2
KINETIC ARR1   4.00E-12
! --- RATE K FROM 2-N-C4H9O2 + NO (LACTOZ) AND
! --- FROM T-C4H9O2 + NO (LIGHTFOOT 1992) AS REFERENCED BY
! --- KIRCHNER AND STOCKWELL, 1996
! --- REPLACED KET WITH ACT -- PRODUCED FROM PROPANE OXID
% R194 
HC5P +  NO        -> .021 HCHO +  .211 ALD +  .500  KET + //
                      .599 HO2 +   .031 MO2  + .245  ETHP + //
                      .334 XO2 +   .124 ONIT + .876  NO2 + //
                      .122 MEK +   .100 ACT
KINETIC ARR1   4.00E-12
!  --- KIRCHNER AND STOCKWELL, 1996
!  --- DIVIDED KET AMONG KET, MEK AND ACT FOR MASS BALANCE
% R195 
HC8P + NO        -> .150 ALD +   .642 KET +  .133  ETHP + //
                      .261 ONIT +  .739 NO2 +  .606  HO2 + //
                      .416 XO2
KINETIC ARR1   4.00E-12
!  --- KIRCHNER AND STOCKWELL, 1996
% R196 
ETEP + NO        -> 1.6  HCHO  +      HO2   +      NO2 + //
                      0.2  ALD
KINETIC ARR1   9.00E-12
!  --- ATKINSON AND AREY 2003
% R197 
OLTP + NO        -> 0.94 ALD   +      HCHO   +     HO2 + //
                           NO2 +   0.06 KET
KINETIC ARR1   4.00E-12
!  --- KIRCHNER AND STOCKWELL, 1996
% R198 
OLIP + NO        ->      HO2  +  1.71 ALD +  0.29  KET + //
                           NO2
KINETIC ARR1   4.00E-12
!  --- KIRCHNER AND STOCKWELL, 1996
%
% R199 
ISOP + NO        -> .046 ISON +  .954 NO2 +  .954  HO2 + //
                      1.00 HCHO +  .418 MACR + .582  MVK
KINETIC ARR2   2.43E-12   -360.
! --- GEIGER ET AL. 2003
!  --- MACR AND MVK split according to Carter 1996
% R200 
MACP + NO        ->      NO2  +  0.25 ACO3 + 0.25  HACE + //
                      0.25 CO  +   0.75 HCHO + 0.50  MGLY + //
                      0.75 HO2
KINETIC ARR2   2.54E-12    -360.
!  --- GEIGER ET AL. 2003
%
% R201 
MVKP + NO        ->      NO2  +  0.7  ALD +  0.7   XO2 + //
                      0.7  ACO3 +  0.3  HCHO + 0.3   MGLY + //
                      0.3  HO2
KINETIC ARR2  4.20E-12   -181.
!4.20E-12  -181  7.71E-12
% R202 
MEKP + NO        -> 0.67 DCB1 +  0.67 HO2 +  0.33  HCHO + //
                           NO2
KINETIC ARR1  4.00E-12
!  --- ESTIMATED TO EQUAL TO MO2 AND ETHP
!  --- KIRCHNER AND STOCKWELL, 1996
% R203 
UALP + NO        ->      NO2    +     HO2  + 0.61  CO + //
                      0.27 ALD  +  0.03 HCHO + 0.18  GLY + //
                      0.21 MGLY +  0.7  KET
KINETIC ARR2   4.20E-12   -181.
!4.20E-12  -181  7.71E-12
% R204 
APIP + NO        -> 0.82 HO2  +  0.43 ALD +  0.82  NO2 + //
                      0.44 KET  +  0.18 ONIT + 0.23  HCHO + //
                      0.11 ACT  +  0.07 ORA1
KINETIC ARR1   4.00E-12
!  --- KIRCHNER AND STOCKWELL, 1996
!  --- PRODUCTS FROM ATKINSON REVIEW 2003(?)
%
% R205 
LIMP + NO        -> 0.90 HO2  +  0.25 MACR + 0.25  KET + //
                      0.03 ACT  +  0.90 NO2 +  0.10  ONIT
KINETIC ARR1   4.00E-12
!  --- KIRCHNER AND STOCKWELL, 1996
!  --- PRODUCTS FROM ATKINSON REVIEW 2003(?)
% R206 
BENP + NO        -> .082 ONIT + .918 HO2 +  .459  UALD + //
                      .918 NO2  +  .459 OLI +  .918  GLY
KINETIC ARR2   2.54E-12   -360.
!  --- FROM MCM V3.1
% R207
XYOP + NO        -> 0.95 HO2  +  .350 GLY +  .600  MGLY + //
                      .700 DCB1 +  .073 DCB2 + .177  DCB3 + //
                      0.05 ONIT +  0.95 NO2 + //
                      0.023 AnBlP + 0.32 AnBmP
KINETIC ARR2   2.70E-12   -360.
!  --- using RACM1 product yields and dividing DCB value among DCB1,2,3
% R208 
ADDC + NO        ->      NO2  +       HO2  +  0.68  GLY + //
                      0.68 OP2  +  0.32 HKET
KINETIC ARR2   2.70E-12   -360.
! --- PRODUCTS FROM MCM V3.1 
% R209 
ACO3 + NO        ->      MO2    +     NO2
KINETIC ARR2   8.10E-12    -270
!  --- Tyndall et al. 2001
% R210 
RCO3 + NO        ->      ETHP   +     NO2
KINETIC ARR2   8.10E-12    -270
!  --- Tyndall et al. 2001
% R211 
KETP + NO        -> 0.54 MGLY +  0.46 ALD +  0.23  ACO3 + //
                      0.77 HO2  +  0.16 XO2  +       NO2
KINETIC ARR1   4.00E-12
! --- RATE K FROM HCP3 + NO
! PRODUCTS 50% FROM ACET\356NE AND 50% FROM MEK
! --- RATE K FROM HCP3 + NO
% R212 
ACTP + NO        -> 1.00 ACO3 +  1.00 NO2 +  1.00  HCHO
KINETIC ARR2   2.90E-12  -300.0
! --- JPL 2006 RATE CONSTANT
% R213 
OLNN + NO        ->      ONIT    +    NO2    +     HO2
KINETIC ARR1   4.00E-12
! --- RATE K FROM HCP3 + NO
% R214
OLND + NO        -> .287 HCHO +  1.24 ALD +  .464  KET + //
                      2.00 NO2
KINETIC ARR1   4.00E-12
!  --- RATE K FROM HCP3 + NO
%
% R215 
MO2 +  HO2       ->      OP1
KINETIC ARR2   4.10E-13  -750.0
!  --- NASA 2006
%
% R216 
ETHP + HO2       ->      OP2
KINETIC ARR2   7.50E-13  -700.0
!  --- NASA 2006
%
% R217 
HC3P + HO2       ->      OP2
KINETIC ARR2   1.66E-13  -1300.0
!  --- KIRCHNER AND STOCKWELL, 1996
%
% R218 
HC5P + HO2       ->      OP2
KINETIC ARR2   1.66E-13  -1300.0
!  --- KIRCHNER AND STOCKWELL, 1996
%
% R219 
HC8P + HO2       ->      OP2
KINETIC ARR2   1.66E-13  -1300.0
!  --- KIRCHNER AND STOCKWELL, 1996
%
% R220 
ETEP + HO2       ->      OP2
KINETIC ARR2   1.90E-13  -1300.0
!  --- KIRCHNER AND STOCKWELL, 1996; LEBRAS 1997
%
% R221 
OLTP + HO2       ->      OP2
KINETIC ARR2   1.66E-13  -1300.0
!  --- KIRCHNER AND STOCKWELL, 1996
%
% R222 
OLIP + HO2       ->      OP2
KINETIC ARR2   1.66E-13  -1300.0
! --- KIRCHNER AND STOCKWELL, 1996
% 
% R223 
ISOP + HO2       ->      ISHP
KINETIC ARR2   2.05E-13  -1300.
!   --- GEIGER ET AL. 2003
% 
% R224 
MACP + HO2       ->      MAHP
KINETIC ARR2   1.82E-13   -1300.
!  --- GEIGER ET AL. 2003
%
% R225 
MVKP + HO2       ->      OP2
KINETIC ARR2   7.70E-14  -1298.
!7.70E-14  -1298  5.99E-12
%
% R226 
UALP + HO2       ->      OP2
KINETIC ARR2   7.70E-14  -1298.
!7.70E-14  -1298  5.99E-12
%
% R227 
APIP + HO2       ->      OP2
KINETIC ARR1   1.50E-11
! --- KIRCHNER AND STOCKWELL, 1996 (EUROTRAC)
%
% R228 
LIMP + HO2       ->      OP2
KINETIC ARR1   1.50E-11
! --- KIRCHNER AND STOCKWELL, 1996 (EUROTRAC)
% 
% R229 
BENP + HO2       ->      OP2
KINETIC ARR2   2.91E-13   -1300.
!  --- MCM V3.1
%
% R230-1
TOLP + HO2    ->   OP2 + 0.78 AnClP
KINETIC ARR2   3.75E-13   -980.
% Addition from a personal correspondence with W. Goliff
% Rate from XYOP + HO2
%
% R230-2
XYLP + HO2    ->   OP2 + 0.71 AnClP
KINETIC ARR2   3.75E-13   -980.
% Addition from a personal correspondence with W. Goliff
% Rate from XYOP + HO2
%  
% R230 
XYOP + HO2       ->      OP2 + 0.71 AnClP
KINETIC ARR2   3.75E-13   -980.
!  --- CARTER 2000
% SOA formation: Florian (2010/03/03)
%
% R231 
ADDC + HO2       ->      OP2
KINETIC ARR2   3.75E-13  -980.
!  --- CARTER 2000
%
% R232 
CHO +  HO2       ->      CSL
KINETIC ARR1   1.00E-11
!  --- CARTER 2000
%
% R233 (0.4 CO2 as a product)
ACO3 + HO2       ->  0.4 PAA  +   0.2 ORA2 +  0.4  MO2 + //
                       0.4 HO      
KINETIC ARR2   4.3E-13   -1040
! --- products Hasson et al. 2004
! --- Rate constant Tyndall et al. 2001
% 
% R234 (0.4 CO2 as a product)
RCO3 + HO2       ->  0.4 PAA  +   0.2 ORA2 +  0.4  ETHP + //
                       0.4 HO      
KINETIC ARR2   4.3E-13   -1040
! --- products Hasson et al. 2004
! --- Rate constant Tyndall et al. 2001
%
% R235 
ACTP + HO2       -> .330 OP2  +  .670 HO  +  .670  HCHO + //
                      .670 ACO3
KINETIC ARR2   1.15E-13  -1300.0
!   --- RATE FROM KIRCHNER AND STOCKWELL, 1996
!   --- PRODUCTS FROM HASSON ET AL. 2004
%
% R236 
MEKP + HO2       ->      OP2
KINETIC ARR2   1.15E-13 -1300.0
!   --- SAME AS KETP + HO2
%
% R237 
KETP + HO2       ->      OP2
KINETIC ARR2   1.15E-13  -1300.0
!   --- KIRCHNER AND STOCKWELL, 1996; LEBRAS 1997
%
% R238 
OLNN + HO2       ->      ONIT
KINETIC ARR2   1.66E-13  -1300.0
! --- KIRCHNER AND STOCKWELL, 1996
! THIS IS ALSO A PEROXIDE, BUT IT IS TREATED AS AN
! ONIT TO ALLOW FOR NITROGEN CONSERVATION
%
% R239 
OLND + HO2       ->      ONIT
KINETIC ARR2   1.66E-13 -1300.0
! --- KIRCHNER AND STOCKWELL, 1996
! THIS IS ALSO A PEROXIDE, BUT IT IS TREATED AS AN
! ONIT TO ALLOW FOR NITROGEN CONSERVATION
%
% R240 
MO2 +  MO2       -> 1.37 HCHO +  0.74 HO2 +  0.63  MOH
KINETIC ARR2   9.50E-14   -390.0
! --- RATE CONSTANT AS MO2 + MO2, TYNDALL ET AL. 2001
! 33% RO + 67% ROH LIGHTFOOT 1992
%
% R241 
ETHP + MO2       -> 0.75 HCHO    +    HO2 +  0.75  ACD + //
                      .250 MOH  +  .250 EOH
KINETIC ARR2   1.18E-13   -158.0
! --- AS 2*SQRT(KM*KP)
! --- KIRCHNER AND STOCKWELL, 1996; LEBRAS 1997
%
% R242 
HC3P + MO2       -> .827 HCHO  + .894 HO2 +  .198  ALD + //
                      .497 KET +   .080 MO2 +  .250  MOH + //
                      .026 XO2  +  .050 GLY +  .026  ETHP + //
                      .250 ROH
KINETIC ARR2   9.46E-14   -431.0
!  --- KIRCHNER AND STOCKWELL, 1996
%
% R243 
HC5P + MO2       -> .777 HCHO +  .842 HO2 +  .251  ALD + //
                      .618 KET  +  .140 ETHP + .191  XO2 + //
                      .018 MO2  +  .250 MOH +  .250  ROH
KINETIC ARR2   1.00E-13   -467.0
!  --- KIRCHNER AND STOCKWELL, 1996
%
% R244 
HC8P + MO2       -> .750 HCHO  + .910 HO2  + .197  ALD + //
                      .652 KET  +  .281 XO2 +  .090  ETHP + //
                      .250 MOH  +  .250 ROH
KINETIC ARR2   4.34E-14   -633.
!  --- KIRCHNER AND STOCKWELL, 1996
%
% R245 
ETEP + MO2       -> 1.95 HCHO   +     HO2 +  0.15  ALD + //
                      .250 MOH  +  .250 ETEG
KINETIC ARR2   1.71E-13   -708.0
!  --- KIRCHNER AND STOCKWELL, 1996
!  --- ETEG is new species ethylene glycol
%
% R246 
OLTP + MO2       -> 1.50 HCHO   +     HO2  + .705  ALD + //
                      .045 KET +   .250 MOH +  .250  ROH
KINETIC ARR2   1.46E-13   -708.0
!  --- KIRCHNER AND STOCKWELL, 1996
! 50% RO + 50% ROH ASSUMED
%
% R247 
OLIP + MO2       -> .750 HCHO   +     HO2 +  1.28  ALD + //
                      .218 KET  +  .250 MOH +  .250  ROH
KINETIC ARR2   9.18E-14   -708.0
!  --- KIRCHNER AND STOCKWELL, 1996
! 50% RO + 50% ROH ASSUMED
%
% R248 
ISOP + MO2       -> 1.54 HCHO +  1.0  HO2 +  .305  MVK + //
                      .219 MACR +  .250 MOH +  .250  ROH
KINETIC ARR2   3.40E-14  -221.
!  --- BASED ON GEIGER ET AL. 2003
%
% R249 
MACP + MO2       -> 1.50 HCHO +  1.00 HO2 +  .167  HACE + //
                      .167 CO  +   .167 ACO3 + .333  MGLY + //
                      .042 ORA2 +  .250 MOH +  .250  ROH
KINETIC ARR2   3.40E-14  -221.
!3.40E-14  -221  7.14E-14
! --- BASED ON GEIGER ET AL. 2003
%
% R250 
MVKP + MO2       -> 1.5  HCHO +  1.0  HO2 +  1.75  ALD + //
                      1.16 XO2  +  .292 ORA2 + .500  MGLY + //
                      1.16 ACO3 +  .250 MOH +  .250  ROH
KINETIC ARR2   3.40E-14   -221.
!3.40E-14  -221  7.14E-14
%
% R251 
UALP + MO2       -> .773 HCHO +  1.0  HO2 +  .203  ALD + //
                      .525 KET  +  .305 CO  +  .105  MGLY + //
                      .135 GLY  +  .250 MOH +  .250  ROH
KINETIC ARR2   3.40E-14    -221.
!3.40E-14  -221  7.14E-14
%
% R252 
APIP + MO2       -> 1.00 HO2  +  .750 ALD +  .750  HCHO + //
                      .750 KET  +  .250 MOH +  .250  ROH
KINETIC ARR2   3.56E-14   -708.0
!  --- KIRCHNER AND STOCKWELL, 1996 (EUROTRAC)
%
% R253 
LIMP + MO2       -> 1.00 HO2  +  .308 MACR + .192  OLI + //
                      1.04 HCHO +  .250 MOH +  .250  ROH
KINETIC ARR2   3.56E-14    -708.0
!  --- KIRCHNER AND STOCKWELL, 1996 (EUROTRAC)
%
% R254 
BENP + MO2       ->      HCHO +  1.6  HO2 +  .600  GLY + //
                      .300 OLI +   0.7  UALD   +     HO2
KINETIC ARR2   3.56E-14   -708.
!  --- PRODUCTS FROM MCMV3.1 (EXACT CAMPAIGN)
!  --- CHANGE .3 TO .7 UALD AND .7 TO .3 OLI
%
% R255 
TOLP + MO2       ->      HCHO +  2.0  HO2 +  .271  GLY + //
                           DCB2 + 0.78 AnClP
KINETIC ARR2   3.56E-14   -708.
!  --- CARTER 2000
% SOA formation: Florian (2010/03/03)
%
% R256 
TLP1 + MO2       ->      HCHO +  1.0  HO2    +     BALD
KINETIC ARR2   3.56E-14   -708.
!  --- CARTER 2000
%
% R257 
PER1 + MO2       ->      HCHO +  2.0  HO2    +     MGLY + //
                           DCB1
KINETIC ARR2   3.56E-14   -708.
!  --- CARTER 2000
%
% R258 
XYOP + MO2       ->      HCHO +  2.0  HO2  + .368  GLY + //
                      .632 MGLY +  .737 DCB1 + .077  DCB2 + //
                      .186 DCB3 + 0.71 AnClP
KINETIC ARR2   3.56E-14   -708.
!  --- CARTER 2000
% SOA formation: Florian (2010/03/03)
%
% R259 
XYL1 + MO2       ->      HCHO +  1.0  HO2   +      BALD
KINETIC ARR2   3.56E-14    -708.
!  --- CARTER 2000
%
% R260 
XYLP + MO2       ->      HCHO  + 2.0  HO2   +      DCB2 + //
                         0.71 AnClP
KINETIC ARR2   3.56E-14   -708.
!  --- CARTER 2000
% SOA formation: Florian (2010/03/03)
%
% R261 
PER2 + MO2       ->      HCHO +  2.0  HO2   +      MGLY + //
                           DCB1 +  2.05 DCB3
KINETIC ARR2   3.56E-14   -708.
!  --- CARTER 2000
%
% R262 
BALP + MO2       ->      HCHO +  1.0  HO2    +     BAL1
KINETIC ARR2   3.56E-14   -708.
!  --- CARTER 2000
%
% R263 
BAL1 + MO2       ->      HCHO +  1.0  HO2    +     BAL2
KINETIC ARR2   3.56E-14    -708.
!  --- CARTER 2000
%
% R264 
ADDC + MO2       ->      HCHO +  2.0  HO2  +  .68  GLY + //
                      0.32 HKET +  0.68 OP2
KINETIC ARR2   3.56E-14   -708.
!  ---PRODUCTS FROM MCM V3.1 
%
% R265 (0.4  CO2 as a product)
ACO3 + MO2       ->      HCHO +  0.9  HO2 +  0.90  MO2 + //
                      0.1  ORA2   
KINETIC ARR2   2.0E-11    -500.0
!  --- Products and rate constant Tyndall et al. 2001
%
% R266 (0.4  CO2 as a product)
RCO3 + MO2       ->      HCHO +  0.9  HO2 +  0.9   MO2 + //
                      0.1  ORA2
KINETIC ARR2   2.0E-11    -500.0
!  --- Products and rate constant Tyndall et al. 2001
%
% R267 
ACTP + MO2       -> 0.25 ROH  +  1.50 HCHO + 0.50  ACO3 + //
                      0.25 MOH +   0.50 HO2 +  .125  ORA2
KINETIC ARR2   7.50E-13   -500.0
! --- JPL 2006 RATE CONSTANT
%
% R268 
MEKP + MO2       -> .334 DCB1 +  .834 HO2 +  0.25  MOH + //
                      1.00 HCHO +  0.25 ROH
KINETIC ARR2   6.91E-13  -508.0
! --- K, E/R ESTIMATED FOR KET = ACETONE,
! 50% RO + 50% ROH ASSUMED
!  --- KIRCHNER AND STOCKWELL, 1996
%
% R269 
KETP + MO2       -> 0.50 DCB1 +  1.00 HO2 +  0.25  MOH + //
                      0.75 HCHO +  0.25 ROH
KINETIC ARR2   6.91E-13   -508.0
! --- K, E/R ESTIMATED FOR KET = ACETONE,
! 50% RO + 50% ROH ASSUMED
!  --- KIRCHNER AND STOCKWELL, 1996
% 
% R270 
OLNN + MO2       ->      HCHO +  2.00 HO2   +      ONIT
KINETIC ARR2   1.60E-13    -708.0
!  --- AS ISO-ONO2 + MO2
!  --- KIRCHNER AND STOCKWELL, 1996
%
% R271 
OLND + MO2       -> .965 HCHO +  .500 HO2 +  .930  ALD + //
                      .348 KET  +  .500 NO2 +  .250  MOH + //
                      0.25 ROH  +  .500 ONIT
KINETIC ARR2   9.68E-14   -708.0
!  --- KIRCHNER AND STOCKWELL, 1996
%
% R272 
ETHP + ACO3      ->      ACD  +  .500 HO2 +  0.5   MO2 + //
                      0.5  ORA2
KINETIC ARR2   1.03E-12   -211.0
!  --- KIRCHNER AND STOCKWELL, 1996
! 50% RO + 50% ROH ASSUMED
%
% R273 
HC3P + ACO3      -> .273 ALD  +  .662 KET +  .394  HO2 + //
                      .580 MO2 +   .500 ORA2 + .130  HCHO + //
                      .026 ETHP +  .026 XO2 +  .067  GLY
KINETIC ARR2   6.90E-13   -460.0
!  --- KIRCHNER AND STOCKWELL, 1996
%
% R274 
HC5P + ACO3      -> .381 ALD  +  .824 KET +  .342  HO2 + //
                      .518 MO2  +  .500 ORA2 + .042  HCHO + //
                      .140 ETHP +  .191 XO2
KINETIC ARR2   5.59E-13    -522.0
!  --- KIRCHNER AND STOCKWELL, 1996
%
% R275 
HC8P + ACO3      -> .217 ALD +   .642 KET +  .303  HO2 + //
                      .500 MO2 +   .495 ORA2 + .067  ETHP + //
                      .208 XO2
KINETIC ARR2   2.47E-13   -683.
!  --- KIRCHNER AND STOCKWELL, 1996
%
% R276 
ETEP + ACO3      -> 1.6  HCHO +  0.2  ALD +  0.5   HO2 + //
                      0.5  MO2 +   0.5  ORA2
KINETIC ARR2   9.48E-13   -765.0
! --- KIRCHNER AND STOCKWELL, 1996
! 50% RO + 50% ROH ASSUMED
%
% R277 
OLTP + ACO3      -> .940 ALD    +     HCHO + .500  HO2 + //
                      .500 MO2  +  .500 ORA2 + .060  KET
KINETIC ARR2   8.11E-13   -765.0
!  --- KIRCHNER AND STOCKWELL, 1996
! --- K, E/R ESTIMATED FROM SELF REACTIONS,
! 50% RO + 50% ROH ASSUMED
%
% R278 
OLIP + ACO3      -> 1.71 ALD  +  .500 HO2 +  .500  MO2 + //
                      .290 KET  +  .500 ORA2
KINETIC ARR2   5.09E-13   -765.0
!  --- KIRCHNER AND STOCKWELL, 1996,
! 50% RO + 50% ROH ASSUMED
%
% R279 
ISOP + ACO3      -> 0.5  HO2 +   0.5  MO2 +  0.5   ORA2 + //
                     1.048 HCHO +  .219 MACR + .305  MVK
KINETIC ARR2   8.40E-14   -221.
!8.40E-14  E/R  -221.  1.77E-13 -- SAME AS UALP + ACO3
!  --- BASED ON GEIGER ET AL. 2003
%
% R280 
MACP + ACO3      -> .500 HO2  +  0.5  MO2 +  0.583 ORA2 + //
                      .167 HACE +  .167 CO  +  0.167 ACO3 + //
                      0.33 MGLY  +      HCHO
KINETIC ARR2   8.40E-14   -221.
!8.40E-14  -221  1.77E-13
!  --- BASED ON GEIGER ET AL. 2003 FOR THE MACP+NO REACTION
%
% R281 
MVKP + ACO3      -> 0.5  HO2 +   0.5  MO2 + 1.083  ORA2 + //
                      2.3  ALD +   1.16 XO2  +       HCHO + //
                      0.5  MGLY +  1.16 ACO3
KINETIC ARR2   8.40E-14   -221.
!8.40E-14  -221  1.77E-13
%
% R282 
UALP + ACO3      -> 0.5  HO2  +  0.5  MO2 +  0.5   ORA2 + //
                      0.27 ALD  +  0.7  KET +  .105  MGLY + //
                      0.5  CO  +  .030  HCHO + 0.18  GLY
KINETIC ARR2   8.40E-14   -221.
!8.40E-14  -221  1.77E-13
%
% R283 
APIP + ACO3      ->  .5  HO2   +      ALD  +   .5  MO2 + //
                           KET   +      ORA2
KINETIC ARR2   7.40E-13   -765.0
!  --- KIRCHNER AND STOCKWELL, 1996 (EUROTRAC-PROCEEDINGS)
% 
% R284 
LIMP + ACO3      ->  .5  HO2 +   .308 MACR + 0.192 OLI + //
                      .385 HCHO  +   .5 MO2  +   .5  ORA2
KINETIC ARR2   7.40E-13    -765.0
!  --- KIRCHNER AND STOCKWELL, 1996 (EUROTRAC-PROCEEDINGS)
%
% R285 
BENP + ACO3      ->      MO2  +  0.60 HO2 +  .600  GLY + //
                      .700 UALD +  0.30 OLI
KINETIC ARR2   7.40E-13    -765.
!  --- PRODUCTS FROM MCMV3.1
! - change 0.3 uald to 0.7 uald and change .7 to .3 oli
%
% R286 
TOLP + ACO3      ->      DCB2   +     HO2   +      MO2 + //
                         0.78 AnClP
KINETIC ARR2   7.40E-13   -765.
! --- NEW MECHANISM FOR TOL BASED ON CALVERT 2002 FOR TOL
% SOA formation: Florian (2010/03/03)
%
% R287 
TLP1 + ACO3      -> 1.00 MO2  +  1.00 BALD
KINETIC ARR2   7.40E-13   -765.
! --- NEW MECHANISM FOR TOL BASED ON CALVERT 2002 FOR TOL
%
% R288 
PER1 + ACO3      ->      DCB1   +     MO2    +     MGLY + //
                           HO2
KINETIC ARR2   7.40E-13    -765.
! --- NEW MECHANISM FOR TOL BASED ON CALVERT 2002 FOR TOL
%
% R289 
PER2 + ACO3      ->      DCB1   +     MO2    +     MGLY + //
                           HO2 +   2.05 DCB3
KINETIC ARR2   7.40E-13   -765.
! --- NEW MECHANISM FOR TOL BASED ON CALVERT 2002 FOR TOL
%
% R290 
BALP + ACO3      ->      BAL1    +    MO2
KINETIC ARR2   7.40E-13   -765.
!same as NO reaction but with different rate constant
%
% R291 
BAL1 + ACO3      ->      BAL2    +    MO2
KINETIC ARR2   7.40E-13    -765.
!same as NO reaction but with different rate constant
%
% R292 
XYOP + ACO3      ->      MO2     +    HO2 +  .368  GLY + //
                      .632 MGLY +  .737 DCB1 + .077  DCB2 + //
                      .186 DCB3 + 0.71 AnClP
KINETIC ARR2   7.40E-13   -765.
!  --- CARTER 2000
% SOA formation: Florian (2010/03/03)
%
% R293 
XYL1 + ACO3      -> 1.00 MO2  +  1.00 BALD
KINETIC ARR2   7.40E-13  -765.
! --- NEW MECHANISM FOR TOL BASED ON CALVERT 2002 FOR TOL
%
% R294 
XYLP + ACO3      ->      DCB2   +     MO2    +     HO2 + //
                         0.71 AnClP
KINETIC ARR2   7.40E-13   -765.
! --- NEW MECHANISM FOR TOL BASED ON CALVERT 2002 FOR TOL
% SOA formation: Florian (2010/03/03)
%
% R295 
ADDC + ACO3      ->      MO2  +   2.0 HO2  +  .68  GLY + //
                      0.32 HKET +  0.68 OP2
KINETIC ARR2   7.40E-13   -708.
!  --- CARTER 2000
%
% R296 (2.0 CO2 as a product)
ACO3 + ACO3      ->  2.0 MO2     
KINETIC ARR2   2.50E-12   -500.0
!  --- LIGHTFOOT 1992, Rate constant Tyndall et al. 2001
%
% R297 (2.0 CO2 as a product)
RCO3 + RCO3      ->  2.0 ETHP    
KINETIC ARR2   2.50E-12    -500.0
!  --- LIGHTFOOT 1992, Rate constant Tyndall et al. 2001
%
% R298 
KETP + ACO3      -> 0.50 DCB1 +  0.50 HO2 +  0.50  ORA2 + //
                      0.50 MO2
KINETIC ARR2   7.51E-13  -565.0
! --- K, E/R ESTIMATED,
! 50% RO + 50% ROH ASSUMED
!  --- KIRCHNER AND STOCKWELL, 1996
%
% R299 
ACTP + ACO3      -> 0.50 MO2   +      HCHO + 0.75  ORA2 + //
                      0.50 ACO3
KINETIC ARR2   7.51E-13   -565.0
! --- K, E/R ESTIMATED,
! --- 50% RO + 50% ROH ASSUMED
!  --- BRIDIER ET AL. 1993 FOR PRODUCTS
!  --- KIRCHNER AND STOCKWELL, 1996 FOR RATE
%
% R300 
MEKP + ACO3      -> 0.50 MO2  +  0.50 ORA2 + 0.334 DCB1 + //
                      0.33 HO2 +   0.33 HCHO
KINETIC ARR2   7.51E-13   -565.0
! --- K, E/R ESTIMATED,
! 50% RO + 50% ROH ASSUMED
!  --- KIRCHNER AND STOCKWELL, 1996
%
% R301 
OLNN + ACO3      ->      ONIT  + 1.00 MO2 +  1.00  HO2
KINETIC ARR2   8.85E-13   -765.0
!  --- AS ISO-ONO2 + ACO3
!  --- KIRCHNER AND STOCKWELL, 1996
%
% R302 
OLND + ACO3      -> .287 HCHO +  1.24 ALD +  .464  KET + //
                      .500 MO2  +  .500 ORA2   +     NO2
KINETIC ARR2   5.37E-13   -765.0
!  --- KIRCHNER AND STOCKWELL, 1996
% 
% R303 
OLNN + OLNN      -> 2.00 ONIT    +    HO2
KINETIC ARR2   7.00E-14  -1000.0
!  --- KIRCHNER AND STOCKWELL, 1996
%
% R304 
OLNN + OLND      -> .202 HCHO +  .640 ALD +  .149  KET + //
                      .500 HO2  +  .500 NO2 +  1.50  ONIT
KINETIC ARR2   4.25E-14  -1000.0
!  --- KIRCHNER AND STOCKWELL, 1996
%
% R305 
OLND + OLND      -> .504 HCHO +  1.21 ALD +  .285  KET + //
                           ONIT   +     NO2
KINETIC ARR2   2.96E-14  -1000.0
!  --- KIRCHNER AND STOCKWELL, 1996
%
% R306 
MO2 +  NO3       ->      HCHO    +    HO2   +      NO2
KINETIC ARR1   1.20E-12
!  --- KIRCHNER AND STOCKWELL, 1996
%
% R307 
ETHP + NO3       ->      ACD    +     HO2   +      NO2
KINETIC ARR1   1.20E-12 
!  --- KIRCHNER AND STOCKWELL, 1996
%
% R308 
HC3P + NO3       -> .050 HCHO +  .248 ALD  + .662  KET + //
                      .067 GLY  +  .789 HO2 +  .159  MO2 + //
                      .051 ETHP +  .051 XO2  +       NO2
KINETIC ARR1   1.20E-12
!  --- ESTIMATED TO EQUAL TO MO2 AND ETHP
!  --- KIRCHNER AND STOCKWELL, 1996
%
% R309 
HC5P + NO3       -> .024 HCHO +  .241 ALD  + .824  KET + //
                      .684 HO2  +  .035 MO2 +  .280  ETHP + //
                      .381 XO2  +       NO2
KINETIC ARR1   1.20E-12 
!  --- ESTIMATED TO EQUAL TO MO2 AND ETHP
!  --- KIRCHNER AND STOCKWELL, 1996
%
% R310 
HC8P + NO3       -> .203 ALD  +  .869 KET +  .180  ETHP + //
                           NO2  +  .820 HO2 +  .563  XO2
KINETIC ARR1   1.20E-12
!  --- ESTIMATED TO EQUAL TO MO2 AND ETHP
!  --- KIRCHNER AND STOCKWELL, 1996
%
% R311 
ETEP + NO3       -> 1.6  HCHO    +    HO2    +     NO2 + //
                      0.2  ALD
KINETIC ARR1   1.20E-12
!  --- ESTIMATED TO EQUAL TO MO2 AND ETHP
!  --- KIRCHNER AND STOCKWELL, 1996
%
% R312 
OLTP + NO3       -> 0.94 ALD    +     HCHO    +    HO2 + //
                           NO2  +  0.06 KET
KINETIC ARR1   1.20E-12
!  --- ESTIMATED TO EQUAL TO MO2 AND ETHP
!  --- KIRCHNER AND STOCKWELL, 1996
%
% R313 
OLIP + NO3       ->      HO2  +  1.71 ALD +  0.29  KET + //
                           NO2
KINETIC ARR1   1.20E-12
!  --- ESTIMATED TO EQUAL TO MO2 AND ETHP
!  --- KIRCHNER AND STOCKWELL, 1996
%
% R314 
ISOP + NO3       -> .438 MACR +  .610 MVK   +      HO2 + //
                           NO2  +  1.05 HCHO
KINETIC ARR1   1.20E-12
!  --- RATE CONSTANT EQUAL HCP + NO3
!  --- BASED ON GEIGER ET AL. 2003
%
% R315 
APIP + NO3       ->      HO2    +     ALD    +     NO2 + //
                           KET
KINETIC ARR1   1.20E-12
!  --- KIRCHNER AND STOCKWELL, 1996 (EUROTRAC-PROCEEDINGS)
%
% R316 
LIMP + NO3       ->      HO2  +  .615 MACR + 0.385 OLI + //
                      .385 HCHO   +     NO2
KINETIC ARR1   1.20E-12
!  --- KIRCHNER AND STOCKWELL, 1996 (EUROTRAC-PROCEEDINGS)
%
% R317 
BENP + NO3       ->      HO2    +     GLY  + .500  UALD + //
                           NO2 +   0.50 OLI
KINETIC ARR1   1.20E-12
!  --- PRODUCTS FROM MCMV3.1
%
% R318 
XYOP + NO3       ->      HO2 +   .368 GLY +  .632  MGLY + //
                      .737 DCB1 +  .077 DCB2 + .186  DCB3 + //
                           NO2  + 0.023 AnBlP + 0.32 AnBmP
KINETIC ARR1   1.20E-12
!  --- CARTER 2000
% SOA formation: Florian (2010/03/03)
%
% R319 
ADDC + NO3       ->      NO2    +     HO2  +  .68  GLY + //
                      0.68 OP2  +  0.32 HKET
KINETIC ARR1   1.20E-12
!  ---PRODUCTS FROM MCM V3.1 
%
% R320 
ACO3 + NO3       ->      MO2    +     NO2
KINETIC ARR1   4.00E-12
!  --- WAYNE 1995
!  --- KIRCHNER AND STOCKWELL, 1996
!  --- NO UPDATES
%
% R321 
RCO3 + NO3       ->      ETHP   +     NO2
KINETIC ARR1   4.00E-12
!  --- WAYNE 1995
!  --- KIRCHNER AND STOCKWELL, 1996
!  --- NO UPDATES
%
% R322 
MEKP + NO3       -> 0.67 DCB1 +  0.67 HO2 +  0.33  HCHO + //
                           NO2
KINETIC ARR1   1.20E-12
!  --- ESTIMATED TO EQUAL TO MO2 AND ETHP
!  --- KIRCHNER AND STOCKWELL, 1996
%
% R323 
KETP + NO3       -> 1.00 DCB1    +    HO2    +     NO2
KINETIC ARR1   1.20E-12
!  --- ESTIMATED TO EQUAL TO MO2 AND ETHP
!  --- KIRCHNER AND STOCKWELL, 1996
%
% R324 
ACTP + NO3       -> 1.00 ACO3 +  1.00 NO2 +  1.00  HCHO
KINETIC ARR1   1.20E-12
!  --- PRODUCTS FROM THE ACTP+NO REACTION
!  --- RATE FROM KIRCHNER AND STOCKWELL, 1996
%
% R325 
OLNN + NO3       ->      ONIT    +    NO2    +     HO2
KINETIC ARR1   1.20E-12
!  --- ESTIMATED TO EQUAL TO MO2 AND ETHP
!  --- KIRCHNER AND STOCKWELL, 1996
%
% R326 
OLND + NO3       -> .287 HCHO  + 1.24 ALD +  .464  KET + //
                      2.00 NO2
KINETIC ARR1   1.20E-12
!  --- ESTIMATED TO EQUAL TO MO2 AND ETHP
!  --- KIRCHNER AND STOCKWELL, 1996
%
% R327 
MVKP + NO3       ->      NO2  +  0.7  ALD  + 2.3   XO2 + //
                      2.3  ACO3 +  0.3  HCHO   +     MGLY + //
                           HO2
KINETIC ARR1   1.20E-12
!same as NO reaction but with different rate constant
%
% R328 
MACP + NO3       ->      NO2  +  0.33 ACO3 + 0.33  HACE + //
                      0.33 CO    +      HCHO + 0.667 MGLY + //
                           HO2
KINETIC ARR1   1.20E-12
!  --- GEIGER ET AL. 2003 - same as NO reaction but with different rate constant
%
% R329 
TLP1 + NO3       -> 1.00 NO2  +  1.00 BALD
KINETIC ARR1   1.20E-12
! -- same as NO reaction but with different rate constant
! --- NEW MECHANISM FOR TOL BASED ON CALVERT 2002 FOR TOL
%
% R330 
TOLP + NO3       ->      DCB2   +     NO2   +      HO2 + //
                         0.053 AnBlP + 0.336 AnBmP
KINETIC ARR1   1.20E-12
! -- same as NO reaction but with different rate constant
! --- NEW MECHANISM FOR TOL BASED ON CALVERT 2002 FOR TOL
% SOA formation
%
% R331 
PER1 + NO3       ->      DCB1   +     NO2   +      MGLY + //
                           HO2
KINETIC ARR1   1.20E-12
! same as NO reaction but with different rate constant
! --- NEW MECHANISM FOR TOL BASED ON CALVERT 2002 FOR TOL
%
% R332 
XYL1 + NO3       -> 1.00 NO2  +  1.00 BALD
KINETIC ARR1   1.20E-12
! -- same as NO reaction but with different rate constant
! --- NEW MECHANISM FOR XYL BASED ON CALVERT 2002 FOR TOL
%
% R333 
XYLP + NO3       ->      DCB2   +     NO2    +     HO2 + //
                         0.023 AnBlP + 0.32 AnBmP
KINETIC ARR1   1.20E-12
! same as NO reaction but with different rate constant
! --- NEW MECHANISM FOR XYL BASED ON CALVERT 2002 FOR TOL
% SOA formation: Florian(2010/03/03)
%
% R334 
PER2 + NO3       ->      DCB1   +     NO2    +     MGLY + //
                           HO2  +  2.05 DCB3
KINETIC ARR1   1.20E-12
! same as NO reaction but with different rate constant
! --- NEW MECHANISM FOR XYL BASED ON CALVERT 2002 FOR TOL
%
% R335 
BALP + NO3       ->      BAL1   +     NO2
KINETIC ARR1   1.20E-12
!same as NO reaction but with different rate constant
%
% R336 
BAL1 + NO3       ->      BAL2   +     NO2
KINETIC ARR1   1.20E-12
!same as NO reaction but with different rate constant
%
% R337 
UALP + NO3       ->      NO2    +     HO2 +  0.61  CO + //
                      0.27 ALD  +  0.03 HCHO + 0.18  GLY + //
                      0.21 MGLY +  0.7  KET
KINETIC ARR1   1.20E-12
!same as NO reaction but with different rate constant
%
% R338 
XO2 +  HO2       ->      OP2
KINETIC ARR2   1.66E-13  -1300.0
!  --- AS PROP + HO2
!  --- KIRCHNER AND STOCKWELL, 1996
%
% R339 
XO2 + MO2       ->      HCHO   +     HO2
KINETIC ARR2   5.99E-15  -1510.0
!  --- KIRCHNER AND STOCKWELL, 1996
%
% R340 
XO2 + ACO3      ->      MO2
KINETIC ARR2   3.40E-14  -1560.0
!  --- KIRCHNER AND STOCKWELL, 1996
%
% R341 
XO2 +  XO2       ->
KINETIC ARR2   7.13E-17 -2950.0
!  --- KIRCHNER AND STOCKWELL, 1996
%
% R342 
XO2 +  NO        ->      NO2
KINETIC ARR1   4.00E-12
!  --- KIRCHNER AND STOCKWELL, 1996
% 
% R343 
XO2 +  NO3       ->      NO2
KINETIC ARR1   1.20E-12
!  --- KIRCHNER AND STOCKWELL, 1996
%
!342 HCHO  HO2       ->      HCO3    
!THERMAL  A-FACT  9.70E-15  E/R -625.0
!
!343 HCO3            ->      HCHO        HO2
!THERMAL  A-FACT  2.40E+12  E/R 7000.0
!
!344 HCO3  NO        ->      ORA1        NO2         HO2
!THERMAL  A-FACT  5.60E-12  E/R   0.0
!
!345 HCO3  HO2       ->      OP1
!THERMAL  A-FACT  5.60E-15  E/R -2300.0
%
% R344 
ORAP + NO        ->      NO2    +     GLY   +      HO2
KINETIC ARR1   4.00E-12
! --- RATE FROM ACTP + NO
%
% R345 
ORAP + HO2       ->      OP2
KINETIC ARR2   1.15E-13  -1300.0
! --- RATE FROM ACTP + HO2
%
% R346 
ORAP + MO2       ->      HCHO   +     HO2    +     GLY 
KINETIC ARR2   7.50E-13  -500.0
! --- SAME AS ACTP + MO2 - JPL 2006 RATE CONSTANT
%
% R347 
ORAP + ACO3      ->      MO2    +     GLY
KINETIC ARR2   7.51E-13   -565.0
! --- FROM ACTP+ACO3
%
% R348 
ORAP + NO3       ->      NO2    +     GLY    +     HO2 
KINETIC ARR1   1.20E-12
! ---  RATE FROM ACTP + NO2
%
% R349 (2.00  CO2 as a product)
RCO3 + ACO3      ->      ETHP   +     MO2  
KINETIC ARR2   2.50E-12   -500.0
! --- LIGHTFOOT 1992, RATE CONST TYNDALL ET AL. 2001
! END OF MECHANISM
%
%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%
%
%  Heterogeneous reactions
%
%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%
%
%--------------------350, HR1---------------
HO2              ->      0.5 H2O2
KINETIC ARR1    1.20E-12 
%  --- HETEROGENEOUS REACTION !! change rate after spack
%
%--------------------351, HR2---------------
NO2              ->      0.5 HONO + 0.5 HNO3
KINETIC ARR1    1.20E-12 
%  --- HETEROGENEOUS REACTION !! change rate after spack
%
%--------------------352, HR3---------------
NO3              ->      HNO3
KINETIC ARR1    1.20E-12 
%  --- HETEROGENEOUS REACTION !! change rate after spack
%
%--------------------353, HR4---------------
N2O5             ->      2 HNO3
KINETIC ARR1    1.20E-12 
%  --- HETEROGENEOUS REACTION !! change rate after spack
END

